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Well-Architectured Fluoropolymers: Synthesis, Properties and Applications

Well-Architectured Fluoropolymers: Synthesis, Properties and Applications PDF Author: Bruno Ameduri
Publisher: Elsevier
ISBN: 0080474829
Category : Technology & Engineering
Languages : en
Pages : 499

Book Description
Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today's engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. - On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells - For immediate use by today's engineers, industrial and academic scientists, and researchers - Written to enable self-managed reading and learning, being both a source of data and a reference

Well-Architectured Fluoropolymers: Synthesis, Properties and Applications

Well-Architectured Fluoropolymers: Synthesis, Properties and Applications PDF Author: Bruno Ameduri
Publisher: Elsevier
ISBN: 0080474829
Category : Technology & Engineering
Languages : en
Pages : 499

Book Description
Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today's engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. - On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells - For immediate use by today's engineers, industrial and academic scientists, and researchers - Written to enable self-managed reading and learning, being both a source of data and a reference

Well-architectured Fluoropolymers

Well-architectured Fluoropolymers PDF Author: B. Améduri
Publisher: Elsevier Science Limited
ISBN: 9780080443881
Category : Science
Languages : en
Pages : 480

Book Description
Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications, is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today's engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. - On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells. - For immediate use by today's engineers, industrial and academic scientists, and researchers - Written to enable self-managed reading and learning, being both a source of data and a reference.

Technology of Fluoropolymers

Technology of Fluoropolymers PDF Author: Jiri G. Drobny
Publisher: CRC Press
ISBN: 1000839834
Category : Technology & Engineering
Languages : en
Pages : 354

Book Description
This third edition has been updated and expanded, providing industrial chemists, technologists, environmental scientists, and engineers with an accurate, compact, and practical source of information on fluoropolymers. Highlighting existing and new industrial, military, medical, and consumer goods applications, this edition adds more detailed information on equipment and processing conditions. It explores breakthroughs in understanding property-structure relationships, new polymerization techniques, and the chemistry underlying polymers, such as melt-processable fluoroplastics. It also expands on the important properties of fluoropolymers, including heat and radiation degradation, health effects, and recycling. Features: Revised, updated, and expanded to continue to provide an accurate, compact, and practical source of information on fluoropolymers Explores the property-structure relationships, polymerization techniques, and the chemistry underlying polymers Fluoropolymers rank high on the specialty polymers group and, due to their unique properties, are naturally part of the solution to the industrial sustainability challenges of the twenty-first century Describes the technology of fluoropolymers, including thermoplastic and elastomeric products Expands upon the important characteristics of fluoropolymers and their recycling.

Opportunities for Fluoropolymers

Opportunities for Fluoropolymers PDF Author: Bruno Ameduri
Publisher: Elsevier
ISBN: 0128219580
Category : Science
Languages : en
Pages : 382

Book Description
Fluoropolymers are very unique materials. Since the middle of the twentieth century fluoropolymers have been used in applications where a wide temperature range, a high resistance to aggressive media, excellent tribological characteristics, and specific low adhesion are required. Today, researchers turn to fluoropolymers to solve new challenges and to develop materials with previously unattainable properties. Opportunities for Fluoropolymers: Synthesis, Characterization, Processing, Simulation and Recycling covers recent developments in fluoropolymers, including synthesis of new copolymers, strategies for radical polymerization of fluoromonomers (conventional or controlled; RDRP), and the modification of fluoropolymers to achieve desired material characteristics. This volume in the Progress in Fluorine Science series is ideal for researchers and engineers who want to learn about the synthetic strategies, properties, and recycling of these special polymers, as well as industrial manufacturers who are interested in achieving new product characteristics in their respective industries. - Written by a global team of fluoropolymer experts - Includes conventional techniques of radical polymerization and more modern controlled polymerization techniques - Covers nanocomposites, which are of interest to researchers and industrial manufacturers of fluoropolymers

Handbook of Specialty Fluorinated Polymers

Handbook of Specialty Fluorinated Polymers PDF Author: Susanta Banerjee
Publisher: William Andrew
ISBN: 0323369960
Category : Technology & Engineering
Languages : en
Pages : 341

Book Description
Fluoropolymers are used in applications demanding service at enhanced temperature while maintaining their structural integrity and have excellent combination of chemical, physical and mechanical properties. Advancements in materials and processing technology mean that a huge amount of research is currently taking place into new, high performance applications for specialty fluorinated polymers. This book is a complete review of the current research in synthesizing new fluorinated high performance polymers and their application in the field of low dielectric constant materials, membrane based separation (gas and liquid) and proton exchange membranes. Special emphasis is given to the preparation of soluble high performance polymers by incorporating fluorine and different structural elements so as to use these classes of polymers in different membrane based applications, including low dielectric constant materials, gas separation, pervaporation, proton exchange membranes in fuel cells, and more. The coverage of processing properties and commercial aspects - as well as a practical assessment of the advantages and disadvantages of specialty fluoropolymers compared to other materials - enables engineers and product designers to apply the latest scientific developments in this area in a practical setting. Thorough coverage of modern applications for specialty fluorinated polymers, including membranes and coatings – giving insight into recent research and the future direction of this technology Brings researchers and engineers up to date with the latest developments in specialty fluoropolymers, to assist in future materials research and part design Includes detailed assessment of the advantages and shortcomings of specialty fluorinated polymers, for ease of comparison with alternative materials

Polymers for PEM Fuel Cells

Polymers for PEM Fuel Cells PDF Author: Hongting Pu
Publisher: John Wiley & Sons
ISBN: 1118869281
Category : Technology & Engineering
Languages : en
Pages : 430

Book Description
Including chemical, synthetic, and cross-disciplinary approaches; this book includes the necessary techniques and technologies to help readers better understand polymers for polymer electrolyte membrane (PEM) fuel cells. The methods in the book are essential to researchers and scientists in the field and will lead to further development in polymer and fuel cell technologies. • Provides complete, essential, and comprehensive overview of polymer applications for PEM fuel cells • Emphasizes state-of-the-art developments and methods, like PEMs for novel fuel cells and polymers for fuel cell catalysts • Includes detailed chapters on major topics, like PEM for direct liquid fuel cells and fluoropolymers and non-fluorinated polymers for PEM • Has relevance to a range of industries – like polymer engineering, materials, and green technology – involved with fuel cell technologies and R&D

Technology of Fluoropolymers

Technology of Fluoropolymers PDF Author: Jiri George Drobny
Publisher: CRC Press
ISBN: 1420063189
Category : Science
Languages : en
Pages : 250

Book Description
Fully revised and updated, this second edition continues to provide industrial chemists, technologists, and engineers with the most accurate, compact, and practical source on fluoropolymers (such as Teflon). Highlighting new industrial, military, medical, and consumer goods applications, this edition adds more detailed information on equipment and

Fluoroplastics

Fluoroplastics PDF Author: Jiri George Drobny
Publisher: iSmithers Rapra Publishing
ISBN: 9781847350077
Category : Science
Languages : en
Pages : 192

Book Description
Fluoropolymers were discovered accidentally by Plunkett in 1938. He was working on freon and accidentally polymerised tetrafluoroethylene. The result was polytetrafluoroethylene (PTFE), more commonly known as Teflon. PTFE is inert to virtually all chemicals and is considered to be the most slippery material in existence - it has the lowest coefficient of friction of any known solid material. These properties have made it one of the most valuable and versatile technologies ever invented, contributing to significant advancements in areas such as aerospace, communications, electronics, industrial.

Click Chemistry in Polymer Science

Click Chemistry in Polymer Science PDF Author: Nikhil K Singha
Publisher: Royal Society of Chemistry
ISBN: 1839169893
Category : Technology & Engineering
Languages : en
Pages : 581

Book Description
‘Click’ reactions are a unique class of versatile synthetic tools used in organic and polymer chemistry to develop new materials. The high efficiency of the click reactions, combined with their easy and straightforward execution, have made them an inevitable tool for the development of a variety of advanced polymer materials with tailor-made architectures and stimuli-responsive features. This book aims to give a comprehensive overview and introduction on the use of ‘click’ chemistry in polymer science, including ‘click,’ ‘click-like,’ and reversible ‘click’ (or ‘un-click’) approaches in the design of macromolecules. Moreover, it will outline recent progress in utilizing different ‘click chemistry’ in the development of functional polymer materials for various applications, such as self-healing, hydrophobic, shape-memory, and bio-based materials. Written and edited by leading experts in the field, chapters cover the use of different ‘click’ reactions, like azide-alkyne, Diels-Alder, Alder-ene, thiol-X, electrophilic substitution, and trans (esterification/amination) reactions, in polymer science. It will also cover the concept of ‘trans-click’ reactions, which have come to the foreground on account of improving the exchangeable efficiency of covalent bonds in covalent adaptable polymer materials. Recognizing the present state-of-the-art, this book will be a suitable reference handbook with a valuable resource of information for students of all levels, for learning and teaching endeavors, and for researchers and scientists working on the next generation of advanced polymeric materials.

Advanced Fluoropolymer Nanocomposites

Advanced Fluoropolymer Nanocomposites PDF Author: Kalim Deshmukh
Publisher: Elsevier
ISBN: 0323957951
Category : Technology & Engineering
Languages : en
Pages : 886

Book Description
Advanced Fluoropolymer Nanocomposites: Fabrication, Processing, Characterization and Applications presents a comprehensive review on the fundamental chemistry, physics, biology and engineering of advanced fluoropolymer nanocomposites. Detailed attention is given to the synthesis, processing characterization, properties and applications of fluoropolymer nanocomposites. Morphological, thermal, electrical, mechanical, tribological and viscoelastic properties are also discussed in detail, along with the influence of synthesis methods on the formation of fluoropolymer nanocomposites, including the effect of nanofiller size and shape and the dispersion state of various nanofillers in different fluoropolymer matrices. This book will be a useful reference resource for scientists, engineers and postgraduate students working in the field of polymer science and technology, materials science and engineering, composites and nanocomposites. This resource will help them find solutions to both fundamental and applied problems associated with their research. It will also assist researchers in becoming more acquainted with the field to address key questions within a short time. - Covers the range of fluoropolymer nanocomposites and their fabrication, processing, structural, physical, thermal, electrical and mechanical properties - Discusses high-performance applications in the electronics, energy, architecture, environmental, biomedical and textile industries - Presents the latest information on disposal and recycling, safety considerations, and the environmental and health impact of fluoropolymer nanocomposites