Viscoelastic Behavior of Rubbery Materials PDF Download

Author: C. Michael Roland
Publisher: Oxford University Press
ISBN: 0199571570
Category : Science
Languages : en
Pages : 341

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Book Description
The gigantic size of polymer molecules makes them "viscoelastic": their behavior changes depending on how fast and for how long the material is used. This book describes the latest discoveries in the field from a fundamental molecular perspective, in order to guide the development of better and new applications for soft materials.

Author: C. Michael Roland
Publisher: OUP Oxford
ISBN: 0191621110
Category : Science
Languages : en
Pages : 344

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Book Description
The enormous size of polymer molecules causes their molecular motions to span a broad range of length scales and give rise to viscoelastic behaviour. This rate-dependence of the properties is a predominant characteristic of soft materials (rubbers, biopolymers, lubricants, adhesives, etc.). Improving the performance and developing new applications for soft materials require an understanding of the basic principles of how molecular motions underlie physical properties. This text is intended to provide grounding in fundamental aspects of the dynamic behavior of rubbery materials, adopting a molecular perspective in its treatment to emphasize how microscopic processes are connected to the observed macroscopic behavior. The latest discoveries and advances in the science and technology of rubbery materials are described and critically analyzed.

Author: Montgomery T. Shaw
Publisher: John Wiley & Sons
ISBN: 0471741825
Category : Technology & Engineering
Languages : en
Pages : 339

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Book Description
A revised molecular approach to a classic on viscoelasticbehavior Because viscoelasticity affects the properties, appearance,processing, and performance of polymers such as rubber, plastic,and adhesives, a proper utilization of such polymers requires aclear understanding of viscoelastic behavior. Now in its third edition, Introduction to Polymer Viscoelasticityremains a classic in the literature of molecular viscoelasticity,bridging the gap between primers on polymer science and advancedresearch-level monographs. Assuming a molecular, rather than amechanical approach, the text provides a strong grounding in thefundamental concepts, detailed derivations, and particularattention to assumptions, simplifications, and limitations. This Third Edition has been entirely revised and updated to reflectrecent developments in the field. New chapters include: * Phenomenological Treatment of Viscoelasticity * Viscoelastic Models * Time-Temperature Correspondence * Transitions and Relaxation in Polymers * Elasticity of Rubbery Networks * Dielectric and NMR Methods With detailed explanations, corresponding equations, andexperimental methods, supported by real-life applications (as wellas the inclusion of a CD-ROM with data to support the exercises),this Third Edition provides today's students and professionals withthe tools they need to create polymers with more desirablequalities than ever.

Author: Roderic S. Lakes
Publisher: Cambridge University Press
ISBN: 052188568X
Category : Science
Languages : en
Pages : 481

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Book Description
This graduate text on viscoelastic materials addresses design applications as diverse as earplugs, computer disks and medical diagnostics.

Author: John D. Ferry
Publisher: John Wiley & Sons
ISBN: 9780471048947
Category : Technology & Engineering
Languages : en
Pages : 676

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Book Description
Viscoelastic behavior reflects the combined viscous and elastic responses, under mechanical stress, of materials which are intermediate between liquids and solids in character. Polymers the basic materials of the rubber and plastic industries and important to the textile, petroleum, automobile, paper, and pharmaceutical industries as well exhibit viscoelasticity to a pronounced degree. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production. Viscoelastic Properties of Polymers examines, in detail, the effects of the many variables on which the basic viscoelastic properties depend. These include temperature, pressure, and time; polymer chemical composition, molecular weight and weight distribution, branching and crystallinity; dilution with solvents or plasticizers; and mixture with other materials to form composite systems. With guidance by molecular theory, the dependence of viscoelastic properties on these variables can be simplified by introducing certain ancillary concepts such as the fractional free volume, the monomeric friction coefficient, and the spacing between entanglement loci, to provide a qualitative understanding and in many cases a quantitative prediction of how to achieve desired results. The phenomenological theory of viscoelasticity which permits interrelation of the results of different types of experiments is presented first, with many useful approximation procedures for calculations given. A wide variety of experimental methods is then described, with critical evaluation of their applicability to polymeric materials of different consistencies and in different regions of the time scale (or, for oscillating deformations, the frequency scale). A review of the present state of molecular theory follows, so that viscoelasticity can be related to the motions of flexible polymer molecules and their entanglements and network junctions. The dependence of viscoestic properties on temperature and pressure, and its descriptions using reduced variables, are discussed in detail. Several chapters are then devoted to the dependence of viscoelastic properties on chemical composition, molecular weight, presence of diluents, and other features, for several characteristic classes of polymer materials. Finally, a few examples are given to illustrate the many potential applications of these principles to practical problems in the processing and use of rubbers, plastics, and fibers, and in the control of vibration and noise. The third edition has been brought up to date to reflect the important developments, in a decade of exceptionally active research, which have led to a wider use of polymers, and a wider recognition of the importance and range of application of viscoelastic properties. Additional data have been incorporated, and the book s chapters on dilute solutions, theory of undiluted polymers, plateau and terminal zones, cross-linked polymers, and concentrated solutions have been extensively rewritten to take into account new theories and new experimental results. Technical managers and research workers in the wide range of industries in which polymers play an important role will find that the book provides basic information for practical applications, and graduate students in chemistry and engineering will find, in its illustrations with real data and real numbers, an accessible introduction to the principles of viscoelasticity.

Author: Sabu Thomas
Publisher: Royal Society of Chemistry
ISBN: 1849737649
Category : Technology & Engineering
Languages : en
Pages : 635

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Book Description
The combination of its unique morphology, physical properties, cost effectiveness and environmental friendliness make natural rubber an appealing constituent for many materials and applications. This comprehensive two volume set covers the synthesis, characterization and applications of natural rubber based blends, interpenetrating polymer networks, composites and nanocomposites. Volume 1 covers different types of natural rubber-based blends and IPNs as well as manufacturing methods, thermo mechanical characterization techniques, life cycle analysis and their applications. Volume 2 focuses on natural rubber-based composites and Nanocomposites including the different types of fillers, the filler-matrix reinforcement mechanisms, manufacturing techniques, and applications. This is the first book to consolidate the current state of the art information on natural rubber based materials with contributions from established international experts in the field. The book provides a "one stop" reference resource for professionals, researchers, industrial practitioners, graduate students, and senior undergraduates in the fields of polymer science and engineering, materials science, surface science, bioengineering and chemical engineering.

Author: James E. Mark
Publisher: Elsevier
ISBN: 0080456014
Category : Science
Languages : en
Pages : 762

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Book Description
The Science and Technology of Rubber, Third Edition provides a broad survey of elastomers with special emphasis on materials with a rubber-like elasticity. As in the 2nd edition, the emphasis remains on a unified treatment of the material; exploring topics from the chemical aspects such as elastomer synthesis and curing, through recent theoretical developments and characterization of equilibrium and dynamic properties, to the final applications of rubber, including tire engineering and manufacturing. Many advances have been made in polymer and elastomers research over the past ten years since the 2nd edition was published. Updated material stresses the continuous relationship between the ongoing research in synthesis, physics, structure and mechanics of rubber technology and industrial applications. Special attention is paid to recent advances in rubber-like elasticity theory and new processing techniques for elastomers. This new edition is comprised of 20% new material, including a new chapter on environmental issues and tire recycling.

Author: Valentin L. Popov
Publisher: Springer
ISBN: 3662587092
Category : Science
Languages : en
Pages : 357

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Book Description
This open access book contains a structured collection of the complete solutions of all essential axisymmetric contact problems. Based on a systematic distinction regarding the type of contact, the regime of friction and the contact geometry, a multitude of technically relevant contact problems from mechanical engineering, the automotive industry and medical engineering are discussed. In addition to contact problems between isotropic elastic and viscoelastic media, contact problems between transversal-isotropic elastic materials and functionally graded materials are addressed, too. The optimization of the latter is a focus of current research especially in the fields of actuator technology and biomechanics. The book takes into account adhesive effects which allow access to contact-mechanical questions about micro- and nano-electromechanical systems. Solutions of the contact problems include both the relationships between the macroscopic force, displacement and contact length, as well as the stress and displacement fields at the surface and, if appropriate, within the half-space medium. Solutions are always obtained with the simplest available method - usually with the method of dimensionality reduction (MDR) or approaches which use the solution of the non-adhesive normal contact problem to solve the respective contact problem.

Author: John J. Aklonis
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 328

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Book Description
A molecular approach to the fundamentals of viscoelastic behavior in polymers, bridging the gap between introductory accounts and advanced research level monographs. This second edition includes new coverage of the theory of reptation, the kinetic theory of rubber elasticity, and an entirely new chapter on dielectric relaxation. Presents all derivations in detail, and treats concepts and models paying special attention to assumptions, simplifications and limitations. Provides problems at the end of each chapter.

Author: Roderic S. Lakes
Publisher: CRC Press
ISBN: 1351355643
Category : Technology & Engineering
Languages : en
Pages : 476

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Book Description
Viscoelastic Solids covers the mathematical theory of viscoelasticity and physical insights, causal mechanisms, and practical applications. The book: presents a development of the theory, addressing both transient and dynamic aspects as well as emphasizing linear viscoelasticity synthesizes the structure of the theory with the aim of developing physical insight illustrates the methods for the solution of stress analysis problems in viscoelastic objects explores experimental methods for the characterization of viscoelastic materials describes the phenomenology of viscoelasticity in a variety of materials, including polymers, metals, high damping alloys, rock, piezoelectric materials, cellular solids, dense composite materials, and biological materials analyzes high damping and extremely low damping provides the theory of viscoelastic composite materials, including examples of various types of structure and the relationships between structure and mechanical properties contains examples on the use of viscoelastic materials in preventing and alleviating human suffering Viscoelastic Solids also demonstrates the use of viscoelasticity for diverse applications, such as earplugs, gaskets, computer disks, satellite stability, medical diagnosis, injury prevention, vibration abatement, tire performance, sports, spacecraft explosions, and music.