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Author: Yildirim H. Erbil Publisher: CRC Press ISBN: 142003880X Category : Science Languages : en Pages : 338
Book Description
The versatility of the emulsion copolymerization reaction and the ability to control the properties of the final latices have led to rapid expansion both in the quantity of polyvinylacetate and vinyl acetate-acrylic copolymer latices and in their applications. Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers provides
Author: Yildirim H. Erbil Publisher: CRC Press ISBN: 142003880X Category : Science Languages : en Pages : 338
Book Description
The versatility of the emulsion copolymerization reaction and the ability to control the properties of the final latices have led to rapid expansion both in the quantity of polyvinylacetate and vinyl acetate-acrylic copolymer latices and in their applications. Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers provides
Author: Mohamed S. El-Aasser Publisher: Springer Science & Business Media ISBN: 9400981147 Category : Science Languages : en Pages : 250
Book Description
It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.
Author: V. I. Eliseeva Publisher: Springer Science & Business Media ISBN: 1468416413 Category : Technology & Engineering Languages : en Pages : 231
Book Description
There is a large body of Soviet work on emulsion polymerization, spanning a period of over three decades, that has been published primarily in the Russian language. Most of this has remained untranslated into English and hence un available to most other scientists. The value of this book lies primarily in the fact that it brings together the most important of these Soviet contributions, along with comment and analysis by the authors, who may be considered among the foremost authorities in this field in the Soviet Union. But the hundreds of literature citations go far beyond the borders of the Soviet Union and serve as an excellent bibliography of the world literature on emulsion polymerization up to the time this book was written. The book covers both fundamental and applied aspects. In the former are included discussions of particle formation mechanisms, a comprehensive theory of emulsion polymerization, copolymerization of polar monomers, and particle morphology and its implications with regard to derived film properties. Among the applied aspects are discussions of continuous emulsion polymerization, both tubular reactors and continuous stirred tank cascades, and various aspects con cerning the manufacture of some of the most important monomers, such as styrene, butadiene, vinyl acetate, methyl methacrylate, acrylonitrile, and chloroprene. This book will be an indispensable reference source for scientists who are entering the field as well as those who are experienced and who have wanted a ready access to this large body of literature.
Author: Renata Jovanovic Publisher: ISBN: Category : Languages : en Pages : 0
Book Description
Several aspects of butyl acrylate/vinyl acetate (BA/VAc) polymerizations were investigated in this thesis. Polymerization process monitoring is a key factor in obtaining high quality products with prespecified properties. Therefore, a considerable part of this work was devoted to the real-time monitoring of BA/VAc emulsion polymerization reactions. An Attenuated Total Reflectance - Fourier Transform Infrared (ATR-FTIR) spectroscopy sensor was used for monitoring conversion and copolymer composition. Due to the novelty of this technique, in the first part of the study, the suitability of this technique for polymerization monitoring was investigated. In the second part of this thesis, the knowledge obtained from the off-line monitoring of the solution polymerizations was employed for the real time monitoring of six high-solids BA/VAc emulsion polymerizations. Finally, the latexes obtained in the second part of this thesis were characterized for a variety of polymer properties of interest to adhesive industry. Among the properties investigated were particle size, rheology, dynamic mechanical properties of the dry polymers and the shear and tensile strength of adhesive bonds when hard maple wood is used as a substrate. (Abstract shortened by UMI.).
Author: Masayoshi Okubo Publisher: Springer Science & Business Media ISBN: 9783540229230 Category : Technology & Engineering Languages : en Pages : 388
Book Description
In this special volume on polymer particles, recent trends and developments in the synthesis of nano- to micron-sized polymer particles by radical polymerization (Emulsion, Miniemulsion, Microemulsion, and Dispersion Polymerizations) of vinyl monomers in environmentally friendly heterogeneous aqueous and supercritical carbon dioxide fluid media are reviewed by prominent worldwide researchers. In addition to the important challenges and possibilities with regards to design and preparation of functionalized polymer particles of controlled size, the topics described are of great current interest due to the increased awareness of environmental issues.
Author: Chorng-Shyan Chern Publisher: John Wiley & Sons ISBN: 0470377933 Category : Science Languages : en Pages : 268
Book Description
Up-to-date coverage of methods of emulsion polymerization This book provides a comprehensive reference on emulsion polymerization methods,focusing on the fundamental mechanisms and kinetics of each process, as well as howthey can be applied to the manufacture of environmentally friendly polymeric materials. Topics covered include: Conventional emulsion polymerization Miniemulsion polymerization Microemulsion polymerization Industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) The role of various colloidal phenomena in emulsion polymerization Important end-use properties of emulsion polymer (latex) products Information on industrial applications in paints, coatings, adhesives, paper and board, and more This is a hands-on reference for graduate students and professionals in polymerchemistry, chemical engineering, and materials science who are involved in researchon coatings, adhesives, rubber, latex, paints, finishes, and other materials that can becreated using various methods of emulsion polymerization.
Author: Yildirim H. Erbil
Author: Yildirim H. Erbil
Author: Mohamed S. El-Aasser
Author: Nils Friis
Author: V. I. Eliseeva
Author: Renata Jovanovic
Author: Mohamed S El-Aasser
Author: David R. Bassett
Author: Edward C. Leonard
Author: Masayoshi Okubo
Author: Chorng-Shyan Chern