Coupled Vibration and Dissociation Relaxation Behind Strong Shock Waves in Carbon Dioxide PDF Download
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Author: Franz Hindelang Publisher: ISBN: Category : Carbon dioxide Languages : en Pages : 44
Book Description
The harmonic oscillator rigid-rotator model has been used to calculate the relaxation region behind a shock wave in carbon dioxide. Finite relaxation rates for the three different vibrational modes and two dissociation reactions are included. Models for the coupling between the vibrational relaxation and the dissociation process are based on the assumption that dissociation can proceed from any vibrational level with equal probability. Two different models for the vibrational excitation have been examined. Solutions have been obtained for the interdependent fluid-flow, chemical rate, and vibrational relaxation-rate equations incorporating estimated rate coefficients. Results are presented in the form of flow-field profiles for density, pressure, translational and vibrational temperatures, and species concentrations. The effects of vibrational excitation, vibration-dissociation coupling, and energy exchange between the vibrational modes are investigated. The effect of vibrational relaxation and vibration-dissociation coupling is much stronger in CO2 with three different vibrational modes than in diatomic gases with only a single mode. The results of this study show that the effect of coupled vibrational relaxation and dissociation can sometimes alter the flow-field profiles by a factor of 2 compared to similar calculations without such coupling. For vibrational relaxation the results indicate that the shock-wave profiles depend primarily on the rate at which the translational energy is fed into internal modes and not so strongly on the energy distribution among the modes.
Author: Franz Hindelang Publisher: ISBN: Category : Carbon dioxide Languages : en Pages : 44
Book Description
The harmonic oscillator rigid-rotator model has been used to calculate the relaxation region behind a shock wave in carbon dioxide. Finite relaxation rates for the three different vibrational modes and two dissociation reactions are included. Models for the coupling between the vibrational relaxation and the dissociation process are based on the assumption that dissociation can proceed from any vibrational level with equal probability. Two different models for the vibrational excitation have been examined. Solutions have been obtained for the interdependent fluid-flow, chemical rate, and vibrational relaxation-rate equations incorporating estimated rate coefficients. Results are presented in the form of flow-field profiles for density, pressure, translational and vibrational temperatures, and species concentrations. The effects of vibrational excitation, vibration-dissociation coupling, and energy exchange between the vibrational modes are investigated. The effect of vibrational relaxation and vibration-dissociation coupling is much stronger in CO2 with three different vibrational modes than in diatomic gases with only a single mode. The results of this study show that the effect of coupled vibrational relaxation and dissociation can sometimes alter the flow-field profiles by a factor of 2 compared to similar calculations without such coupling. For vibrational relaxation the results indicate that the shock-wave profiles depend primarily on the rate at which the translational energy is fed into internal modes and not so strongly on the energy distribution among the modes.
Author: Karl F. Herzfeld Publisher: Academic Press ISBN: 1483275701 Category : Science Languages : en Pages : 554
Book Description
Absorption and Dispersion of Ultrasonic Waves focuses on the influence of ultrasonics on molecular processes in liquids and gases, including hydrodynamics, energy exchange, and chemical reactions. The book first offers information on the Stokes-Navier equations of hydrodynamics, as well as equations of motion, viscosity, formal introduction of volume viscosity, and linearized wave equation for a nonviscous fluid. The manuscript then ponders on energy exchange between internal and external degrees of freedom as relaxation phenomenon; effect of slow energy exchange on sound propagation; different ways of evaluating the dispersion curve; and exact calculation of absorption and dispersion. The text examines the effects of chemical reactions, thermodynamic theory of relaxation, and mixtures. The book also evaluates the absorption of high intensity sound waves, ratio of relaxation absorption to classical absorption at maximum, and gas mixtures. Discussions also focus on translational relaxation in monatomic gases, linear triatomic molecules, and results for rotational relaxation. The manuscript is a dependable source of data for readers interested in the absorption and dispersion of ultrasonic waves.
Author: Barbara Kirchner Publisher: Springer ISBN: 3319897942 Category : Science Languages : en Pages : 295
Book Description
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. The chapters “Ionic Liquid–Liquid Chromatography: A New General Purpose Separation Methodology”, “Proteins in Ionic Liquids: Current Status of Experiments and Simulations”, “Lewis Acidic Ionic Liquids” and "Quantum Chemical Modeling of Hydrogen Bonding in Ionic Liquids" are available open access under a Creative Commons Attribution 4.0 International License via link.springer.com.
Author: Franz Hindelang
Author: Franz Hindelang
Author: Donald James Eckstrom
Author: J. W. Gallagher
Author: Karl F. Herzfeld
Author: Barbara Kirchner
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Author: Peter McAllum Walsh
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Author: Joseph Grumer