VAPOR PRESSURES OF INORGANIC SUBSTANCES: ZIRCONIUM DIOXIDE. PDF Download
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Author: Publisher: ISBN: Category : Languages : en Pages : 17
Book Description
The Knudsen effusion method was used to measure the vapor pressure of ZrO2 and a stoichiometric ZrO2+Zr mixture between 2014 and 2290 K. The pressure was calculated from rate of effusion data, using the equation p=m square root of 2 pi RT/M (p is the pressure in atmospheres; m, the rate of effusion in g/sq cm/sec; R, the molar gas constant; and M, the mol wt of the vapor). The same rates of evaporation in both cases indicated that ZrO2 vaporizes as ZrO2. The mean heat of evaporation (140.3 + or - 1.5 kcal) of ZrO2 was determined from the slope of the log p vs 1/T plot for the stated temperature range. By using a previously determined heat of evaporation for Zr and delta H sub f of ZrO2(s) (NBS values), 375 + or - 5 kcal/mol was obtained for the heat of dissociation for ZrO2 (g) into Zr (g) and O (g). The bp pf ZrO2 was calculated to be 3735 K from the NBS data for temperature, heat, and entropy of fusion. (See also AD18365).
Author: Publisher: ISBN: Category : Languages : en Pages : 17
Book Description
The Knudsen effusion method was used to measure the vapor pressure of ZrO2 and a stoichiometric ZrO2+Zr mixture between 2014 and 2290 K. The pressure was calculated from rate of effusion data, using the equation p=m square root of 2 pi RT/M (p is the pressure in atmospheres; m, the rate of effusion in g/sq cm/sec; R, the molar gas constant; and M, the mol wt of the vapor). The same rates of evaporation in both cases indicated that ZrO2 vaporizes as ZrO2. The mean heat of evaporation (140.3 + or - 1.5 kcal) of ZrO2 was determined from the slope of the log p vs 1/T plot for the stated temperature range. By using a previously determined heat of evaporation for Zr and delta H sub f of ZrO2(s) (NBS values), 375 + or - 5 kcal/mol was obtained for the heat of dissociation for ZrO2 (g) into Zr (g) and O (g). The bp pf ZrO2 was calculated to be 3735 K from the NBS data for temperature, heat, and entropy of fusion. (See also AD18365).
Author: James M. Scarborough Publisher: ISBN: Category : Vapor pressure Languages : en Pages : 32
Book Description
Briefly, the methods of determining low vapor pressures have been reviewed. Emphasis has been placed on molecular effusion, including a theoretical discussion and the subsequent application of molecular beams to the determination of vapor pressure. The problems met in the preparation, purification and handling of anhydrous zirconium tetrachloride have been discussed. Vapor pressure measurements on zirconium tetrachloride have been made over a temperature range of fifty degrees, 70 deg C. to 120 deg C, . and the mean molar heat of sublimation for this temperature range has been calculated. The value of 20.3 kcal per mole obtained is not unreasonable in view of the fact that values for the same quantity determined by other investigators in the temperature range of 239 deg C. to 346 deg C. is reported to be 24.4 kcal. per mole.
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Author: Kenneth Keith Kelley
Author: Carl L. Yaws
Author: D. W. Kuhn
Author: Armour Research Foundation (U.S.)
Author: M. M. Nakata
Author: James M. Scarborough
Author: Thomas Earl Jordan
Author: G. A. Burrell
Author: