Using Solid-solution Aqueous-solution Theories to Model the Crystallization of ZSM-5 Zeolites PDF Download

Author: Dustin W. Fickel
Publisher:
ISBN:
Category : Crystallization
Languages : en
Pages : 87

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Book Description
ZSM-5 is one of the more important and commonly used zeolites. It is the second most used zeolite in catalysis due to its unique framework and three-dimensional pore structure. The work in this thesis focuses on the formation of ZSM-5 through non-organic synthesis. To understand the formation of this zeolite, solid-solution aqueous-solution (SSAS) theories and thermodynamics are applied to quantify the relationship among the compositions of the resulting crystalline zeolite, the synthesis gel, and the aqueous phase during the synthesis.

Author: Rosemarie Szostak
Publisher: Springer Science & Business Media
ISBN: 9401095299
Category : Science
Languages : en
Pages : 473

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Book Description
From areport by a Lieutenant Colonel W.A. Ross (Chern. News, Nov.15, 1878, p. 236). Progress did not accelerate during the next 50 years. McBain, in his clas sic 1932 book, The Sorption oi Gases by So lids, devoted a chapter to sorp tion by chabasite, other zeolites, and permeable crystals. McBain remarked that "great interest attaches to the finding of Weigel and Steinhoff [0. Weigel and E. Steinhoff, Z. Kris!., 61, 125 (1925{raquo}) that chabasite rapidly sorbs the vapors of water, methyl and ethyl alcohol and formie acid, whereas acetone, ether and benzene are largely excluded. The significance of their results was pointed out by McBain [J.W. McBain, Colloid. Syrnp. Mon., 20, 1 (1926{raquo}) and recognized by alliater writers. It is evident that the partially dehydrated chabasite forms a nearly perfect molecular sieve or a semipermeable membrane of extremely regular structure ... ". While the significance of the above observation may have been recog nized, it had little impact. Thus, an eminent pioneer in the synthesis and characterization af zeolites, Professor R.M. Barrer, spent nearly two dec ades (following his Ph. D. studies in the 1930s) developing a firm foundation for the rapid growth in scientific understanding and industrial applications of zeolites which has taken place during the last 30 years.

Author:
Publisher: Newnes
ISBN: 0080965296
Category : Science
Languages : en
Pages : 7694

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Book Description
Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

Author: Krijn P. de Jong
Publisher: John Wiley & Sons
ISBN: 3527320407
Category : Science
Languages : en
Pages : 436

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Book Description
This practical book combines recent progress with a discussion of the general aspects of catalyst preparation. The first part deals with the basic principles of solid catalyst preparation, explaining the main aspects of sol-gel chemistry and interfacial chemistry, followed by such techniques as co-precipitation and immobilization. New tools for catalyst preparation research, including microspectroscopy and high-throughput experimentation, are also taken into account. The second part heightens the practical relevance by providing six case studies on such topics as the preparation of zeolites, hydrotreating catalysts, methanol catalysts and gold catalysts

Author: Mihai V. Putz
Publisher: CRC Press
ISBN: 0429663153
Category : Science
Languages : en
Pages : 401

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Book Description
New Frontiers in Nanochemistry: Concepts, Theories, and Trends, Volume 2: Topological Nanochemistry is the second of the new three-volume set that explains and explores the important basic and advanced modern concepts in multidisciplinary chemistry. Under the broad expertise of the editor, this second volume explores the rich research areas of nanochemistry with a specific focus on the design and control of nanotechnology by structural and reactive topology. The objective of this particular volume is to emphasize the application of nanochemistry. With 46 entries from eminent international scientists and scholars, the content in this volume spans concepts from A-to-Z—from entries on the atom-bond connectivity index to the Zagreb indices, from connectivity to vapor phase epitaxy, and from fullerenes to topological reactivity—and much more. The definitions within the text are accompanied by brief but comprehensive explicative essays as well as figures, tables, etc., providing a holistic understanding of the concepts presented.

Author:
Publisher:
ISBN:
Category : Chemistry, Physical and theoretical
Languages : en
Pages : 870

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Author: Javier García-Martínez
Publisher: John Wiley & Sons
ISBN: 3527335749
Category : Technology & Engineering
Languages : en
Pages : 608

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Book Description
Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.

Author: H. Robson
Publisher: Gulf Professional Publishing
ISBN: 9780444507037
Category : Architecture
Languages : en
Pages : 288

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Book Description
Zeolite synthesis is an active field of research. As long as this continues, new phases will be discovered and new techniques for preparing existing phases will appear. This edition of Verified Synthesis of Zeolitic Materials contains all the recipes from the first edition plus 24 new recipes. Five new introductory articles have been included plus those from the first edition, some of which have been substantially revised. The XRD patterns have been recorded using different instrument settings from those in the first edition and are intended to conform to typical X-ray diffraction practice. In most cases, only the XRD pattern for the productas synthesised is printed here. The exceptions are those phases which show marked changes in the XRD pattern upon calcination.

Author: Ruren Xu
Publisher: John Wiley & Sons
ISBN: 0470822368
Category : Science
Languages : en
Pages : 616

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Book Description
Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.

Author: Mario L. Occelli
Publisher:
ISBN:
Category : Language Arts & Disciplines
Languages : en
Pages : 672

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Book Description
This volume is a complete progress report on the various aspects of zeolite synthesis on a molecular level. It provides many examples that illustrate how zeolites can be crystallized and what the important parameters are that control crystallization. Forty-two chapters cover such topics as: crystallization techniques; gel chemistry; crystal size and morphology; the role of organic compounds; and novel synthesis procedures. It offers a complete review of zeolite synthesis as well as the latest finding in this important field. Contains benchmark contributions from many notable pioneers in the field, including R.M. Barrer, H. Robson, and Robert Milton.