Transuranic Decontamination of Nitric Acid Solutions by the Truex Solvent Extraction Process PDF Download

Author: George F. Vandegrift
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 116

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Author:
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Languages : en
Pages : 0

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This report summarizes the work that has been performed to date at Argonne National Laboratory on the development of the TRUEX process, a solvent extraction process employing a bifunctional organophosphorous reagent in a PUREX process solvent (tributyl phosphate-normal paraffinic hydrocarbons). The purpose of this extraction process is to separate and concentrate transuranic (TRU) elements from nuclear waste. Assessments were made of the use of two TRUEX solvents: one incorporating the well-studied dihexyl-N, N-diethylcarbamoylmethylphosphonate (DHDECMP) and a second incorporating an extractant with superior properties for a 1M HNO3 acid feed, octyl(phenyl)-N, N-diisobutylcarbamoylmethylphosphine oxide (O/sub phi/D(IB)CMPO). In this report, conceptual flowsheets for the removal of soluble TRUs from high-level nuclear wastes using these two TRUEX proces solvents are presented, and flowsheet features are discussed in detail. The conceptual flowsheet for TRU-element removal from a PUREX waste by the O/sub phi/D(IB)CMPO-TRUEX process solvent was tested in a bench-scale countercurrent experiment, and results of that experiment are presented and discussed. The conclusion of this study is that the TRUEX process is able to separate TRUs from high-level wastes so that the major portion of the solid waste (approx. 99%) can be classified as non-TRU. Areas where more experimentation is needed are listed at the end of the report. 45 references, 17 figures, 56 tables.

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Category :
Languages : en
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High-level liquid waste is produced during the processing of irradiated nuclear fuel by the PUREX process. In some cases the treatment of metallurgical scrap to recover the plutonium values also generates a nitric acid waste solution. Both waste solutions contain sufficient concentrations of transuranic elements (mostly 241Am) to require handling and disposal as a TRU waste. This paper describes a recently developed solvent extraction/recovery process called TRUEX (transuranium extraction) which is designed to reduce the TRU concentration in nitric waste solutions to

Author: Thomas E Carleson
Publisher: CRC Press
ISBN: 1351357832
Category : Technology & Engineering
Languages : en
Pages : 503

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Separation Techniques in Nuclear Waste Management is an up-to-date, comprehensive survey of processes for separation of nuclear wastes. Comprised of articles by scientists and engineers at universities and national laboratories in the U.S. and overseas, the book provides excellent reference information for individuals working in nuclear waste management. Specifically, the book covers current separation technologies and techniques for waste liquid, solid, and gas streams that contain radionuclides. Such wastes are typical of those produced as a result of nuclear materials processing and spent fuel reprocessing. Chapters on promising new technologies and state-of-the-art processes currently in use provide valuable information for design engineers, as well as for research scientists. The articles in Separation Techniques in Nuclear Waste Management are brief and concise - designed for quick access to pertinent information. Many of the contributors are leaders in their fields. It is the most current survey available of the latest nuclear waste management techniques.

Author: Bruce A. Moyer
Publisher: CRC Press
ISBN: 142005970X
Category : Science
Languages : en
Pages : 682

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The growth in the world's nuclear industry, motivated by peaking world oil supplies, concerns about the greenhouse effect, and domestic needs for energy independence, has resulted in a heightened focus on the need for next-generation nuclear fuel-cycle technologies. Ion Exchange and Solvent Extraction: A Series of Advances, Volume 19 provides a com

Author: Messrs L. Cecille
Publisher: Springer Science & Business Media
ISBN: 9401136548
Category : Science
Languages : en
Pages : 363

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The purpose of this technical seminar was to evaluate the present state of the art in matter of advanced separation techniques like solvent extraction, ion-exchange, chemical precipitation, membrane and electrical processes for the treatment of radioactive liquid waste and a selection of some specific industrial non-radioactive effluents. Through this initiative, the organisers aimed at promoting the exchange of information between scientists from various origins (universities, research centres and industries) while contributing to the necessary overcoming of the artificial barriers which too often limit the "technology transfer" between the nuclear and non-nuclear sectors. Vll CONTENTS PREFACE ........................................ V ABBREVIATIONS ...................................... xiv OPENING SESSION WELCOME ADDRESS C. MANCINI (ENEA) .................................... 3 OPENING ADDRESS S. FINZI (CEC) ....................................... 7 AREAS WHERE ADVANCED SEPARATION TECHNIQUES ARE DESIRABLE G. GROSSI (ENEA), L. CECILLE (CEC) ....................... 11 REVIEW OF NEW EXTRACT ANTS POTENTIALLY APPLICABLE TO THE PROCESSING OF RADIOACTIVE LIQUID WASTES (Summary) P.R. DANESI, International Atomic Energy Agency, Vienna, Austria . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 . . . . . . . . . .

Author: Gregory R. Choppin
Publisher: Springer Science & Business Media
ISBN: 1489914064
Category : Science
Languages : en
Pages : 276

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The symposium which provided the incentive for this volume was conducted in San th Diego, California as a part of the 207 National Meeting of the American Chemical Society, March 13-17, 1994. It was conceived partly to continue an informal decennial sequence of sym posia dedicated to the topic off element separations. A lot has changed in the world of f ele ments over the last ten years, precipitating a change in emphasis which should be evident to most practitioners in the field. Production and reprocessing of nuclear fuels are no longer the principal drivers of f element separation technology. Separations technology for environment restoration, waste disposal, and the preparation of high purity lanthanides are now the defming parameters in this important field. These imperatives are reflected in the contributions to this volume. The symposium itself must be considered a success, as the attendance at all sessions was above expectations, despite the fact that it was conducted on the last two days of a large five day meeting. Our thanks to the speakers for their quality presentations, and to the audience who persevered to the end of a long meeting and against the temptation of the excellent weather of San Diego in the springtime. A complete list of symposium participants is given in Appendix 1. Preparation of this volume has been a relatively painless undertaking, largely as a result ofthe high quality ofthe submitted papers.

Author: Kenneth D. Kok
Publisher: CRC Press
ISBN: 1315356309
Category : Science
Languages : en
Pages : 1328

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Building upon the success of the first edition, the Nuclear Engineering Handbook, Second Edition, provides a comprehensive, up-to-date overview of nuclear power engineering. Consisting of chapters written by leading experts, this volume spans a wide range of topics in the areas of nuclear power reactor design and operation, nuclear fuel cycles, and radiation detection. Plant safety issues are addressed, and the economics of nuclear power generation in the 21st century are presented. The Second Edition also includes full coverage of Generation IV reactor designs, and new information on MRS technologies, small modular reactors, and fast reactors.

Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 54

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The goal of this process is to separate the transuranic elements from the bulk components so that the bulk components can be disposed of as low-level waste with only a small transuranic-containing fraction requiring geologic disposal. The pretreatment process examined here is the one indicated to be most promising in the initial studies. It involves dissolving the unwashed sludge in nitric acid and then using the TRUEX solvent extraction process to remove the transuranic elements from the bulk components of the waste. The areas identified in this work that need additional information are gradual precipitate formation as dissolved sludge solutions age, and formation of solid material when the dissolved sludge solution is contacted with the solvent used in the TRUEX process. 5 refs., 71 figs., 10 tabs.

Author: L.R. Morss
Publisher: Springer Science & Business Media
ISBN: 1402035985
Category : Science
Languages : en
Pages : 4059

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The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.