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Book Description
Ce travail vise à étudier le couplage entre écoulement et interactions physico-chimiques dans les sols, dans différentes conditions de saturation en eau, afin d'améliorer la prédiction du devenir des polluants. Il s'agit de comprendre en quoi le taux de saturation du milieu affecte la réactivité du sol vis-à-vis des polluants, et d'évaluer le pouvoir prédictif du transport de solutés réactifs étudié en milieu saturé sur la réactivité en conditions non saturées. Différents processus sont considérés : l'échange de cations calcium-zinc sur un milieu poreux modèle (sable-kaolinite), la sorption et désorption d'un composé organique sur une terre non contaminée, le transport de polluants prioritaires tels que les HAP sur une terre de friche industrielle. Dans chaque cas, des expériences en colonne de laboratoire ont été conduites en conditions d'écoulement saturé et non saturé permanent, permettant tout d'abord la caractérisation de l'hydrodynamique, puis l'étude du couplage avec la réactivité. Les courbes de percée obtenues ont été ensuite modélisées avec des codes tels que CXTFIT. On a montré l'influence de la teneur en eau du milieu sur le transport réactif, variable suivant le type de réaction considéré, la structure des milieux jouant également un rôle important. L'échange d'ions sur le milieu modèle n'est globalement pas affecté par la teneur en eau, dans une gamme proche de la saturation. En revanche, une plus forte sorption et une plus faible mobilisation des polluants organiques ont été observées en conditions non saturées. Le transport réactif de ces composés ne peut donc pas être prédit en conditions non saturées à partir de mesures en milieu saturé, qui peuvent surestimer le transport.
Book Description
Ce travail vise à étudier le couplage entre écoulement et interactions physico-chimiques dans les sols, dans différentes conditions de saturation en eau, afin d'améliorer la prédiction du devenir des polluants. Il s'agit de comprendre en quoi le taux de saturation du milieu affecte la réactivité du sol vis-à-vis des polluants, et d'évaluer le pouvoir prédictif du transport de solutés réactifs étudié en milieu saturé sur la réactivité en conditions non saturées. Différents processus sont considérés : l'échange de cations calcium-zinc sur un milieu poreux modèle (sable-kaolinite), la sorption et désorption d'un composé organique sur une terre non contaminée, le transport de polluants prioritaires tels que les HAP sur une terre de friche industrielle. Dans chaque cas, des expériences en colonne de laboratoire ont été conduites en conditions d'écoulement saturé et non saturé permanent, permettant tout d'abord la caractérisation de l'hydrodynamique, puis l'étude du couplage avec la réactivité. Les courbes de percée obtenues ont été ensuite modélisées avec des codes tels que CXTFIT. On a montré l'influence de la teneur en eau du milieu sur le transport réactif, variable suivant le type de réaction considéré, la structure des milieux jouant également un rôle important. L'échange d'ions sur le milieu modèle n'est globalement pas affecté par la teneur en eau, dans une gamme proche de la saturation. En revanche, une plus forte sorption et une plus faible mobilisation des polluants organiques ont été observées en conditions non saturées. Le transport réactif de ces composés ne peut donc pas être prédit en conditions non saturées à partir de mesures en milieu saturé, qui peuvent surestimer le transport.
Author: Michel Fremond Publisher: Springer Science & Business Media ISBN: 3540323996 Category : Technology & Engineering Languages : en Pages : 405
Book Description
In this edited book various novel approaches to problems of modern civil engineering are demonstrated. Experts associated within the Lagrange Laboratory present recent research results in civil engineering dealing both with modelling and computational aspects. Many modern topics are covered, such as monumental dams, soil mechanics and geotechnics, granular media, contact and friction problems, damage and fracture, new structural materials, and vibration damping – presenting the state of the art of mechanical modelling and computational issues in civil engineering.
Author: Helmut Kobus Publisher: Springer Science & Business Media ISBN: 3642457509 Category : Science Languages : en Pages : 366
Book Description
The complex topic of in-situ subsurface remediation technologies has been ad dressed at an international symposium at the Universitat Stuttgart on September 26 and 27, 1995, on the occasion of the inauguration of the research facility VEGAS (Versuchseinrichtung zur Grundwasser- und Altlastensanierung). The results are contained in this book with 22 contributions from leading experts in the field from Europe and North America. The book illustrates the role of large-scale experiments in groundwater and subsurface remediation research. The subtopics address the various links between conventional laboratory experiments, technology-scale experiments and field-site studies, showing the contribution of large-scale experiments to bridging the gap between small-scale investigations and large-scale field investigations (upscaling). The interdisciplinary nature of the problems requires a multidisciplinary approach. Therefore, the idea has been followed to bring together the various disciplines in volved in the different aspects and facets of subsurface flow, transport and trans as hydraulics and hydrology, physics, formation, involving such diverse disciplines chemistry, microbiology, geology, industrial, chemical and hydraulic engineering, mathematics and hydroinformatics. The individual contributions from these di versified fields address the subject from different angles in an attempt to form a coherent picture of the various aspects of the complex problems of subsurface remediation. The focus is on research approaches and strategies with respect to the development of new and improved technologies and to the role of large-scale experiments in research and application.
Author: Giovanni Bidoglio Publisher: Springer Science & Business Media ISBN: 9401710244 Category : Science Languages : en Pages : 534
Book Description
Aquatic systems play a salient role in the complex processes of energy and matter exchange between the geosphere and the atmosphere. For example, reactions taking place in cloud water droplets can substantially alter the atmospheric budget and chemistry of trace gases; pollution induced weathering reactions at water/soil interfaces can affect the availability of nutrients and increase the concentration of potentially toxic metals in groundwaters. Moreover, the inextricable links between the water cycle, the geosphere and the atmosphere ensure that apparently localized environmental problems have increasingly impacts in other parts of the world. To identify local-to-global scale variables associated with environmental changes, a focus must be placed on the recognition of processes, rather than a continued reliance on monitoring state variables. However, in heterogeneous aquatic systems, small scale aspects of a process under observation may not be summed directly to obtain regional estimates because of process nonlinearities with change in scale. To understand this, the integrated use of measurements across a range of scales is required.
Author: Bernardo Caicedo Publisher: CRC Press ISBN: 0415620953 Category : Technology & Engineering Languages : en Pages : 612
Book Description
New theories and testing techniques related with Unsaturated Soil Mechanics have proven to be valuable tools to study a broad spectrum of geo-materials which includes rocks, rock fills, frozen soils and domiciliary solid wastes. These new theories and testing techniques have permitted the analysis of several traditional problems from a new perspective (e.g., swelling or collapsible soils and compacted soils or pavements materials), and they have also shown their efficiency to study new energy-related problems like CO2 sequestration and nuclear waste disposal. Advances in Unsaturated Soils is a collection of papers from the 1st Pan-American Conference on Unsaturated Soils organized in Cartagena de Indias, Colombia, in February 2013. The volume includes 76 research papers coming for all over the world, as well as 7 keynotes papers by well known international researchers. The contributions present a variety of topics including: • Advances in testing techniques • Unsaturated soil behavior • Constitutive modeling and microstructure • Numerical modeling • Geotechnical problems Advances in Unsaturated Soils is expected to become a useful reference to academics and professionals involved in Unsaturated Soil Mechanics.
Author: J.M. Crolet Publisher: Springer Science & Business Media ISBN: 9401728569 Category : Science Languages : en Pages : 272
Book Description
Porous media, and especially phenomena of transport in such materials, are an impor1ant field of interest for geologists, hydrogeologists, researchers in soil and fluid mechanics, petroleum and chemical engineers, physicists and scientists in many other disciplines. The development of better numerical simulation techniques in combination with the enormous expansion of computer tools, have enabled numerical simulation of transport phenomena (mass of phases and components, energy etc. ) in porous domains of interest. Before any practical application of the results of such simulations can be used, it is essential that the simulation models have been proven to be valid. In order to establish the greatest possible coherence between the models and the physical reality, frequent interaction between numericians, mathematicians and the previously quoted researchers, is necessary. Once this coherence is established, the numerical simulations could be used to predict various phenomena such as water management, propagation of pollutants etc. These simulations could be, in many cases, the only financially acceptable tool to carry out an investigation. Current studies within various fields of applications include not only physical comprehension aspects of flow and energy or solute transport in saturated or unsaturated media but also numerical aspects in deriving strong complex equations. Among the various fields of applications generally two types of problems can be observed. Those associated with the pollution of the environment and those linked to water management. The former are essentially a problem in industrialized countries, the latter are a major source of concern in North-Africa.
Author: Gilles Pijaudier-Cabot Publisher: John Wiley & Sons ISBN: 1118577450 Category : Technology & Engineering Languages : en Pages : 258
Book Description
CO2 capture and geological storage is seen as the most effective technology to rapidly reduce the emission of greenhouse gases into the atmosphere. Up until now and before proceeding to an industrial development of this technology, laboratory research has been conducted for several years and pilot projects have been launched. So far, these studies have mainly focused on transport and geochemical issues and few studies have been dedicated to the geomechanical issues in CO2 storage facilities. The purpose of this book is to give an overview of the multiphysics processes occurring in CO2 storage facilities, with particular attention given to coupled geomechanical problems. The book is divided into three parts. The first part is dedicated to transport processes and focuses on the efficiency of the storage complex and the evaluation of possible leakage paths. The second part deals with issues related to reservoir injectivity and the presence of fractures and occurrence of damage. The final part of the book concerns the serviceability and ageing of the geomaterials whose poromechanical properties may be altered by contact with the injected reactive fluid.
Author: Valérie Gujisaite
Author: Valérie Gujisaite
Author: Michel Fremond
Author: Helmut Kobus
Author: National Research Council Canada
Author: Giovanni Bidoglio
Author: Bernardo Caicedo
Author: J.M. Crolet
Author: 
Author: Gilles Pijaudier-Cabot
Author: