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Statistical Thermodynamics of Alloys

Statistical Thermodynamics of Alloys PDF Author: N.A. Gokcen
Publisher: Springer Science & Business Media
ISBN: 1468450530
Category : Science
Languages : en
Pages : 330

Book Description
This book is intended for scientists, researchers, and graduate students interested in solutions in general, and solutions of metals in particular. Readers are assumed to have a good background in thermodynamics, presented in such books as those cited at the end of Chapter 1, "Thermo dynamic Background." The contents of the book are limited to the solutions of metals + metals, and metals + metalloids, but the results are also appli cable to numerous other types of solutions encountered by metallurgists, materials scientists, geologists, ceramists, and chemists. Attempts have been made to cover each topic in depth with numerical examples whenever necessary. Chapter 2 presents phase equilibria and phase diagrams as related to the thermodynamics of solutions. The emphasis is on the binary diagrams since the ternary diagrams can be understood in terms of the binary diagrams coupled with the phase rule, and the Gibbs energies of mixing. The cal culation of thermodynamic properties from the phase diagrams is not emphasized because such a procedure generally yields mediocre results. Nevertheless, the reader can readily obtain thermodynamic data from phase diagrams by reversing the detailed process of calculation of phase diagrams from thermodynamic data. Empirical rules on phase stability are given in this chapter for a brief and clear understanding of the physical and atomistic factors underlying the alloy phase formation.

Statistical Thermodynamics of Alloys

Statistical Thermodynamics of Alloys PDF Author: N.A. Gokcen
Publisher: Springer Science & Business Media
ISBN: 1468450530
Category : Science
Languages : en
Pages : 330

Book Description
This book is intended for scientists, researchers, and graduate students interested in solutions in general, and solutions of metals in particular. Readers are assumed to have a good background in thermodynamics, presented in such books as those cited at the end of Chapter 1, "Thermo dynamic Background." The contents of the book are limited to the solutions of metals + metals, and metals + metalloids, but the results are also appli cable to numerous other types of solutions encountered by metallurgists, materials scientists, geologists, ceramists, and chemists. Attempts have been made to cover each topic in depth with numerical examples whenever necessary. Chapter 2 presents phase equilibria and phase diagrams as related to the thermodynamics of solutions. The emphasis is on the binary diagrams since the ternary diagrams can be understood in terms of the binary diagrams coupled with the phase rule, and the Gibbs energies of mixing. The cal culation of thermodynamic properties from the phase diagrams is not emphasized because such a procedure generally yields mediocre results. Nevertheless, the reader can readily obtain thermodynamic data from phase diagrams by reversing the detailed process of calculation of phase diagrams from thermodynamic data. Empirical rules on phase stability are given in this chapter for a brief and clear understanding of the physical and atomistic factors underlying the alloy phase formation.

Thermodynamics of Alloy Formation

Thermodynamics of Alloy Formation PDF Author: Y. Austin Chang
Publisher: Minerals, Metals, & Materials Society
ISBN:
Category : Science
Languages : en
Pages : 330

Book Description
State-of-the-art experimental techniques used to obtain information on thermodynamic stabilities of alloy phases are presented and discussed in these proceedings from the 1997 Hume Rothery Symposium. Coverage includes an examination of thermodynamic stability and structure of materials in the amorphous state. Also, experimental information obtained for materials in both the stable and metastable state is used to evaluate the thermodynamic models of alloy phases and to calculate phase diagrams.

Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys

Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys PDF Author: Felicitas Predel
Publisher: Springer
ISBN: 9783642249761
Category : Science
Languages : en
Pages : 254

Book Description
Thermodynamics determines the properties and region of existence of any alloy. Pressure, temperature and composition are the key parameters that dictate its crystal structure, crystallographic data, physical and mechanical properties. Phase diagrams are of utmost importance as overviews of the particularities of any alloying mixture. The present volume presents phase equilibria, thermodynamic and crystallographic data of the binary alloys K-O ... Y-Zr.

Solution Calorimetry

Solution Calorimetry PDF Author: K. N. Marsh
Publisher: Wiley-Blackwell
ISBN: 9780865428522
Category : Science
Languages : en
Pages : 331

Book Description
Synthetic organic chemistry is currently advancing in many new and exciting directions. Formation of C-H, C-O and C-C bonds with high diastero- and enantio-selectivity is still emerging; and as methods such as these develop, sythetic strategies to complex organic molecules follow. By being able to make structural entities at will, the prospect for understanding molecular function,"

Basics of Thermodynamics and Phase Transitions in Complex Intermetallics

Basics of Thermodynamics and Phase Transitions in Complex Intermetallics PDF Author: Esther Belin-Ferr‚
Publisher: World Scientific
ISBN: 9812790586
Category : Technology & Engineering
Languages : en
Pages : 408

Book Description
Complex metal alloys (CMAs) comprise a huge group of largely unknown alloys and compounds, where many phases are formed with crystal structures based on giant unit cells containing atom clusters, ranging from tens of to more than thousand atoms per unit cell. In these phases, for many phenomena, the physical length scales are substantially smaller than the unit-cell dimension. Hence, these materials offer unique combinations of properties which are mutually exclusive in conventional materials, such as metallic electric conductivity combined with low thermal conductivity, good light absorption with high-temperature stability, high metallic hardness with reduced wetting by liquids, etc.This book is the first of a series of books issued yearly as a deliverable to the European Community of the School established within the European Network of Excellence CMA. Written by reputed experts in the fields of metal physics, surface physics, surface chemistry, metallurgy, and process engineering, this book brings together expertise found inside as well as outside the network to provide a comprehensive overview of the current state of knowledge in CMAs.

Structural Thermodynamics of Alloys

Structural Thermodynamics of Alloys PDF Author: J. Manenc
Publisher: Springer Science & Business Media
ISBN: 940102605X
Category : Science
Languages : en
Pages : 222

Book Description
Technical progress has for a very long time been directly dependent on progress in metallurgy, which is itself connected with improvements in the technology of alloys. Metals are most frequently used in the form of alloys for several reasons: the quantity of pure metal in its native state in the earth's crust is very limited; pure metals must be extracted from ores which are themselves impure. Finally, the methods of treatment used lead more easily to alloys than to pure metals. The most typical case is that of iron, where a pure ore may be found, but which is the starting point for cast iron or steel, alloys of iron and carbon. In addition, the properties of alloys are in general superior to those of pure metals and modem metallurgy consists of controlling these properties so as to make them conform to the requirements of the design office. Whilst the engineer was formerly compelled to adapt his designs and constructions to the materials available, such as wood, stone, bronze, iron, cast iron and ordinary steels, he can now expect, due to metallurgical research, the creation of special alloys meeting specific requirements. These requirements must of course be reasonable, but VIII INTRODUCTION must be sufficiently imperative for them to become the motive for progress.

The Application of Chemical Thermodynamics to the Study of Metallic Alloy Formation

The Application of Chemical Thermodynamics to the Study of Metallic Alloy Formation PDF Author:
Publisher:
ISBN:
Category : Magnesium-cadmium alloys
Languages : en
Pages : 14

Book Description


Computational Thermodynamics of Materials

Computational Thermodynamics of Materials PDF Author: Zi-Kui Liu
Publisher: Cambridge University Press
ISBN: 0521198968
Category : Science
Languages : en
Pages : 261

Book Description
Integrates fundamental concepts with experimental data and practical applications, including worked examples and end-of-chapter problems.

High-Entropy Alloys

High-Entropy Alloys PDF Author: Michael C. Gao
Publisher: Springer
ISBN: 3319270133
Category : Technology & Engineering
Languages : en
Pages : 524

Book Description
This book provides a systematic and comprehensive description of high-entropy alloys (HEAs). The authors summarize key properties of HEAs from the perspective of both fundamental understanding and applications, which are supported by in-depth analyses. The book also contains computational modeling in tackling HEAs, which help elucidate the formation mechanisms and properties of HEAs from various length and time scales.

Thermodynamics

Thermodynamics PDF Author: Juan Carlos Moreno Piraján
Publisher: BoD – Books on Demand
ISBN: 9533079797
Category : Science
Languages : en
Pages : 450

Book Description
Thermodynamics is one of the most exciting branches of physical chemistry which has greatly contributed to the modern science. Being concentrated on a wide range of applications of thermodynamics, this book gathers a series of contributions by the finest scientists in the world, gathered in an orderly manner. It can be used in post-graduate courses for students and as a reference book, as it is written in a language pleasing to the reader. It can also serve as a reference material for researchers to whom the thermodynamics is one of the area of interest.