Thermodynamic and Kinetic Properties of Metal Ions in Aqueous Solution PDF Download

Author: Welby G. Courtney
Publisher:
ISBN:
Category : Metal ions
Languages : en
Pages : 54

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Author:
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ISBN:
Category :
Languages : en
Pages :

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Author: Arthur E. Martell
Publisher: Springer
ISBN: 9780306452482
Category : Science
Languages : en
Pages : 254

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Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.

Author: John P. Hunt
Publisher:
ISBN:
Category : Ions
Languages : en
Pages : 144

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Author: John Burgess
Publisher:
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Category : Science
Languages : en
Pages : 492

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Author: Anne-Marie Couture
Publisher:
ISBN:
Category : Electrolyte solutions
Languages : en
Pages : 0

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Author: Giovanni Bidoglio
Publisher: Springer Science & Business Media
ISBN: 9401710244
Category : Science
Languages : en
Pages : 534

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Aquatic systems play a salient role in the complex processes of energy and matter exchange between the geosphere and the atmosphere. For example, reactions taking place in cloud water droplets can substantially alter the atmospheric budget and chemistry of trace gases; pollution induced weathering reactions at water/soil interfaces can affect the availability of nutrients and increase the concentration of potentially toxic metals in groundwaters. Moreover, the inextricable links between the water cycle, the geosphere and the atmosphere ensure that apparently localized environmental problems have increasingly impacts in other parts of the world. To identify local-to-global scale variables associated with environmental changes, a focus must be placed on the recognition of processes, rather than a continued reliance on monitoring state variables. However, in heterogeneous aquatic systems, small scale aspects of a process under observation may not be summed directly to obtain regional estimates because of process nonlinearities with change in scale. To understand this, the integrated use of measurements across a range of scales is required.

Author:
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ISBN:
Category : Physical instruments
Languages : en
Pages : 204

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Author: Jean-Claude G. Bunzli
Publisher: Elsevier
ISBN: 0323851096
Category : Science
Languages : en
Pages : 340

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Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 60 presents the latest release in this continuous series that covers all aspects of rare earth science, including chemistry, life sciences, materials science and physics. Presents up-to-date overviews and new developments in the field of rare earths, covering both their physics and chemistry Contains individual chapters that are comprehensive and broad, along with critical reviews Provides contributions from highly experienced, invited experts

Author: National Measurement Laboratory (U.S.). Office of Standard Reference Data
Publisher:
ISBN:
Category : Chemistry, Physical and theoretical
Languages : en
Pages : 204

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