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Author: A.K. Galwey Publisher: Elsevier ISBN: 0080542794 Category : Science Languages : en Pages : 626
Book Description
The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress. Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration. Features of this book: • Gives a comprehensive in-depth survey of a rarely-reviewed subject. • Reviews methods used in studies of thermal decompositions of solids. • Discusses patterns of subject development perceived from an extensive literature survey. This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.
Author: A.K. Galwey Publisher: Elsevier ISBN: 0080542794 Category : Science Languages : en Pages : 626
Book Description
The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress. Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration. Features of this book: • Gives a comprehensive in-depth survey of a rarely-reviewed subject. • Reviews methods used in studies of thermal decompositions of solids. • Discusses patterns of subject development perceived from an extensive literature survey. This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.
Author: Boris V. L'vov Publisher: Springer Science & Business Media ISBN: 1402056729 Category : Science Languages : en Pages : 254
Book Description
This book covers the results of investigations into the mechanisms and kinetics of thermal decompositions of solid and liquid substances on the basis of thermochemical analyses. The main features of these reactions are explained and many problems and unusual phenomena, which have accumulated in this field are interpreted. New methods of TA measurement and calculation have been developed, which permit the precision and accuracy of determination of kinetic parameters to be increased substantially.
Author: Jaroslav Sestak Publisher: Elsevier ISBN: 0323858112 Category : Science Languages : en Pages : 646
Book Description
Thermal Analysis and Thermodynamic Properties of Solids, Second Edition covers foundational principles and recent updates in the field, presenting an authoritative overview of theoretical knowledge and practical applications across several fields. Since the first edition of this book was published, large developments have occurred in the theoretical understanding of—and subsequent ability to assess and apply—principles of thermal analysis. Drawing on the knowledge of its expert author, this second edition provides fascinating insight for both new and experienced students, researchers, and industry professionals whose work is influenced or impacted by thermo analysis principles and tools. Part 1 provides a detailed introduction and guide to theoretical aspects of thermal analysis and the related impact of thermodynamics. Key terminology and concepts, the fundamentals of thermophysical examinations, thermostatics, equilibrium background, thermotics, reaction kinetics and models, thermokinetics and the exploitation of fractals are all discussed. Part 2 then goes on to discuss practical applications of this theoretical information to topics such as crystallization kinetics and glass states, thermodynamics in superconductor models, and climate change. Includes fully updated as well as new chapters on kinetic phase diagrams, thermokinetics in DTA experiments, and crystallization kinetics Discusses the influence of key derivatives such as thermostatics, thermodynamics, thermotics, and thermokinetics Helps readers understand and describe reaction kinetics in solids, both in terms of simplified descriptions of the reaction mechanism models and averaged descriptions using fractals
Author: H. Y. Sohn Publisher: Elsevier ISBN: 0128164662 Category : Science Languages : en Pages : 536
Book Description
Fluid-Solid Reactions, Second Edition takes a detailed and thorough look at the scope of fluid-solid reaction systems, focusing on the four phenomena: external mass transfer, pore diffusion, chemical reaction, and adsorption/desorption. This completely revised new edition builds on the classic original edition through the introduction of cutting-edge new theories and applications, including the formulation and application of a new and convenient law that governs fluid-solid reaction kinetics. This book will be of primary interest to practicing engineers engaged in process research, development, and design in the many fields where fluid-solid reactions are critical to workflow and research. Fluid-solid reactions play a major role in the technology of most industrialized nations. These reactions encompass a very broad field, including the extraction of metals from their ores, the combustion of solid fuels, coal gasification, and the incineration of solid refuse. Features 50% new and revised content, arming researchers with the latest developments in the field Details a new unified approach to modeling the rates of fluid-solid reaction systems Authored by one of the world’s foremost experts on fluid-solid reactions and their applications in the field
Author: James E. House Publisher: Elsevier ISBN: 0443134294 Category : Technology & Engineering Languages : en Pages : 350
Book Description
Introduction to Solid State Chemistry provides a strong background to the structures of solids and factors that determine this structure. The content presented will also stress transformations of solids both in physical forms and chemical composition. In so doing, topics such as phase transitions, sintering, reactions of coordination compounds, photovoltaic compounds are described, whilst kinetics and mechanisms of solid state reactions are covered in depth. There are currently few books that deal with solid state chemistry, where a considerable number instead deal with solid state physics and materials science/engineering. This book provides someone needing or wishing to learn about the chemistry of solids a comprehensive resource that describes structures of solids, the behaviour of solids under applied stresses, the types of reactions that solids undergo, and the phenomenological aspects of reactions in solids. Kinetics of reactions in solids is very seldom covered in current literature and an understanding of the mechanisms of reactions in solids is necessary for many applications. James E. House provides a balanced treatment of structure, dynamics, and behaviour of solids at a level commensurate with upper-level undergraduates or beginning graduate students who wish to obtain an introduction and overview to solid state chemistry. Provides a?fundamental introduction and entry point to solid state chemistry, acting as a useful prerequisite for further learning in the area Presents a balanced approach that not only emphasizes structures of solids but also provides information on reactions of solids and how they occur Gives much-needed focus to the kinetics of reactions of solids and their mechanisms where existing literature covers little of this Explores crucial solid state chemistry topics such as solar energy conversion, reactions of solid coordination compounds, diffusion, sintering, and other transformations of solids Features accessible and well-written examples and case studies featuring many new and bespoke supporting illustrations, offering an excellent framework that will help students to understand reaction mechanisms
Author: United States. Air Force. Directorate of Chemical and Atmospheric Sciences Publisher: ISBN: Category : Atmospheric chemistry Languages : en Pages : 248
Author: L. D. Whipple Publisher: ISBN: Category : Chemistry Languages : en Pages : 248
Book Description
The purpose of this book is to provide an overall view of the Chemistry program of the Directorate of Chemical Sciences, Air Force Office of Scientific Research.
Author: Peter Atkins Publisher: Oxford University Press, USA ISBN: 0199236178 Category : Science Languages : en Pages : 852
Book Description
Inorganic Chemistry fifth edition represents an integral part of a student's chemistry education. Basic chemical principles are set out clearly in 'Foundations' and are fully developed throughout the text, culminating in the cutting-edge research topics of the 'Frontiers', which illustrate the dynamic nature of inorganic chemistry.
Author: Imre Miklós Szilágyi Publisher: Springer ISBN: 3319094866 Category : Science Languages : en Pages : 372
Book Description
This is an expanded and revised second edition, presenting accurate and comprehensive information about our leading thermal scientists to current and future generations. In our globalized world, most researchers in thermal analysis do not know each other in person and are not familiar with each other’s achievements. This volume provides the reader with an up-to-date list of the prominent members in this community. The publication contains only living scientists. The selection is based partly on several decades of the editors' personal professional experience and also partly on the opinion of the Regional Editors of the Journal of Thermal Analysis and Calorimetry.