Author: Jeffrey Huw Williams
Publisher: Morgan & Claypool Publishers
ISBN: 1643272926
Category : Science
Languages : en
Pages : 146
Book Description
It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.
The Molecule as Meme
Author: Jeffrey Huw Williams
Publisher: Morgan & Claypool Publishers
ISBN: 1643272926
Category : Science
Languages : en
Pages : 146
Book Description
It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.
Publisher: Morgan & Claypool Publishers
ISBN: 1643272926
Category : Science
Languages : en
Pages : 146
Book Description
It was not until 1971 that the authority for defining scientific units, the General Conference of Weights and Measures got around to defining the unit that is the basis of chemistry (the mole, or the quantity of something). Yet for all this tardiness in putting the chemical sciences on a sound quantitative basis, chemistry is an old and venerable subject and one naturally asks the question, why? Well, the truth is that up until the mid-1920s, many physicists did not believe in the reality of molecules. Indeed, it was not until after the physics community had accepted Ernest Rutherford's 1913 solar-system-like model of the atom, and the quantum mechanical model of the coupling of electron spins in atoms that physicists started to take seriously the necessity of explaining the chemical changes that chemists had been observing, investigating and recording since the days of the alchemists.
Crystal Optics with Spatial Dispersion, and Excitons
Author: Vladimir M. Agranovich
Publisher: Springer Science & Business Media
ISBN: 3662024063
Category : Science
Languages : en
Pages : 454
Book Description
Spatial dispersion, namely, the dependence of the dielectric-constant tensor on the wave vector (i.e., on the wavelength) at a fixed frequency, is receiving increased attention in electrodynamics and condensed-matter optics, partic ularly in crystal optics. In contrast to frequency dispersion, namely, the frequency dependence of the dielectric constant, spatial dispersion is of interest in optics mainly when it leads to qualitatively new phenomena. One such phenomenon has been weH known for many years; it is the natural optical activity (gyrotropy). But there are other interesting effects due to spatial dispersion, namely, new normal waves near absorption lines, optical anisotropy of cubic crystals, and many others. Crystal optics that takes spatial dispersion into account includes classical crystal optics with frequency dispersion only, as a special case. In our opinion, this fact alone justifies efforts to develop crystal optics with spatial dispersion taken into account, although admittedly its influence is smaH in some cases and it is observable only under rather special conditions. Furthermore, spatial dispersion in crystal optics deserves attention from another point as well, namely, the investigation of excitons that can be excited by light. We contend that crystal optics with spatial dispersion and the theory of excitons are fields that overlap to a great extent, and that it is sometimes quite impossible to separate them. It is our aim to show the true interplay be tween these interrelations and to combine the macroscopic and microscopic approaches to crystal optics with spatial dispersion and exciton theory.
Publisher: Springer Science & Business Media
ISBN: 3662024063
Category : Science
Languages : en
Pages : 454
Book Description
Spatial dispersion, namely, the dependence of the dielectric-constant tensor on the wave vector (i.e., on the wavelength) at a fixed frequency, is receiving increased attention in electrodynamics and condensed-matter optics, partic ularly in crystal optics. In contrast to frequency dispersion, namely, the frequency dependence of the dielectric constant, spatial dispersion is of interest in optics mainly when it leads to qualitatively new phenomena. One such phenomenon has been weH known for many years; it is the natural optical activity (gyrotropy). But there are other interesting effects due to spatial dispersion, namely, new normal waves near absorption lines, optical anisotropy of cubic crystals, and many others. Crystal optics that takes spatial dispersion into account includes classical crystal optics with frequency dispersion only, as a special case. In our opinion, this fact alone justifies efforts to develop crystal optics with spatial dispersion taken into account, although admittedly its influence is smaH in some cases and it is observable only under rather special conditions. Furthermore, spatial dispersion in crystal optics deserves attention from another point as well, namely, the investigation of excitons that can be excited by light. We contend that crystal optics with spatial dispersion and the theory of excitons are fields that overlap to a great extent, and that it is sometimes quite impossible to separate them. It is our aim to show the true interplay be tween these interrelations and to combine the macroscopic and microscopic approaches to crystal optics with spatial dispersion and exciton theory.
Crystal Symmetries
Author: B. K. Vainshtein
Publisher: Elsevier
ISBN: 1483299104
Category : Science
Languages : en
Pages : 330
Book Description
Crystal Symmetries is a timely account of the progress in the most diverse fields of crystallography. It presents a broad overview of the theory of symmetry and contains state of the art reports of its modern directions and applications to crystal physics and crystal properties. Geometry takes a special place in this treatise. Structural aspects of phase transitions, correlation of structure and properties, polytypism, modulated structures, and other topics are discussed. Applications of important techniques, such as X-ray crystallography, biophysical studies, EPR spectroscopy, crystal optics, and nuclear solid state physics, are represented. Contains 30 research and review papers.
Publisher: Elsevier
ISBN: 1483299104
Category : Science
Languages : en
Pages : 330
Book Description
Crystal Symmetries is a timely account of the progress in the most diverse fields of crystallography. It presents a broad overview of the theory of symmetry and contains state of the art reports of its modern directions and applications to crystal physics and crystal properties. Geometry takes a special place in this treatise. Structural aspects of phase transitions, correlation of structure and properties, polytypism, modulated structures, and other topics are discussed. Applications of important techniques, such as X-ray crystallography, biophysical studies, EPR spectroscopy, crystal optics, and nuclear solid state physics, are represented. Contains 30 research and review papers.
Physical Properties of Crystals
Author: J. F. Nye
Publisher: Oxford University Press
ISBN: 9780198511656
Category : Mathematics
Languages : en
Pages : 356
Book Description
First published in 1957, this classic study has been reissued in a paperback version that includes an additional chapter bringing the material up to date. The author formulates the physical properties of crystals systematically in tensor notation, presenting tensor properties in terms of their common mathematical basis and the thermodynamic relations between them. The mathematical groundwork is laid in a discussion of tensors of the first and second ranks. Tensors of higher ranks and matrix methods are then introduced as natural developments of the theory. A similar pattern is followed in discussing thermodynamic and optical aspects.
Publisher: Oxford University Press
ISBN: 9780198511656
Category : Mathematics
Languages : en
Pages : 356
Book Description
First published in 1957, this classic study has been reissued in a paperback version that includes an additional chapter bringing the material up to date. The author formulates the physical properties of crystals systematically in tensor notation, presenting tensor properties in terms of their common mathematical basis and the thermodynamic relations between them. The mathematical groundwork is laid in a discussion of tensors of the first and second ranks. Tensors of higher ranks and matrix methods are then introduced as natural developments of the theory. A similar pattern is followed in discussing thermodynamic and optical aspects.
Volume 25: Optical Methods of Investigating Solid Bodies
Author: D. V. Skobel tsyn
Publisher: Springer Science & Business Media
ISBN: 1468472062
Category : Science
Languages : en
Pages : 189
Book Description
The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3' SbP3' As 0 - SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3' Ge02' Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3' Ge02' Te02 are simi lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td' The force constants and vibration fre 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated.
Publisher: Springer Science & Business Media
ISBN: 1468472062
Category : Science
Languages : en
Pages : 189
Book Description
The principal results of the work are as follows: 1. A simplified technique was devised for obtaining Raman spectra of powders. 2. The Raman and infrared absorption spectra of the following oxides were investigated: AsP3' SbP3' As 0 - SbP5. Te02. Ge02 (two forms) in the crystalline state, and ASP3' Ge02' Te0 in the glassy state. 2 5 2 3. The vibrational spectra of the crystalline and glassy forms of the oxides ASP3' Ge02' Te02 are simi lar in many main respects, indicating a similarity of their structural units which determine the vibrational spec tra of these substances. 4. By a study of the vibrational spectrum it was shown that arsenious anhydride has a molecular structure and consists of As0 molecules having symmetry of the point group Td' The force constants and vibration fre 4 6 quencies of the As 0 molecule were calculated. and the vibrational spectrum of arsenious anhydride was re 4 6 liably interpreted with the aid of these results. 5. A similar result was obtained for antimonous anhydride. consisting of Sb0 molecule.s with symmetry 4 6 ofthe point group Td. The force constants for this molecule were found and the vibrational spectrum was calculated.
Chiral Analysis
Author: Kenneth W. Busch
Publisher: Elsevier
ISBN: 0080469280
Category : Science
Languages : en
Pages : 721
Book Description
Chiral Analysis covers an important area of analytical chemistry of relevance to a wide variety of scientific professionals. The target audience is scientific professionals with an undergraduate background in chemistry or a related discipline, specifically organic chemists, researchers in drug discovery, pharmaceutical researchers involved with process analysis or combinatorial libraries, and graduate students in chemistry. Chapters have been written with the nonspecialist in mind so as to be self-contained.* Broad coverage - spectroscopic and separation methods covered in a single volume* Up-to-date and detailed review of the various techniques available and/or under development in this field* Contributions from leading experts in the field
Publisher: Elsevier
ISBN: 0080469280
Category : Science
Languages : en
Pages : 721
Book Description
Chiral Analysis covers an important area of analytical chemistry of relevance to a wide variety of scientific professionals. The target audience is scientific professionals with an undergraduate background in chemistry or a related discipline, specifically organic chemists, researchers in drug discovery, pharmaceutical researchers involved with process analysis or combinatorial libraries, and graduate students in chemistry. Chapters have been written with the nonspecialist in mind so as to be self-contained.* Broad coverage - spectroscopic and separation methods covered in a single volume* Up-to-date and detailed review of the various techniques available and/or under development in this field* Contributions from leading experts in the field
The Molecular Basis of Optical Activity
Author: Elliot Charney
Publisher: Krieger Publishing Company
ISBN:
Category : Science
Languages : en
Pages : 392
Book Description
Publisher: Krieger Publishing Company
ISBN:
Category : Science
Languages : en
Pages : 392
Book Description
Opticals Effects in Liquid Crystals
Author: I. Jánossy
Publisher: Springer Science & Business Media
ISBN: 9401131805
Category : Science
Languages : en
Pages : 242
Book Description
In 1988 physicists and chemists commemorated the centenary of the discovery of the first liquid crystals. Fora long period after this discovery, although many significant results were found, liquid crystal research remained a marginal topic of condensed matter physics. The situation changed in the sixties. At that time the remarkable electro-optical properties of liquid crystals were recognized and found soon widespread application in numeric displays. From a more fundamental point of view, the interest in disordered systems. increased in general at the same time. Liquid crystals represented an important dass of such systems. Among others, phase transitions, hydrodynamics and topological defects occurring in them attracted considerable attention. The connection between the liquid-crystalline state and the structure of biological membranes stimulated a Iot of works also. In the present volume we discuss a relatively new and rapidly developing branch of the fi. eld, namely nonlinear optical effects in liquid crystals. Optical studies have always played a signifi. cant role in liquid crystal science. Research of optical nonlinearities in liquid crystals began at the end of the sixties. Since then it became a powerful tool in the investigation of symmetry properties, interfacial phenomena or dynamic behaviour. Furthermore, several new aspects of nonlinear processes were demonstrated and studied extensively in liquid crystals. The subject covered in this book is therefore of importance both for liquid crystal research and for nonlinear optics itself. The term "nonlinear optics" is used here in a broad sense.
Publisher: Springer Science & Business Media
ISBN: 9401131805
Category : Science
Languages : en
Pages : 242
Book Description
In 1988 physicists and chemists commemorated the centenary of the discovery of the first liquid crystals. Fora long period after this discovery, although many significant results were found, liquid crystal research remained a marginal topic of condensed matter physics. The situation changed in the sixties. At that time the remarkable electro-optical properties of liquid crystals were recognized and found soon widespread application in numeric displays. From a more fundamental point of view, the interest in disordered systems. increased in general at the same time. Liquid crystals represented an important dass of such systems. Among others, phase transitions, hydrodynamics and topological defects occurring in them attracted considerable attention. The connection between the liquid-crystalline state and the structure of biological membranes stimulated a Iot of works also. In the present volume we discuss a relatively new and rapidly developing branch of the fi. eld, namely nonlinear optical effects in liquid crystals. Optical studies have always played a signifi. cant role in liquid crystal science. Research of optical nonlinearities in liquid crystals began at the end of the sixties. Since then it became a powerful tool in the investigation of symmetry properties, interfacial phenomena or dynamic behaviour. Furthermore, several new aspects of nonlinear processes were demonstrated and studied extensively in liquid crystals. The subject covered in this book is therefore of importance both for liquid crystal research and for nonlinear optics itself. The term "nonlinear optics" is used here in a broad sense.
tudes on Theoretical Physics
Author: Leonid M. Barkovsky
Publisher: World Scientific
ISBN: 9789812702296
Category : Science
Languages : en
Pages : 408
Book Description
- A collection of papers spanning decades and touching on a wide variety of research topics on modern theoretical physics written by leading scientists from the Belarusian State University bull; Provides concise information about the methods and applicati.
Publisher: World Scientific
ISBN: 9789812702296
Category : Science
Languages : en
Pages : 408
Book Description
- A collection of papers spanning decades and touching on a wide variety of research topics on modern theoretical physics written by leading scientists from the Belarusian State University bull; Provides concise information about the methods and applicati.
Vibrational Optical Activity
Author: Laurence A. Nafie
Publisher: John Wiley & Sons
ISBN: 1119977533
Category : Science
Languages : en
Pages : 373
Book Description
This unique book stands as the only comprehensive introduction to vibrational optical activity (VOA) and is the first single book that serves as a complete reference for this relatively new, but increasingly important area of molecular spectroscopy. Key features: A single-source reference on this topic that introduces, describes the background and foundation of this area of spectroscopy. Serves as a guide on how to use it to carry out applications with relevant problem solving. Depth and breadth of the subject is presented in a logical, complete and progressive fashion. Although intended as an introductory text, this book provides in depth coverage of this topic relevant to both students and professionals by taking the reader from basic theory through to practical and instrumental approaches.
Publisher: John Wiley & Sons
ISBN: 1119977533
Category : Science
Languages : en
Pages : 373
Book Description
This unique book stands as the only comprehensive introduction to vibrational optical activity (VOA) and is the first single book that serves as a complete reference for this relatively new, but increasingly important area of molecular spectroscopy. Key features: A single-source reference on this topic that introduces, describes the background and foundation of this area of spectroscopy. Serves as a guide on how to use it to carry out applications with relevant problem solving. Depth and breadth of the subject is presented in a logical, complete and progressive fashion. Although intended as an introductory text, this book provides in depth coverage of this topic relevant to both students and professionals by taking the reader from basic theory through to practical and instrumental approaches.