The Variational Theory of Classical Liquids and Liquid Mixtures PDF Download

Author: Brian Norman Perry
Publisher:
ISBN:
Category : Argon
Languages : en
Pages :

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Author: Jean-Pierre Hansen
Publisher: Academic Press
ISBN: 012387033X
Category : Science
Languages : en
Pages : 637

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Book Description
Comprehensive coverage of topics in the theory of classical liquids Widely regarded as the standard text in its field, Theory of Simple Liquids gives an advanced but self-contained account of liquid state theory within the unifying framework provided by classical statistical mechanics. The structure of this revised and updated Fourth Edition is similar to that of the previous one but there are significant shifts in emphasis and much new material has been added. Major changes and Key Features in content include: - Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchical reference theory of criticality, and the dynamics of super-cooled liquids. - New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. - An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation. - Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchian reference of criticality, and the dynamics of super-cooled liquids. - New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. - An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation.

Author: Andrés Santos
Publisher: Springer
ISBN: 331929668X
Category : Science
Languages : en
Pages : 299

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This short primer offers non-specialist readers a concise, yet comprehensive introduction to the field of classical fluids – providing both fundamental information and a number of selected topics to bridge the gap between the basics and ongoing research. In particular, hard-sphere systems represent a favorite playground in statistical mechanics, both in and out of equilibrium, as they represent the simplest models of many-body systems of interacting particles, and at higher temperature and densities they have proven to be very useful as reference systems for real fluids. Moreover, their usefulness in the realm of soft condensed matter has become increasingly recognized – for instance, the effective interaction among (sterically stabilized) colloidal particles can be tuned to almost perfectly match the hard-sphere model. These lecture notes present a brief, self-contained overview of equilibrium statistical mechanics of classical fluids, with special applications to both the structural and thermodynamic properties of systems made of particles interacting via the hard-sphere potential or closely related model potentials. In particular it addresses the exact statistical-mechanical properties of one-dimensional systems, the issue of thermodynamic (in)consistency among different routes in the context of several approximate theories, and the construction of analytical or semi-analytical approximations for the structural properties. Written pedagogically at the graduate level, with many figures, tables, photographs, and guided end-of-chapter exercises, this introductory text benefits students and newcomers to the field alike.

Author: J S Rowlinson
Publisher: Butterworth-Heinemann
ISBN: 1483140679
Category : Science
Languages : en
Pages : 337

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Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynamics of and inequalities at the critical point; measurement of thermodynamic functions in the critical region; experimental values of the critical exponents; and scaling of the free energy. The change of thermodynamic functions with composition is the subject of the next two chapters, followed by an analysis of fluid mixtures at high pressures. The final chapter is devoted to the statistical thermodynamics of fluids and mixtures, paying particular attention to the thermodynamic properties in terms of the forces between the molecules; the balance of intermolecular potentials between like and unlike molecules; and phase behavior. This monograph will be of interest to students and researchers in the fields of chemistry and chemical engineering.

Author: Jean-Pierre Hansen
Publisher: Elsevier
ISBN: 0080455077
Category : Science
Languages : en
Pages : 430

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Book Description
The third edition of Theory of Simple Liquids is an updated, advanced, but self-contained introduction to the principles of liquid-state theory. It presents the modern, molecular theory of the structural, thermodynamic interfacial and dynamical properties of the liquid phase of materials constituted of atoms, small molecules or ions. This book leans on concepts and methods form classical Statistical Mechanics in which theoretical predictions are systematically compared with experimental data and results from numerical simulations. The overall layout of the book is similar to that of the previous two editions however, there are considerable changes in emphasis and several key additions including:•up-to-date presentation of modern theories of liquid-vapour coexistence and criticality•areas of considerable present and future interest such as super-cooled liquids and the glass transition•the area of liquid metals, which has grown into a mature subject area, now presented as part of the chapter ionic liquids•Provides cutting-edge research in the principles of liquid-state theory•Includes frequent comparisons of theoretical predictions with experimental and simulation data•Suitable for researchers and post-graduates in the field of condensed matter science (Physics, Chemistry, Material Science), biophysics as well as those in the oil industry

Author: John Shipley Rowlinson
Publisher:
ISBN:
Category : Liquids
Languages : en
Pages : 396

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Author: Jean-Pierre Hansen
Publisher: Elsevier
ISBN: 0080571018
Category : Science
Languages : en
Pages : 569

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This book gives a comprehensive and up-to-date treatment of the theory of "simple" liquids. The new second edition has been rearranged and considerably expanded to give a balanced account both of basic theory and of the advances of the past decade. It presents the main ideas of modern liquid state theory in a way that is both pedagogical and self-contained. The book should be accessible to graduate students and research workers, both experimentalists and theorists, who have a good background in elementary mechanics. - Compares theoretical deductions with experimental results - Molecular dynamics - Monte Carlo computations - Covers ionic, metallic, and molecular liquids

Author: G. A. Martynov
Publisher: CRC Press
ISBN:
Category : Art
Languages : en
Pages : 500

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Book Description
This monograph concentrates on the statistical mechanics of fluid systems in equilibrium. The approach is classical. It shows how macroscopic properties of matter (structure, thermodynamic) can be calculated ab initio from knowledge of a few microscopic quantities. Dealing predominantly with liquids, the treatment of gases is included as a specific example. Accessible to both experimentalists & theorists, chapters can be referred to independently making this a useful handbook. A valuable monograph for postgraduate students & researchers in the fields of statistical physics, physical chemistry, chemical engineering & theoretical chemistry.

Author: Max Born
Publisher: CUP Archive
ISBN:
Category :
Languages : en
Pages : 116

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Author: C. Hoheisel
Publisher: Elsevier Publishing Company
ISBN: 9780444898357
Category : Science
Languages : en
Pages : 362

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Book Description
This book discusses the thermodynamic and structural properties as well as the transport processes of liquids and liquid mixtures. It provides an exhaustive account of current theoretical methods to treat static and dynamic behaviour of liquid systems and compares results obtained with different theoretical approximations and computer calculations. A thorough comparison of results available from computer calculations and various theoretical approximations is also presented. Particular emphasis is placed on the discussion of binary mixtures, while transport processes of molecular liquids are dealt with at length. Part A of this monograph deals with the static properties of liquids, while Part B treats the dynamic properties and transport coefficients of liquid systems. All essential results are explained using very clear plots and diagrams and additional tables contribute to the presentation of the topics covered. All scientists working in the field of thermodynamics and transport of liquids and dense gases will welcome this book.