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The Uranium Isotope Paleoredox Proxy

The Uranium Isotope Paleoredox Proxy PDF Author: Kimberly V. Lau
Publisher: Cambridge University Press
ISBN: 1108605249
Category : Science
Languages : en
Pages : 57

Book Description
Uranium isotopes (238U/235U) have emerged as a proxy to reconstruct the redox conditions of the Earth's oceans and atmosphere based upon the large isotopic fractionation between reduced U(IV) and oxidized U(VI). Variations in 238U/235U, particularly when recorded in carbonate sediments, can track global trends in marine oxygenation and de-oxygenation. It is unique from other proxies because reduction primarily occurs at the sediment-water interface, and this sensitivity makes U isotopes especially relevant for the habitability of benthic animals. This Element covers the background, methods, and case studies of this promising tool for understanding Earth's environmental transitions, as rapid development continues to refine the accuracy of interpretations of 238U/235U records.

The Uranium Isotope Paleoredox Proxy

The Uranium Isotope Paleoredox Proxy PDF Author: Kimberly V. Lau
Publisher: Cambridge University Press
ISBN: 1108605249
Category : Science
Languages : en
Pages : 57

Book Description
Uranium isotopes (238U/235U) have emerged as a proxy to reconstruct the redox conditions of the Earth's oceans and atmosphere based upon the large isotopic fractionation between reduced U(IV) and oxidized U(VI). Variations in 238U/235U, particularly when recorded in carbonate sediments, can track global trends in marine oxygenation and de-oxygenation. It is unique from other proxies because reduction primarily occurs at the sediment-water interface, and this sensitivity makes U isotopes especially relevant for the habitability of benthic animals. This Element covers the background, methods, and case studies of this promising tool for understanding Earth's environmental transitions, as rapid development continues to refine the accuracy of interpretations of 238U/235U records.

The Iron Speciation Paleoredox Proxy

The Iron Speciation Paleoredox Proxy PDF Author: Simon W. Poulton
Publisher: Cambridge University Press
ISBN: 1108848591
Category : Science
Languages : en
Pages : 34

Book Description
In one form or another, iron speciation has had a long history as a paleoredox proxy. The technique has been refined considerably over the years, and the most recent scheme is unique in its potential to distinguish three major oceanic redox states - oxygenated, ferruginous and euxinic. This Element covers the theory behind the proxy, methods involved in applying the technique, and potential complications in interpreting Fe speciation data. A series of case studies are also provided, which highlight how more advanced consideration of the data, often in concert with other techniques, can provide unprecedented insight into the redox state of ancient oceans.

Large Igneous Provinces

Large Igneous Provinces PDF Author: Richard E. Ernst
Publisher: Cambridge University Press
ISBN: 1316060519
Category : Science
Languages : en
Pages : 667

Book Description
Large igneous provinces (LIPs) are intraplate magmatic events, involving volumes of mainly mafic magma upwards of 100,000 km3, and often above 1 million km3. They are linked to continental break-up, global environmental catastrophes, regional uplift and a variety of ore deposit types. In this up-to-date, fascinating book, leading expert Richard E. Ernst explores all aspects of LIPs, beginning by introducing their definition and essential characteristics. Topics covered include continental and oceanic LIPs; their origins, structures, and geochemistry; geological and environmental effects; association with silicic, carbonatite and kimberlite magmatism; and analogues of LIPs in the Archean, and on other planets. The book concludes with an assessment of LIPs' influence on natural resources such as mineral deposits, petroleum and aquifers. This is a one-stop resource for researchers and graduate students in a wide range of disciplines, including tectonics, igneous petrology, geochemistry, geophysics, Earth history, and planetary geology, and for mining industry professionals.

Molybdenum as a Paleoredox Proxy

Molybdenum as a Paleoredox Proxy PDF Author: Stephan R. Hlohowskyj
Publisher: Cambridge University Press
ISBN: 1009002260
Category : Science
Languages : en
Pages : 57

Book Description
Molybdenum (Mo) is a widely used trace metal for investigating redox conditions. However, unanswered questions remain that concentration and bulk isotopic analysis cannot specially answer. Improvements can be made by combining new geochemical techniques to traditional methods of Mo analysis. In this Element, we propose a refinement of Mo geochemistry within aquatic systems, ancient rocks, and modern sediments through molecular geochemistry (systematically combining concentration, isotope ratio, elemental mapping, and speciation analyses). Specifically, to intermediate sulfide concentrations governing Mo behavior below the 'switch-point' and dominant sequestration pathways in low oxygen conditions. The aim of this work is to 1) aid and improve the breadth of Mo paleoproxy interpretations by considering Mo speciation and 2) address outstanding research gaps concerning Mo systematics (cycling, partitioning, sequestration, etc.). The Mo paleoproxy has potential to solve ever complex research questions. By using molecular geochemical recommendations, improved Mo paleoproxy interpretations and reconstruction can be achieved.

Vanadium Isotopes

Vanadium Isotopes PDF Author: Sune G. Nielsen
Publisher: Cambridge University Press
ISBN: 9781108797948
Category : Science
Languages : en
Pages : 75

Book Description
Vanadium isotope ratios (51V/50V) have potential to provide information about changes in past ocean oxygen contents. In particular, V isotopes may find utility in tracing variations at non-zero oxygen concentrations because the redox couple that controls V elemental and isotopic abundances in seawater (vanadate-vanadyl) appears to operate around 10M O2. This characteristic sets V isotopes apart from many other metal isotope redox proxies that require more reducing conditions to register significant changes in their isotope budgets. The oxygen abundance sensitivity range of V isotopes suggests that this paleoproxy could be particularly useful in tracing marine oxygenation changes throughout the Phanerozoic and potentially beyond.

Stable Isotope Geochemistry

Stable Isotope Geochemistry PDF Author: Jochen Hoefs
Publisher: Springer Science & Business Media
ISBN: 3662033771
Category : Science
Languages : en
Pages : 333

Book Description
Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the fields of geoscience. It is subdivided into three parts: - theoretical and experimental principles; - fractionation mechanisms of light elements; - the natural variations of geologically important reservoirs. In this updated 4th edition many of the chapters have been expanded, especially those on techniques and environmental aspects. The main focus is on recent results and new developments. For students and scientists alike the book will be a primary reference with regard to how and where stable isotopes can be used to solve geological problems.

Modern and Ancient Continental Shelf Anoxia

Modern and Ancient Continental Shelf Anoxia PDF Author: Richard V. Tyson
Publisher: Geological Society Publishing House
ISBN:
Category : Nature
Languages : en
Pages : 490

Book Description


Earth History of Oxygen and the iprOxy

Earth History of Oxygen and the iprOxy PDF Author: Zunli Lu
Publisher: Cambridge University Press
ISBN: 1009028413
Category : Science
Languages : en
Pages : 49

Book Description
How oxygen levels in Earth's atmosphere and oceans evolved has always been a central question in Earth System Science. Researchers have developed numerous tracers to tackle this question, utilizing geochemical characteristics of different elements. Iodine incorporated in calcium carbonate (including biogenic) minerals, reported as I/Ca, is a proxy for dissolved oxygen in seawater. Here we review the rationale behind this proxy, its recent applications and some potential future research directions.

Micro-XRF Studies of Sediment Cores

Micro-XRF Studies of Sediment Cores PDF Author: Ian W. Croudace
Publisher: Springer
ISBN: 9401798494
Category : Science
Languages : en
Pages : 668

Book Description
This volume presents papers on the use of micro-XRF core scanners in palaeoenvironmental research. It contains a broad ranging view of instrument capability and points to future developments that will help contribute to higher precision elemental data and faster core analysis. Readers will find a diverse range of research by leading experts that have used micro-XRF core scanners in a wide range of scientific applications. The book includes specific application papers reporting on the use of XRF core scanners in a variety of marine, lacustrine, and pollution studies. In addition, coverage also examines practical aspects of core scanner usage, data optimisation and data calibration and interpretation. In a little over a decade, micro-XRF sediment core scanners have made a substantive contribution to palaeoenvironmental research. Their impact is based on their ability to rapidly, non-destructively and automatically scan sediment cores. Not only do they rapidly provide important proxy data without damaging samples, but they can obtain environmental data at decadal, annual and even sub-annual scales. This volume will help both experienced and new users of these non-destructive core scanners take full advantage of one of the most powerful geochemical screening tools in the environmental scientist's toolbox.

Non-Traditional Stable Isotopes

Non-Traditional Stable Isotopes PDF Author: Fang-Zhen Teng
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110545632
Category : Science
Languages : en
Pages : 902

Book Description
The development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.