Author: B. R. PhillipsPublisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The Thermal Decomposition of Inorganic Solids
Author: B. R. PhillipsThermal Decomposition of Inorganic Solids
Author: Brian Ross PhillipsHigh Temperature Properties and Thermal Decomposition of Inorganic Salts with Oxyanions
Author: Kurt H. SternPublisher: CRC Press
ISBN: 9780849302565
Category : Science
Languages : en
Pages : 30
Book Description
Twenty years ago author Kurt Stern produced four monographs for the National Bureau of Standards on the high-temperature properties of inorganic salts containing oxyanions. Although relied upon by scientists and engineers around the world, these monographs have now become increasingly difficult to access and increasingly outdated. High Temperature Properties and Thermal Decomposition of Inorganic Salts with Oxyanions unifies, expands upon, and brings up-to-date those standard-setting documents. It offers both qualitative and quantitative information on the behavior and properties of approximately 300 compounds, complete with thermodynamic tables of decomposition equilibria and information regarding decomposition kinetics. For each class of compounds, an existence chart in the form of a periodic table tells you at a glance which compounds are known to exist, those whose existence is uncertain, and those about which nothing is known. Supplementary tables give information about phase transitions and densities in both solid and liquid phases. Within this single volume, the author provides a comprehensive, critical review of the high-temperature properties of all the major classes of inorganic salts with oxyanions. If you work with materials or processes that involve salts at elevated temperatures, you now have an authoritative resource that obviates the need to perform extensive literature searches, data evaluations, and thermodynamic calculations-and saves you time.
Studies of the Thermal Decomposition of Solids with Special References to Inorganic Complexes
Author: M A. HughesThermal Decomposition of Ionic Solids
Author: A.K. GalweyPublisher: Elsevier
ISBN: 0080542794
Category : Science
Languages : en
Pages : 626
Book Description
The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress. Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration. Features of this book: • Gives a comprehensive in-depth survey of a rarely-reviewed subject. • Reviews methods used in studies of thermal decompositions of solids. • Discusses patterns of subject development perceived from an extensive literature survey. This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.
Thermal Decomposition of Solids and Melts
Author: Boris V. L'vovPublisher: Springer Science & Business Media
ISBN: 1402056729
Category : Science
Languages : en
Pages : 254
Book Description
This book covers the results of investigations into the mechanisms and kinetics of thermal decompositions of solid and liquid substances on the basis of thermochemical analyses. The main features of these reactions are explained and many problems and unusual phenomena, which have accumulated in this field are interpreted. New methods of TA measurement and calculation have been developed, which permit the precision and accuracy of determination of kinetic parameters to be increased substantially.
Changes in Thermal, Photo, and Radiation Stabilities of Solid Inorganic Compounds
Author: Yu A. ZakharovPublisher:
ISBN:
Category :
Languages : en
Pages : 40
Book Description
The Russian review examines the decomposition of inorganic solids, especially salts, and the changes in decomposition rates and mechanisms induced by various external factors, including donor-acceptor action, catalytic impurities, electromagnetic fields, and light. Emphasis is on thermal decomposition processes. Included are 149 references.
The Effects of Inorganic Solids and Certain Gases on the Thermal Decomposition of Catechol
Author: Jerome Apilan RoblesKinetics of Thermal Decomposition of Solids
Author: G. A. RazumovPublisher:
ISBN:
Category :
Languages : en
Pages : 19
Book Description
It is shown that Yerofeyev's equation, which is commonly used for practical purposes, cannot correctly describe the process of thermal decomposition of inorganic crystals, since it applies only to the case of a reaction in a coninuous medium, when the nuclei are formed in the volume. During the thermal decomposition of crystals, the nuclei are formed only on their surface. A solution is given for the problem involving the calculation of the probability of the reaction at a given point of the solid and for the general case of a solid of any shape and for an arbitrary law of formation of nuclei not only on the surface of the solid but also in its volume. The exact solution obtained is analyzed in two limiting cases, and it is shown that the total activation energy depends not only on the nature of the substance, but also on the size and shape of the particles. The theory of similitude was used to find two dimensionless variables which determine the process of thermal decomposition. (Author).
Thermal Analysis and Thermodynamic Properties of Solids
Author: Jaroslav SestakPublisher: Elsevier
ISBN: 0323858112
Category : Science
Languages : en
Pages : 646
Book Description
Thermal Analysis and Thermodynamic Properties of Solids, Second Edition covers foundational principles and recent updates in the field, presenting an authoritative overview of theoretical knowledge and practical applications across several fields. Since the first edition of this book was published, large developments have occurred in the theoretical understanding of—and subsequent ability to assess and apply—principles of thermal analysis. Drawing on the knowledge of its expert author, this second edition provides fascinating insight for both new and experienced students, researchers, and industry professionals whose work is influenced or impacted by thermo analysis principles and tools. Part 1 provides a detailed introduction and guide to theoretical aspects of thermal analysis and the related impact of thermodynamics. Key terminology and concepts, the fundamentals of thermophysical examinations, thermostatics, equilibrium background, thermotics, reaction kinetics and models, thermokinetics and the exploitation of fractals are all discussed. Part 2 then goes on to discuss practical applications of this theoretical information to topics such as crystallization kinetics and glass states, thermodynamics in superconductor models, and climate change. Includes fully updated as well as new chapters on kinetic phase diagrams, thermokinetics in DTA experiments, and crystallization kinetics Discusses the influence of key derivatives such as thermostatics, thermodynamics, thermotics, and thermokinetics Helps readers understand and describe reaction kinetics in solids, both in terms of simplified descriptions of the reaction mechanism models and averaged descriptions using fractals