Author: Holger Bernhard FriedrichPublisher:
ISBN:
Category :
Languages : en
Pages : 598
Book Description
The Synthesis and Reactivity of Functionalised Alkyl Transition Metal Complexes
Author: Holger Bernhard FriedrichPublisher:
ISBN:
Category :
Languages : en
Pages : 598
Book Description
The Synthesis, Reactivity and Application of Functionalized Alkyl Transition Metal Complexes
Author: Yi-Hsien LiaoThe synthesis, reactivity and application of functionalized alkyl transition metal complexes
Author: I-Hsien LiaoThe Synthesis and Reactivity of Transition Metal Alkyl and Hydride Complexes
Author: Eric Grant ThalerPublisher:
ISBN:
Category : Organochromium compounds
Languages : en
Pages : 400
Book Description
Transition Metals in the Synthesis of Complex Organic Molecules
Author: Louis S. HegedusPublisher:
ISBN:
Category : Science
Languages : en
Pages : 488
Book Description
The third edition of Transition Metals in the Synthesis of Complex Organic Molecules is a comprehensive revision and significant expansion of the second edition. The clear and systematic approach to the formation, manipulation, and reactivity of organometallic complexes has been maintained. The book is divided into 10 chapters starting with general formalisms, electron counting, and basic principles of organometallic reaction mechanisms. The organic chemistry of transition metals is then presented by class of metal complex, with many examples of applications in the synthesis of complex natural products and pharmaceuticals. The book is ideal for advanced undergraduate and graduate students as well as all practicing synthetic organic chemists. It is written for organic chemists and offers an easy entry into the field of organotransition metal chemistry without requiring a background in inorganic chemistry.
Organometallic Chemistry
Author: Ian J S FairlambPublisher: Royal Society of Chemistry
ISBN: 184973769X
Category : Science
Languages : en
Pages : 253
Book Description
A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M3ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields.
Synthesis and Reactivity of Late Transition Metal Complexes Featuring a Bis(8-quinolyl)methylsilyl Ligand
Author: Preeyanuch SangtrirutnugulPublisher:
ISBN:
Category :
Languages : en
Pages : 684
Book Description
Transition Metal Reagents and Catalysts
Author: Jiro TsujiPublisher: John Wiley & Sons
ISBN: 9780471560272
Category : Science
Languages : en
Pages : 500
Book Description
Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Alkane Functionalization
Author: Armando J. L. PombeiroPublisher: John Wiley & Sons
ISBN: 111937880X
Category : Science
Languages : en
Pages : 680
Book Description
Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.
Synthesis and Reactivity Studies of Late Transition Metal Complexes Relevant to C-H Bond Activation and Functionalization
Author: Susan Kloek HansonPublisher:
ISBN:
Category : Chemical bonds
Languages : en
Pages : 334
Book Description