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Ions in Solution and their Solvation

Ions in Solution and their Solvation PDF Author: Yizhak Marcus
Publisher: John Wiley & Sons
ISBN: 1118889142
Category : Science
Languages : en
Pages : 308

Book Description
The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods

Ions in Solution and their Solvation

Ions in Solution and their Solvation PDF Author: Yizhak Marcus
Publisher: John Wiley & Sons
ISBN: 1118889142
Category : Science
Languages : en
Pages : 308

Book Description
The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods

Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents

Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents PDF Author: K. Burger
Publisher: Elsevier
ISBN: 0444597514
Category : Science
Languages : en
Pages : 269

Book Description
Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.

Ionic Solvation

Ionic Solvation PDF Author: GennadiÄ­ Alekseevich Krestov
Publisher: Prentice Hall
ISBN:
Category : Science
Languages : en
Pages : 368

Book Description
This comprehensive, widely-read anthology presents cogent and provocativearticles from differing political perspectives on major issues in post-World WarII America. The fourth edition is considerably expanded to include newselections on the AIDS epidemic, gay rights, the women's movement, and theClinton-Gore administration. In addition to articles by leading historians theeditors have chosen first-person accounts by participants in each of the issuesunder discussion, from Martin Luther King, Jr.'s "Letter from the BirminghamJail" to Al Gore's speech on environmentalism. With lively introductions to eachsection providing a context for the articles, this book helps students makesense of the tumultuous world of our time.

Part I, Spectoscopic Studies of Ionic Solvation. Part II, Gas Chromatographic Studies of Convulsant Tetrazoles

Part I, Spectoscopic Studies of Ionic Solvation. Part II, Gas Chromatographic Studies of Convulsant Tetrazoles PDF Author: Robert Gary Baum
Publisher:
ISBN:
Category : Lithium
Languages : en
Pages : 348

Book Description


Highlights in Solute-Solvent Interactions

Highlights in Solute-Solvent Interactions PDF Author: Wolfgang Linert
Publisher: Springer Science & Business Media
ISBN: 9783211837313
Category : Science
Languages : en
Pages : 236

Book Description
Most organic molecules retain their integrity when dissolved, and even though in such cases the effects exerted by solvents are, in the language of the coordination chemist, of the "outer sphere" kind, the choice of solvent can be critical to the successful outcome of an operation or preparation. Solubilities of reactants and products must be taken into account, and even if the organic principals in the reactions retain their integrity, many of the reagents are electrolytes, and their state of aggregation will affect their reactivity. In testifying to the importance of understanding solute-solvent interactions I draw attention to a large class of inorganic species for which the involvement in the chemical and physical properties by the solvent is even more deeply seated. It is comprised by the large body of metal atoms in low oxidation states for which solvent molecules intervene as reagents. At the same time, because the ions carry charges, the effects arising from outer sphere interactions are usually greater than they are for neutral molecules. To cite an example: when FeCb(s) is dissolved in water to form a dilute - say O. OlO- solution there is a complete reorganization of the coordination sphere of the cation. Whereas in the solid each cation is surrounded by six chloride ions, in the solution the dominant form is [Fe(H20)6]3+ followed by [Fe(H20)sCI]2+, [Fe(H20)4CI2]+, etc. in rapidly decreasing abundance.

The Chemical Physics of Solvation

The Chemical Physics of Solvation PDF Author: Revaz R. Dogonadze
Publisher:
ISBN: 9780444416995
Category : Ions
Languages : en
Pages : 555

Book Description


Spectroscopic Studies of Ionic Solvation in Nonaqueous Media

Spectroscopic Studies of Ionic Solvation in Nonaqueous Media PDF Author: Mark Shiel Greenberg
Publisher:
ISBN:
Category : Solvation
Languages : en
Pages : 330

Book Description


Ab Initio Molecular Dynamics

Ab Initio Molecular Dynamics PDF Author: Dominik Marx
Publisher: Cambridge University Press
ISBN: 1139477196
Category : Science
Languages : en
Pages : 503

Book Description
Ab initio molecular dynamics revolutionized the field of realistic computer simulation of complex molecular systems and processes, including chemical reactions, by unifying molecular dynamics and electronic structure theory. This book provides the first coherent presentation of this rapidly growing field, covering a vast range of methods and their applications, from basic theory to advanced methods. This fascinating text for graduate students and researchers contains systematic derivations of various ab initio molecular dynamics techniques to enable readers to understand and assess the merits and drawbacks of commonly used methods. It also discusses the special features of the widely used Car–Parrinello approach, correcting various misconceptions currently found in research literature. The book contains pseudo-code and program layout for typical plane wave electronic structure codes, allowing newcomers to the field to understand commonly used program packages and enabling developers to improve and add new features in their code.

Solvation Thermodynamics

Solvation Thermodynamics PDF Author: Arieh Y. Ben-Naim
Publisher: Springer Science & Business Media
ISBN: 1475765509
Category : Science
Languages : en
Pages : 253

Book Description
This book deals with a subject that has been studied since the beginning of physical chemistry. Despite the thousands of articles and scores of books devoted to solvation thermodynamics, I feel that some fundamen tal and well-established concepts underlying the traditional approach to this subject are not satisfactory and need revision. The main reason for this need is that solvation thermodynamics has traditionally been treated in the context of classical (macroscopic) ther modynamics alone. However, solvation is inherently a molecular pro cess, dependent upon local rather than macroscopic properties of the system. Therefore, the starting point should be based on statistical mechanical methods. For many years it has been believed that certain thermodynamic quantities, such as the standard free energy (or enthalpy or entropy) of solution, may be used as measures of the corresponding functions of solvation of a given solute in a given solvent. I first challenged this notion in a paper published in 1978 based on analysis at the molecular level. During the past ten years, I have introduced several new quantities which, in my opinion, should replace the conventional measures of solvation thermodynamics. To avoid confusing the new quantities with those referred to conventionally in the literature as standard quantities of solvation, I called these "nonconventional," "generalized," and "local" standard quantities and attempted to point out the advantages of these new quantities over the conventional ones.

Modern Physical Organic Chemistry

Modern Physical Organic Chemistry PDF Author: Eric V. Anslyn
Publisher: University Science Books
ISBN: 9781891389313
Category : Science
Languages : en
Pages : 1148

Book Description
In additionto covering thoroughly the core areas of physical organic chemistry -structure and mechanism - this book will escortthe practitioner of organic chemistry into a field that has been thoroughlyupdated.