The Preparation and Characterization of Highly Dispersed Supported Bimetallic Catalysts from Inorganic and Organometallic Molecular Precursors PDF Download

Author: Bert Donald Chandler
Publisher:
ISBN:
Category :
Languages : en
Pages : 576

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Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 698

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Author: Robert Rioux
Publisher: Springer Science & Business Media
ISBN: 0387980490
Category : Science
Languages : en
Pages : 531

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Book Description
This book is an excellent compilation of cutting-edge research in heterogeneous catalysis and related disciplines – surface science, organometallic catalysis, and enzymatic catalysis. In 23 chapters by noted experts, the volume demonstrates varied approaches using model systems and their successes in understanding aspects of heterogeneous catalysis, both metal- and metal oxide-based catalysis in extended single crystal and nanostructured catalytic materials. To truly appreciate the astounding advances of modern heterogeneous catalysis, let us first consider the subject from a historical perspective. Heterogeneous catalysis had its beginnings in England and France with the work of scientists such as Humphrey Davy (1778–1829), Michael Faraday (1791–1867), and Paul Sabatier (1854–1941). Sabatier postulated that surface compounds, si- lar to those familiar in bulk to chemists, were the intermediate species leading to catalytic products. Sabatier proposed, for example, that NiH moieties on a Ni sur- 2 face were able to hydrogenate ethylene, whereas NiH was not. In the USA, Irving Langmuir concluded just the opposite, namely, that chemisorbed surface species are chemically bound to surfaces and are unlike known molecules. These chemisorbed species were the active participants in catalysis. The equilibrium between gas-phase molecules and adsorbed chemisorbed species (yielding an adsorption isotherm) produced a monolayer by simple site-filling kinetics.

Author:
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ISBN:
Category : Dissertation abstracts
Languages : en
Pages : 848

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Author:
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ISBN:
Category : Chemistry
Languages : en
Pages : 1846

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Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.

Author: John H. Sinfelt
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 190

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Presents an account of the research on bimetallic catalysts. Focuses attention on the possibility of influencing the selectivity of chemical transformations on metal surfaces and preparing metal alloys in a highly dispersed state. Covers the validation and elucidation of the bimetallic cluster concept. Includes figures and tables.

Author: Michel Boudart
Publisher: Princeton University Press
ISBN: 1400853338
Category : Science
Languages : en
Pages : 241

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This book is a critical account of the principles of the kinetics of heterogeneous catalytic reactions in the light of recent developments in surface science and catalysis science. Originally published in 1984. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

Author: Daniel L. Fedlheim
Publisher: CRC Press
ISBN: 9780585404394
Category : Science
Languages : en
Pages : 348

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A state-of-the-art reference, Metal Nanoparticles offers the latest research on the synthesis, characterization, and applications of nanoparticles. Following an introduction of structural, optical, electronic, and electrochemical properties of nanoparticles, the book elaborates on nanoclusters, hyper-Raleigh scattering, nanoarrays, and several applications including single electron devices, chemical sensors, biomolecule sensors, and DNA detection. The text emphasizes how size, shape, and surface chemistry affect particle performance throughout. Topics include synthesis and formation of nanoclusters, nanosphere lithography, modeling of nanoparticle optical properties, and biomolecule sensors.

Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 754

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Author: David C Sherrington
Publisher: Royal Society of Chemistry
ISBN: 1847551963
Category : Science
Languages : en
Pages : 282

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The need to improve both the efficiency and environmental acceptability of industrial processes is driving the development of heterogeneous catalysts across the chemical industry, including commodity, specialty and fine chemicals and in pharmaceuticals and agrochemicals. Drawing on international research, Supported Catalysts and their Applications discusses aspects of the design, synthesis and application of solid supported reagents and catalysts, including supported reagents for multi-step organic synthesis; selectivity in oxidation catalysis; mesoporous molecular sieve catalysts; and the use of Zeolite Beta in organic reactions. In addition, the two discrete areas of heterogeneous catalysis (inorganic oxide materials and polymer-based catalysts) that were developing in parallel are now shown to be converging, which will be of great benefit to the whole field. Providing a snapshot of the state-of-the-art in this fast-moving field, this book will be welcomed by industrialists and researchers, particularly in the agrochemicals and pharmaceuticals industries.