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Author: Stanley Gerald Thompson Publisher: ISBN: Category : Americium Languages : en Pages : 18
Book Description
An isotope of the element with atomic number 97 has been discovered as a product of the helium-ion bombardment of americium. This isotope decays with the emission of alpha-particles of maximum energy 6.72 Mev (30 percent) and it emits lower energy alpha-particles of energies 6.55 Mev (53 percent) and 6.20 Mev (17 percent). The half-life of this isotope is 4.6 hours and it decays primarily by electron capture with about 0.1 percent branching decay by alpha-particle emission. The mass number is probably 243 as indicated by chemical separation of the alpha-particle and electron-capture daughters. The name berkelium, symbol Bk, is proposed for element 97. The chemical separation of element 97 from the target material and other reaction products was made by combinations of precipitation and ion exchange adsorption methods making use of its anticipated (III) and (IV) oxidation states and its position as a member of the actinide transition series. The distinctive chemical properties made use of in its separation and the equally distinctive decay properties of the particular isotope constitute the principal evidence for the new element.
Author: Stanley Gerald Thompson Publisher: ISBN: Category : Americium Languages : en Pages : 18
Book Description
An isotope of the element with atomic number 97 has been discovered as a product of the helium-ion bombardment of americium. This isotope decays with the emission of alpha-particles of maximum energy 6.72 Mev (30 percent) and it emits lower energy alpha-particles of energies 6.55 Mev (53 percent) and 6.20 Mev (17 percent). The half-life of this isotope is 4.6 hours and it decays primarily by electron capture with about 0.1 percent branching decay by alpha-particle emission. The mass number is probably 243 as indicated by chemical separation of the alpha-particle and electron-capture daughters. The name berkelium, symbol Bk, is proposed for element 97. The chemical separation of element 97 from the target material and other reaction products was made by combinations of precipitation and ion exchange adsorption methods making use of its anticipated (III) and (IV) oxidation states and its position as a member of the actinide transition series. The distinctive chemical properties made use of in its separation and the equally distinctive decay properties of the particular isotope constitute the principal evidence for the new element.
Author: Stanley Gerald Thompson Publisher: ISBN: Category : Berkelium Languages : en Pages : 10
Book Description
The recent production by Thompson, Ghiorso, and Seaborg of a radioactive isotope of berkelium (atomic number 97) makes it possible to investigate the chemical properties of this transuranium element by means of the tracer technique. This isotope has been prepared through the bombardment of Am241 with about 35 Mev helium ions in the 60-inch cyclotron of the Crocker Laboratory and is believed to have the mass number 243, or possibly 244. This Bk243 has a half-life of 4.6 hours and decays by electron capture with about 0.1% branching decay by alpha-particle emission. In the present tracer chemical experiments, the radiations accompanying the electron capture process were used as a means of detection and were counted in two ways. Where the sample deposits on the platinum plates were essentially weightless, as was the case following the evaporation and ignition of the elutriant solutions in the column adsorption experiments, a high efficiency was obtained by using a windowloess proportional counter to count the Auger electrons. The thicker samples from the precipitation experiments in which carrier materials were used were counted close to the thin window (3 mg/cm2 mica) of a bell type Geiger counter filled with 10 cm. xenon to enhance the efficiency for counting the x-rays. An aluminum absorber of thickness about 20 mg/cm2 was used between the sample and counter window to reduce errors due to variable absorption of soft components caused by small differences in sample thickness.
Author: Glenn Theodore Seaborg Publisher: World Scientific ISBN: 9789810214401 Category : Science Languages : en Pages : 728
Book Description
During his distinguished career spanning more than 50 years, Nobel laureate (Chemistry) Glenn T Seaborg published over 500 works. This volume puts together about 100 of his selected papers. The papers are divided into five categories. Category I consists of papers which detail the discovery of 10 transuranium elements and numerous heavy isotopes of special importance. Category II papers describe the discovery of a number of isotopes which became the workhorses of nuclear medicine or found other applications. Papers in Category III describe how the chemical properties of transuranium elements were originally determined, how chemistry is applied in nuclear sciences, and other chemical investigations, including early work done with the great chemist G N Lewis. Papers in Category IV cover radioactive decay chains and nuclear systematics. Lastly, papers in Category V illustrate how the powerful methods of chemistry are used to explain nuclear reactions in low, intermediate and high energy nuclear physics.
Author: Glenn T. Seaborg Publisher: John Wiley & Sons ISBN: 0471890626 Category : Science Languages : en Pages : 386
Book Description
Written by Glenn T. Seaborg, Nobel Laureate and pre-eminent figure in the field, with the assistance of Walter D. Loveland, it covers all aspects of transuranium elements, including their discovery, chemical properties, nuclear properties, nuclear synthesis reactions, experimental techniques, natural occurrence, superheavy elements, and predictions for the future. Published on the fiftieth anniversary of the discovery of transuranium elements, it conveys the essence of the ideas and distinctive blend of theory and experiment that has marked their study.
Author: Publisher: ISBN: Category : Californium Languages : en Pages : 32
Book Description
Definite identification has been made of an isotope of the element with atomic number 98 through the irradiation of Cm242 with about 35-Mev helium ions in the Berkeley Crocker Laboratory 60-inch cyclotron. The isotope which has been identified has an observed half-life of about 45 minutes and is thought to have the mass number 244. The observed mode of decay of 98244 is through the emission of alpha-particles, with energy of about 7.1 Mev, which agrees with predictions. Other considerations involving the systematics of radioactivity in this region indicate that it should also be unstable toward decay by electron capture. The chemical separation and identification of the new element was accomplished through the use of ion exchange adsorption methods employing the resin Dowex-50. The element 98 isotope appears in the eka-dysprosium position on elution curves containing berkelium and curium as reference points--that is, it precedes berkelium and curium off the column in like manner that dysprosium precedes terbium and gadolinium. The experiments so far have revealed only the tripositive oxidation state of eka-dysprosium character and suggest either that higher oxidation states are not stable in aqueous solutions or that the rates of oxidation are slow. The successful identification of so small an amount of an isotope of element 98 was possible only through having made accurate predictions of the chemical and radioactive properties.
Author: Glen W. Watson Publisher: Good Press ISBN: Category : History Languages : en Pages : 32
Book Description
Uncover the fascinating chronicles of elemental exploration in 'A Brief History of Element Discovery, Synthesis, and Analysis' by Glen W. Watson. Delve into the intricate world of chemistry and biology, where the secrets of the elements are unveiled in a concise and engaging manner. With its meticulously researched content and engaging storytelling, this book is a must-have for both amateur enthusiasts and seasoned professionals alike. Join the author on a quest to satisfy the curious minds of chemists and biologists, as the rich tapestry of element exploration comes to life within these pages.
Author: National Research Council Publisher: National Academies Press ISBN: 0309037891 Category : Science Languages : en Pages : 623
Book Description
This book describes hazards from radon progeny and other alpha-emitters that humans may inhale or ingest from their environment. In their analysis, the authors summarize in one document clinical and epidemiological evidence, the results of animal studies, research on alpha-particle damage at the cellular level, metabolic pathways for internal alpha-emitters, dosimetry and microdosimetry of radionuclides deposited in specific tissues, and the chemical toxicity of some low-specific-activity alpha-emitters. Techniques for estimating the risks to humans posed by radon and other internally deposited alpha-emitters are offered, along with a discussion of formulas, models, methods, and the level of uncertainty inherent in the risk estimates.
Author: L.R. Morss Publisher: Springer Science & Business Media ISBN: 1402035985 Category : Science Languages : en Pages : 4059
Book Description
The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.
Author: Sergey Krivovichev Publisher: Elsevier ISBN: 0080467911 Category : Science Languages : en Pages : 505
Book Description
Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions.* Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'
Author: Stanley Gerald Thompson
Author: Stanley Gerald Thompson
Author: Stanley Gerald Thompson
Author: Glenn Theodore Seaborg
Author: Glenn T. Seaborg
Author: 
Author: Glen W. Watson
Author: National Research Council
Author: L.R. Morss
Author: Sergey Krivovichev
Author: U.S. Atomic Energy Commission