Author: Bertha Gerda MarsmanPublisher:
ISBN:
Category :
Languages : en
Pages : 129
Book Description
The Catalytic Asymmetric Synthesis of Optically Active Epoxy Ketones
Author: Bertha Gerda MarsmanPublisher:
ISBN:
Category :
Languages : en
Pages : 129
Book Description
The catalytic asymmetric synthesis of optically active epoxy ketones
Author: Bea MarsmanThe catalytic asymmetric synthesis of optically active epoxy ke...
Author: Bertha Gerda MarsmanPublisher:
ISBN:
Category :
Languages : en
Pages : 148
Book Description
Catalytic Asymmetric Synthesis
Author: Takahiko AkiyamaPublisher: John Wiley & Sons
ISBN: 1119736390
Category : Science
Languages : en
Pages : 798
Book Description
Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most important catalytic asymmetric reactions known today This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important and recent developments in catalytic asymmetric synthesis. Edited by two well-qualified experts, sample topics covered in the work include: Metal catalysis, organocatalysis, photoredox catalysis, enzyme catalysis C–H bond functionalization reactions Carbon–carbon bond formation reactions, carbon–halogen bond formation reactions, hydrogenations, polymerizations, flow reactions Axially chiral compounds Retaining the best of its predecessors but now thoroughly up to date with the important and recent developments in catalytic asymmetric synthesis, the 4th edition of Catalytic Asymmetric Synthesis serves as an excellent desktop reference and text for researchers and students, from upper-level undergraduates all the way to experienced professionals in industry or academia.
Epoxidations and Hydroperoxidations of α,β-Unsaturated Ketones
Author: Corinna ReisingerPublisher: Springer Science & Business Media
ISBN: 3642281184
Category : Science
Languages : en
Pages : 266
Book Description
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic α,β-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydroperoxidation of α,β-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.
Asymmetric Synthesis
Author: James D. MorrisonPublisher: Elsevier
ISBN: 008092493X
Category : Science
Languages : en
Pages : 409
Book Description
The chapters in this volume have been written by some of the foremost practictioners in the field and should be of interest to both mechanistic and synthetic chemists.
Catalytic Methods in Asymmetric Synthesis
Author: Michelangelo GruttadauriaPublisher: John Wiley & Sons
ISBN: 0470641363
Category : Science
Languages : en
Pages : 720
Book Description
This book covers advances in the methods of catalytic asymmetric synthesis and their applications. Coverage moves from new materials and technologies to homogeneous metal-free catalysts and homogeneous metal catalysts. The applications of several methodologies for the synthesis of biologically active molecules are discussed. Part I addresses recent advances in new materials and technologies such as supported catalysts, supports, self-supported catalysts, chiral ionic liquids, supercritical fluids, flow reactors and microwaves related to asymmetric catalysis. Part II covers advances and milestones in organocatalytic, enzymatic and metal-based mediated asymmetric synthesis, including applications for the synthesis of biologically active molecules. Written by leading international experts, this book consists of 16 chapters with 2000 References and illustrations of 560 schemes and figures.
Green Approaches To Asymmetric Catalytic Synthesis
Author: Angela PattiPublisher: Springer Science & Business Media
ISBN: 9400714548
Category : Science
Languages : en
Pages : 150
Book Description
Nowadays, chirality is widely accepted as an important factor in molecular recognition processes and the biological activity of many pharmaceutical drugs and agrochemicals; this is confirmed by the continuous need for synthetic methods which lead to single or enriched enantiomers of such compounds. By presenting a review of the various and more recently developed approaches for both metal-transition and organocatalysis, this volume describes the development of “greener” asymmetric reactions which preserve stereoselectivity. The author summarizes the impressive amount of research that has been gathered within this field into three chapters focusing on: i)the search of alternative catalysts, ii) alternative solvents, and iii) alternative synthetic strategies and processes. For each topic, the fundamentals and some valuable applications are discussed.
Comprehensive Asymmetric Catalysis
Author: Eric N. JacobsenPublisher:
ISBN:
Category : Asymmetric synthesis
Languages : en
Pages : 536
Book Description
Accompanying CD-ROM contains the full-text search and a state-of-the-art graphic substructure search routine.
Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis
Author: Shinichi ItsunoPublisher: John Wiley & Sons
ISBN: 1118063953
Category : Technology & Engineering
Languages : en
Pages : 674
Book Description
This book reviews chiral polymer synthesis and its application to asymmetric catalysis. It features the design and use of polymer-immobilized catalysts and methods for their design and synthesis. Chapters cover peptide-catalyzed and enantioselective synthesis, optically-active polymers, and continuous flow processes. It collects recent advances in an important field of polymer and organic chemistry, with leading researchers explaining applications in academic and industry R & D.