The Anomeric Effect and Related Stereoelectronic Effects at Oxygen PDF Download

Author: A. J. Kirby
Publisher: Springer Science & Business Media
ISBN: 3642686761
Category : Science
Languages : en
Pages : 157

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Author: Eusebio Juaristi
Publisher: CRC Press
ISBN: 9780849389412
Category : Science
Languages : en
Pages : 248

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Book Description
This book provides a comprehensive review of the structural, conformational, and chemical manifestations of the anomeric effect. In order to present a cogent discussion of this most fundamental and relevant phenomenon, three chapters examine our present understanding of the origin of this conformational effect, based upon a wealth of theoretical and physical data. Equally important, however, are three additional chapters that deal with the general consequences of the stereoelectronic interactions that are associated with the basis of the anomeric effect. The remainder of the book is devoted to new areas of development in the topic-such as differentiation of the endo and exo anomeric interactions, specific analysis of the enthalpic component of anomeric effects, critical evaluation of the kinetics and reverse anomeric effects, discovery of a new substantial effect in second- and lower-row anomeric segments, and others.

Author: Gregory Robert James Thatcher
Publisher: Washington, DC : American Chemical Society
ISBN:
Category : Medical
Languages : en
Pages : 328

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Book Description
Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area. Explores applications in carbohydrate chemistry, including enzymology, as well as organometallic chemistry and the chemistry of phosphates and sulfates. Includes examination of molecular modeling methods in compounds influenced by stereoelectronic effects.

Author: Gregory Robert James Thatcher
Publisher: Washington, DC : American Chemical Society
ISBN:
Category : Medical
Languages : de
Pages : 716

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Book Description
Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area. Explores applications in carbohydrate chemistry, including enzymology, as well as organometallic chemistry and the chemistry of phosphates and sulfates. Includes examination of molecular modeling methods in compounds influenced by stereoelectronic effects.

Author: Anthony John Kirby
Publisher: Oxford University Press, USA
ISBN:
Category : Reactivity (Chemistry).
Languages : en
Pages : 108

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Book Description
Stereoelectronic effects control the way molecules are put together an d account for the "rules of engagement" which operate when molecules m eet and react. Understanding these effects is the key to understanding molecular behavior, since the same basic three-dimensional interactio ns are responsible for both structure and reactivity. This concise and very accessible volume provides a comprehensive, intentionally non-ma thematical coverage of stereochemistry, along with an in-depth discuss ion of the main classes of organic reactions, promoting a logical and simple way of thinking about chemistry.

Author: Igor V. Alabugin
Publisher: John Wiley & Sons
ISBN: 1118906349
Category : Science
Languages : en
Pages : 404

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Book Description
Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules An advanced textbook that provides an up-to-date overview of the field, starting from the fundamental principles Presents a large selection of modern examples of stereoelectronic effects in organic reactivity Shows practical applications of stereoelectronic effects in asymmetric catalysis, photochemical processes, bioorganic chemistry and biochemistry, inorganic and organometallic reactivity, supramolecular chemistry and materials science

Author: Momcilo Miljkovic
Publisher: Springer Science & Business Media
ISBN: 0387922652
Category : Science
Languages : en
Pages : 547

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Book Description
All essential areas of basic synthetic carbohydrate chemistry are covered and appropriately described. In addition, this book explains the basic reaction mechanisms while taking into account modern concepts such as stereoelectronic principles.

Author: Veejendra K. Yadav
Publisher: Springer Nature
ISBN: 303075622X
Category : Science
Languages : en
Pages : 262

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Book Description
In this second edition, the author has thoroughly updated each chapter and expanded the content with addition of three new chapters. This book comments on several key aspects of stereochemical control of organic reactions in measured detail to allow the reader easily grasp these concepts. In addition, emphasis is given to key information and important aspects of steric and stereoelectronic effects and their control on conformational profile and reactivity features. This book is not only an indispensable resource for advanced undergraduate and graduate students studying the stereochemical aspects of organic reactions, but also a good reference book for all organic chemists in both industry and academia.

Author: Dipak Kumar Mandal
Publisher: Academic Press
ISBN: 0128240938
Category : Science
Languages : en
Pages : 640

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Book Description
Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. - Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes - Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs - Features novel rules and mnemonics to delineate product stereochemistry - Includes up-to-date coverage with over 1300 selective references

Author: Bertram O. Fraser-Reid
Publisher: Springer Science & Business Media
ISBN: 3540361545
Category : Science
Languages : en
Pages : 2847

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Book Description
As a reflection of the quantum leap that has been made in the study of glycostructures, the first edition of this book has been completely revised and updated. The editors give up-to-date information on glycostructures, their chemistry and chemical biology in the form of a completely comprehensive survey. Glycostructures play highly diverse and crucial roles in a myriad of organisms and important systems in biology, physiology, medicine, bioengineering and technology. Only in recent years have the tools been developed to partly understand the highly complex functions and the chemistry behind them. While many facts remain undiscovered, this MRW has been contributed to by a large number of the world’s leading researchers in the field.