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Author: Petr Carsky Publisher: CRC Press ISBN: 1439839115 Category : Science Languages : en Pages : 311
Book Description
Since the turn of the 21st century, the field of electron molecule collisions has undergone a renaissance. The importance of such collisions in applications from radiation chemistry to astrochemistry has flowered, and their role in industrial processes such as plasma technology and lighting are vital to the advancement of next generation devices. F
Author: P.G. Burke Publisher: Springer Science & Business Media ISBN: 1461310490 Category : Science Languages : en Pages : 275
Book Description
This volume contains the invited papers and selected contributed papers presented at the International Symposium on 'Electron-Molecule Scattering and Photoionization' held at SERC's Daresbury Laboratory, Cheshire, England from 18th to 19th July, 1987. This Symposium was a Satellite Meeting to the XVth International Conference on the Physics of Electronic and Atomic Collisions (ICPEAC I and follows a tradition of Satellite Meetings i. n related areas of collisions held in association with previous ICPEAC's. In order to make this volume as representative of the Symposium as possible 'Hot Topics' presented orally at the meeting together with a few papers selected by the Programme Committee from the contributed posters are included. The Editors are grateful to the authors for responding rapidly to the invitation to submit their contri butions for inclusion in the volume, as indeed they are grateful to all the authors for the high quality of their contributions. The Symposium brought together over 100 scientists from many countries and from broad interdisciplinary backgrounds to hear about current rapid advances in electron-molecule scatteri. ng and photoioniza tion. These advances have been stimulated on the experimental side by the increasing availability of electron beams with millivolt energy resolution, by synchrotron radiation sources and by intense tunable lasers. On the theoretical side the introduction of new computational methods enables accurate predictions to be made, resulting in a new and deeper understanding of the basic physical processes involved.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
Most of our detailed information on the spectroscopy and dynamics of the electronic continuum of molecules is based on the complementary probes - photoionization and electron scattering. Though usually studied separately, it is most useful to appreciate the connections between these two processes since our understanding of one is often the key to interpreting or even generating new results in the other. We approach this subject in two steps. First, we very briefly outline the well-established connections, e.g., the Bethe-Born theory and comparisons of isoelectronic systems. Then we focus on a point of contact - the role of shape resonances in molecular photoionization and electron-molecule scattering - for which a substantial amount of new information has become available. Specific topics include mapping of resonances from the neutral (h? + molecule) to the negative ion (e + molecule) system, angular distributions, and interaction with vibration.
Author: Joseph Berkowitz Publisher: Academic Press ISBN: 032314828X Category : Science Languages : en Pages : 490
Book Description
Photoabsorption, Photoionization, and Photoelectron Spectroscopy explores photoabsorption processes involving individual, isolated molecules in the wavelength or photon energy range from the ionization thresholds of molecules (usually in the vacuum ultraviolet region) through the soft and hard X-ray region and beyond the ""K edge."" The interaction between electromagnetic radiation and isolated molecules based on photoabsorption, photoionization, and photoelectron spectroscopy studies is described, along with the techniques for measurement of total and partial cross sections. This book is comprised of eight chapters and examines the decomposition of molecules and molecular ions as well as mildly excited (valence shell excitation) and highly excited (inner shell excitation) molecules. After providing a general theoretical background, it discusses certain classes of atoms and molecules and considers electromagnetic interactions with gases. The following chapters focus on photoabsorption below the first ionization limit; quasi-discrete states above the first ionization potential; and the ionization continuum. Total photoabsorption and photoionization cross sections for selected molecules are also considered, and the angular distribution of photoelectrons is analyzed. The various measurement techniques are described in the last chapter. This monograph will be of interest to radiation chemists, radiation physicists, photochemists, mass spectrometrists, and perhaps radiation biologists.
Author: Isao Shimamura Publisher: Springer Science & Business Media ISBN: 1461323576 Category : Science Languages : en Pages : 578
Book Description
Scattering phenomena play an important role in modern physics. Many significant discoveries have been made through collision experiments. Amongst diverse kinds of collision systems, this book sheds light on the collision of an electron with a molecule. The electron-molecule collision provides a basic scattering problem. It is scattering by a nonspherical, multicentered composite particle with its centers having degrees of freedom of motion. The molecule can even disintegrate, Le., dissociate or ionize into fragments, some or all of which may also be molecules. Although it is a difficult problem, the recent theoretical, experimental, and computational progress has been so significant as to warrant publication of a book that specializes in this field. The progress owes partly to technical develop ments in measurements and computations. No less important has been the great and continuing stimulus from such fields of application as astrophysics, the physics of the earth's upper atmosphere, laser physics, radiation physics, the physics of gas discharges, magnetohydrodynamic power generation, and so on. This book aims at introducing the reader to the problem of electron molecule collisions, elucidating the physics behind the phenomena, and review ing, to some extent, up-to-date important results. This book should be appropri ate for graduate reading in physics and chemistry. We also believe that investi gators in atomic and molecular physics will benefit much from this book.