Author: Thomas L. Hatfield
Publisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 418
Book Description
Synthesis, Characterization and Electrochemical Investigations of Metal Complexes Derived from Pendant-arm Macrocycles
Author: Thomas L. Hatfield
Publisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 418
Book Description
Publisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 418
Book Description
Synthesis and Characterization of Pendant Arm Macrocycles and Their Transition Metal Complexes
Author: Nelson Zhang
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Copper(II) complexes of certain PAMs have been made and characterized by X-ray crystallography. For the aliphatic PAMs, both Cu(II) and Ni(II) complexes have been formed, and redox kinetics for the Ni(II) complexes have been measured. The effect of steric bulk of the PAMs on electron transfer from Ni(III) centers using an outer sphere reductant has been examined.
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
Copper(II) complexes of certain PAMs have been made and characterized by X-ray crystallography. For the aliphatic PAMs, both Cu(II) and Ni(II) complexes have been formed, and redox kinetics for the Ni(II) complexes have been measured. The effect of steric bulk of the PAMs on electron transfer from Ni(III) centers using an outer sphere reductant has been examined.
Synthesis and Investigation of Transition Metal Complexes with Small Pendant Arm Macrocycles
Author: Norman Munro Macdonald
Publisher:
ISBN:
Category : Macrocyclic compounds
Languages : en
Pages : 0
Book Description
Publisher:
ISBN:
Category : Macrocyclic compounds
Languages : en
Pages : 0
Book Description
N4-Macrocyclic Metal Complexes
Author: J.H. Zagal
Publisher: Springer Science & Business Media
ISBN: 0387284303
Category : Science
Languages : en
Pages : 828
Book Description
In response to significant developments in sensor science and technology, this book offers insight into the various extended applications and developments of N4 macrocycle complexes in biomimetic electrocatalysis. Chapters are devoted to the chemistry, electronic and electrochemical properties of porphyrin- based polymetallated supramolecular redox catalysts and their applications in analytical and photoelectrochemical molecular devices; the use of porphyrins, phthalocyanines and related complexes as electrocatalysts for the detection of a wide variety of environmentally polluting and biologically relevant molecules; and the use of electropolymerized metalloporphyrin and metallophthalocyanine films as powerful materials for analytical tools, especially for sensing biologically relevant species.
Publisher: Springer Science & Business Media
ISBN: 0387284303
Category : Science
Languages : en
Pages : 828
Book Description
In response to significant developments in sensor science and technology, this book offers insight into the various extended applications and developments of N4 macrocycle complexes in biomimetic electrocatalysis. Chapters are devoted to the chemistry, electronic and electrochemical properties of porphyrin- based polymetallated supramolecular redox catalysts and their applications in analytical and photoelectrochemical molecular devices; the use of porphyrins, phthalocyanines and related complexes as electrocatalysts for the detection of a wide variety of environmentally polluting and biologically relevant molecules; and the use of electropolymerized metalloporphyrin and metallophthalocyanine films as powerful materials for analytical tools, especially for sensing biologically relevant species.
Synthesis and Characterisation of Transition Metal Complexes with New Pendant Arm- and Bicyclo- Macrocyclic Ligands
Author: Denis Gérard Fortier
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 502
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 502
Book Description
Studies Involving Metal Complexes of Mixed-donor Pendant-arm Macrocyclic Ligands Derived from Salicylaldehyde
Direct Synthesis of Metal Complexes
Author: B.I. Kharisov
Publisher: Elsevier
ISBN: 0128110627
Category : Science
Languages : en
Pages : 470
Book Description
Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Publisher: Elsevier
ISBN: 0128110627
Category : Science
Languages : en
Pages : 470
Book Description
Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter
Synthesis,Biological Studies of Macrocyclic Transition Metal Complexes
Author: Rayees Sheikh
Publisher: LAP Lambert Academic Publishing
ISBN: 9783659146572
Category :
Languages : en
Pages : 156
Book Description
This book presents the important facts about the synthesis and biological studies of macrocyclic transition metal complexes. A detailed synthetic discussion of the reaction steps in each mechanism and their relationship with transition metal complexes has been considered. Macrocyclic ligands and their transition metal complexes depends upon the nature of reactants and the corresponding metal ion. The macrocyclic ligand are a growing class of compounds with varying chemistry a wide range of different molecular topologies and set of donor atoms. Aza type ligands appear as very promising to be used as antifertile, antibacterial, antifungal and other biological properties. Macrocyclic metal complexes play a central role in the construction of molecular materials, which display magnetic properties and find applications in material and supramolecular chemistry and biochemistry. It is believed that the present book will provide a succinct and clear introduction to synthesis, characterization and biological studies macrocyclic ligands with transition metal complexes that meets the needs of researchers at a variety of levels in several disciplines.
Publisher: LAP Lambert Academic Publishing
ISBN: 9783659146572
Category :
Languages : en
Pages : 156
Book Description
This book presents the important facts about the synthesis and biological studies of macrocyclic transition metal complexes. A detailed synthetic discussion of the reaction steps in each mechanism and their relationship with transition metal complexes has been considered. Macrocyclic ligands and their transition metal complexes depends upon the nature of reactants and the corresponding metal ion. The macrocyclic ligand are a growing class of compounds with varying chemistry a wide range of different molecular topologies and set of donor atoms. Aza type ligands appear as very promising to be used as antifertile, antibacterial, antifungal and other biological properties. Macrocyclic metal complexes play a central role in the construction of molecular materials, which display magnetic properties and find applications in material and supramolecular chemistry and biochemistry. It is believed that the present book will provide a succinct and clear introduction to synthesis, characterization and biological studies macrocyclic ligands with transition metal complexes that meets the needs of researchers at a variety of levels in several disciplines.
Design, Synthesis, and Photophysical and Electrochemical Studies of Redox-Active Macrocyclic Dinuclear Transition Metal Complexes as Potential Molecular Switches
Author: Jianfei Kong
Publisher: Open Dissertation Press
ISBN: 9781374702301
Category :
Languages : en
Pages :
Book Description
This dissertation, "Design, Synthesis, and Photophysical and Electrochemical Studies of Redox-active Macrocyclic Dinuclear Transition Metal Complexes as Potential Molecular Switches" by Jianfei, Kong, 孔建飞, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b4284170 Subjects: Transition metal complexes - Synthesis Macrocyclic compounds Electrochemistry Photochemistry
Publisher: Open Dissertation Press
ISBN: 9781374702301
Category :
Languages : en
Pages :
Book Description
This dissertation, "Design, Synthesis, and Photophysical and Electrochemical Studies of Redox-active Macrocyclic Dinuclear Transition Metal Complexes as Potential Molecular Switches" by Jianfei, Kong, 孔建飞, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b4284170 Subjects: Transition metal complexes - Synthesis Macrocyclic compounds Electrochemistry Photochemistry