Synthesis and Reactivity of Low-valent Titanium and Zirconium Complexes PDF Download

Author: Tamara Elizabeth Hanna
Publisher:
ISBN:
Category :
Languages : en
Pages : 932

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Author: Ana-Rita Mayol
Publisher:
ISBN:
Category :
Languages : en
Pages : 250

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Author: Ludmila Scoles
Publisher:
ISBN:
Category : Titanium
Languages : en
Pages : 0

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The chemistry of low-valent titanium is poorly developed apart from ubuquitous cyclopentadienyl derivatives.

Author: P.C. Wailes
Publisher: Elsevier
ISBN: 0323156479
Category : Science
Languages : en
Pages : 313

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Organometallic Chemistry of Titanium, Zirconium, and Hafnium covers the chemistry of organic complexes of titanium, zirconium, and hafnium having metal-to-carbon linkage. This book is organized into eight chapters that consider the significant developments in delineating the chemistry of these metal derivatives. This book starts with a description of the stability and bonding in cyclopentadienyl derivatives of the metals, based on the thermodynamic and spectroscopic evidence. The remaining chapters discuss the preparation and reactions of titanium-, zirconium-, and hafnium-bonded organic compounds. These chapters also look into the synthetic difficulties encountered from the reactions and preparation of these compounds. The stabilization and adduct formation of these metal complexes are also explored. Organic chemists and organic chemistry researchers and students will find this book invaluable.

Author: Josué Rolando Aguilar Calderón
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 126

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Author: Jennifer Lynn Polse
Publisher:
ISBN:
Category :
Languages : en
Pages : 418

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Author: Ana-Rita Mayol
Publisher:
ISBN: 9780599132955
Category :
Languages : en
Pages : 136

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The preparation of W(III), [(silox)2WCl(CO)]2, 30, and W(IV), [(silox)2W(CO)]2, 31, bimetallic complexes was accomplished. Structural studies and Extended Huckel calculations were performed on 31 to gain a better understanding of the bonding in the molecule. Thermolysis or photolysis of 30 yield a mixed valence bimetallic [(silox)3W = W(silox)(CO) 2], 32.

Author: R. J. H. Clark
Publisher: Elsevier
ISBN: 1483159213
Category : Science
Languages : en
Pages : 151

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The Chemistry of Titanium, Zirconium and Hafnium deals with the chemistry of titanium, zirconium, and hafnium and covers topics ranging from the occurrence and metallurgy of all three elements to their nuclear, physical, and chemical properties as well as analytical chemistry. The compounds of titanium, zirconium, and hafnium are also discussed. This volume is comprised of two chapters and opens with a historical overview and discovery of titanium, along with its occurrence and distribution, metallurgical aspects, and nuclear and physicochemical properties. The compounds of titanium are also considered, including alloys and complexes; hydrides and oxides; halides and oxyhalides; titanates and antimonides; and carbides and borides. The second chapter is devoted to zirconium and hafnium, their occurrence and metallurgy; and physical, chemical, and biological properties. Compounds of zirconium and hafnium are described, from alloys and hydrides to zirconates and hafnates; nitrides, phosphides, and arsenides; carbides, silicides, and germanides; molybdates, tungstates, halates, and perchlorates; alkoxides, mercaptides, and dithiocarbamates; and amides, alkylamides, triazenes, phthalocyanines, and bipyridyls. This book will be a valuable source of information for inorganic chemists.

Author: Chandrasekhar Srikantaiah Bajgur
Publisher:
ISBN:
Category :
Languages : en
Pages : 414

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