Synthesis and Polymerization of Metal-Containing Monomers PDF Download

Author: Anatoly D. Pomogailo
Publisher: CRC Press
ISBN: 1351085506
Category : Science
Languages : en
Pages : 176

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Book Description
This book overviews methods for the synthesis of metal-containing monomers with various types of metal bonds to the organic moiety of the molecule, such as ionic, covalent, donor-acceptor, and others. Published data on homopolymerization, copolymerization, and graft polymerization of these monomers are generalized. Synthesis and Polymerization of Metal-Containing Monomers discusses features typical of the molecular and structural organization of the resulting metal-containing polymers, their properties and the associated major applications, such as catalytical and biological activity, electrophysical characteristics, and thermal resistance.

Author: Anatoly D. Pomogailo
Publisher: CRC Press
ISBN: 1351093959
Category : Science
Languages : en
Pages : 159

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Book Description
This book overviews methods for the synthesis of metal-containing monomers with various types of metal bonds to the organic moiety of the molecule, such as ionic, covalent, donor-acceptor, and others. Published data on homopolymerization, copolymerization, and graft polymerization of these monomers are generalized. Synthesis and Polymerization of Metal-Containing Monomers discusses features typical of the molecular and structural organization of the resulting metal-containing polymers, their properties and the associated major applications, such as catalytical and biological activity, electrophysical characteristics, and thermal resistance.

Author: Charles E. Carraher Jr.
Publisher: Springer Science & Business Media
ISBN: 1461306698
Category : Science
Languages : en
Pages : 506

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Book Description
Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal TI -complexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi conductors and possessed one or two dimensional conductivity. Thus applications in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homogeneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homogeneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst. The first symposium on Organometallic Polymers, held at the National Meeting of the American Chemical Society in September 1977, attracted a large number of scientists interested in this field, both established investigators and newcomers. Subsequent symposia in 1977, 1979, 1983, and 1987 have seen the field mature. Hundreds of papers and patents have been published.

Author: Ronald D. Archer
Publisher: John Wiley & Sons
ISBN: 0471458449
Category : Science
Languages : en
Pages : 264

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Book Description
A balanced and concise coverage of inorganic polymers Inorganic polymers contain elements other than carbon as part of their principal backbone structure and are known to exhibit a wide range of composition and structure. Emphasizing physical properties, chemical synthesis, and characterization of inorganic polymers, Inorganic and Organometallic Polymers presents valuable and informative coverage of the field. With numerous examples of real-world practical applications and end-of-chapter exercises, Inorganic and Organometallic Polymers is suitable for use as a text in special topics in organic and polymer chemistry courses. The book features useful sections on: Classification schemes for inorganic polymers Synthesis of inorganic polymers, including step-growth syntheses, chain polymerizations, ring-opening polymerizations, and reductive coupling reactions Practical inorganic polymer chemistry topics such as polymer elastomers, dental and medical polymers, lubricants, lithographic resists, pre-ceramics, and more Inorganic and Organometallic Polymers is a valuable one-volume introduction for professional and student inorganic chemists, polymer chemists, and materials scientists.

Author: Alaa S. Abd-El-Aziz
Publisher: John Wiley & Sons
ISBN: 047008605X
Category : Technology & Engineering
Languages : en
Pages : 545

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Book Description
A detailed, up-to-date review of transition metal-containing polymers Promising advances in the electrical, optical, magnetic, biological, and catalytic properties that metal-containing polymers possess have led to notable expansion in the field of transition metal-containing polymers. Frontiers in Transition Metal-Containing Polymers provides a comprehensive, up-to-date review of the synthesis, properties, and applications of transition metal-containing polymers, including an overview of the historical development of these types of polymers. Written by the leading researchers in the field, this thorough volume covers the routes to organometallic and coordination polymers, as well as characterization and applications of transition metal-containing monomers and polymers. Other topics discussed include: Metallo-supramolecular coordination polymers based on nitrogen ligands Coordination polymers based on phosphorus ligands Polypeptide-based metallobiopolymers and DNA-based metallopolymers Metallodendrimers Self-assembly of metal-containing block copolymers Applications including drug delivery, optics, molecular devices, sensors, conductive materials, and more

Author: Alaa S Abd-El-Aziz
Publisher: Royal Society of Chemistry
ISBN: 178801412X
Category : Technology & Engineering
Languages : en
Pages : 241

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Book Description
New materials are required to solve global challenges such as the growing energy demand and reducing the threat of new and re-emerging diseases and infections. Metallopolymers is an exciting and promising area of research and this book focuses on the strategy of incorporating transition metals into macromolecules to design functional materials for addressing such problems. The book starts with an introduction to current global challenges and the role of materials science in tackling these, it then discusses the fundamentals of metallopolymers and their synthesis. The final chapters look at specific applications of the materials from photovoltaics and light-emitting diodes for energy conservation, to biological sensors and drug delivery platforms. Written by leading experts in the field, this book is an ideal reference for students and researchers working in polymer chemistry, organometallic chemistry and materials science interested in both the polymers and their applications in energy and health.

Author: Mohamed Naceur Belgacem
Publisher: Elsevier
ISBN: 0080560512
Category : Technology & Engineering
Languages : en
Pages : 562

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Book Description
The progressive dwindling of fossil resources, coupled with the drastic increase in oil prices, have sparked a feverish activity in search of alternatives based on renewable resources for the production of energy. Given the predominance of petroleum- and carbon-based chemistry for the manufacture of organic chemical commodities, a similar preoccupation has recently generated numerous initiatives aimed at replacing these fossil sources with renewable counterparts. In particular, major efforts are being conducted in the field of polymer science and technology to prepare macromolecular materials based on renewable resources. The concept of the bio-refinery, viz. the rational exploitation of the vegetable biomass in terms of the separation of its components and their utilisation as such, or after suitable chemical modifications, is thus gaining momentum and considerable financial backing from both the public and private sectors. This collection of chapters, each one written by internationally recognised experts in the corresponding field, covers in a comprehensive fashion all the major aspects related to the synthesis, characterization and properties of macromolecular materials prepared using renewable resources as such, or after appropriate modifications. Thus, monomers such as terpenes and furans, oligomers like rosin and tannins, and polymers ranging from cellulose to proteins and including macromolecules synthesized by microbes, are discussed with the purpose of showing the extraordinary variety of materials that can be prepared from their intelligent exploitation. Particular emphasis has been placed on recent advances and imminent perspectives, given the incessantly growing interest that this area is experiencing in both the scientific and technological realms. - Discusses bio-refining with explicit application to materials - Replete with examples of applications of the concept of sustainable development - Presents an impressive variety of novel macromolecular materials

Author: Gulzhian I. Dzhardimalieva
Publisher: Springer
ISBN: 3319560247
Category : Technology & Engineering
Languages : en
Pages : 1036

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Book Description
This book deals with the chemistry of polymeric metal chelates. The main results and the production and chemical structure of polymers with chelate units as well as the specificity of metal complex binding of different structure are presented here. This book also reveals the transformations which components undergo in the course of chelation. Special attention is paid not only to synthetic but also to natural (including living) systems. The usage of polymeric metal chelates and their development are examined. The related research was performed for chelates with chain structure. This book is useful to researchers being active in synthesis and design of macromolecular metal chelates

Author: Xing-Hong Zhang
Publisher: John Wiley & Sons
ISBN: 3527823808
Category : Technology & Engineering
Languages : en
Pages : 482

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Book Description
A must-have resource to the booming field of sulfur-containing polymers Sulfur-Containing Polymers is a state-of-the-art text that offers a synthesis of the various sulfur-containing polymers from low-cost sulfur resources such as elemental sulfur, carbon disulfide (CS2), carbonyl sulfide (COS) and mercaptan. With contributions from noted experts on the topic, the book presents an in-depth understanding of the mechanisms related to the synthesis of sulfur-containing polymers. The book also includes a review of the various types of sulfur-containing polymers, such as: poly(thioester)s, poly(thioether)s and poly(thiocarbonate)s and poly(thiourethane)s with linear or hyperbranched (dendrimer) architectures. The expert authors provide the fundamentals on the structure-property relationship and applications of sulfur-containing polymers. Designed to be beneficial for both research and application-oriented chemists and engineers, the book contains the most recent research and developments of sulfur-containing polymers. This important book: Offers the first comprehensive handbook on the topic Contains state-of-the-art research on synthesis of sulfur containing polymers from low-cost sulfur-containing compounds Examines the synthesis, mechanism, structure properties, and applications of various types of sulful-containing polymers Includes contributions from well-known experts Written for polymer chemists, materials scientists, chemists in industry, biochemists, and chemical engineers, Sulfur-Containing Polymers offers a groundbreaking text to the field with inforamtion on the most recent research.

Author: Ezat Khosravi
Publisher: Springer Science & Business Media
ISBN: 9401003734
Category : Science
Languages : en
Pages : 489

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Book Description
Since the last ASI in Turkey in Sept. 1995, the olefin metathesis has made remarkable strong developments with an incredible speed in various directions. New catalyst systems have been developed which have resulted in the synthesis of novel materials. Other fascinating developments have been the new catalysts for stereoselective metathesis and catalysts with considerable functional group tolerance. These new catalysts in addition to Ring Opening Metathesis Polymerisation (ROMP) and Acyclic Diene Metathesis (ADMET) are now powerful tools for Ring Closing Metathesis (RCM) and have found many applications in the synthesis of natural products. A lot of information has been established about all aspects of the olefin metathesis and there is a vast literature concerning the process, covering the initiators, mechanistic features and applications of this reaction in organic and polymer synthesis. The NATO ASI on rd th ROMP and Related Chemistry took place in Polanica-Zdroj, Poland during 3 to 15 Sept. 2000, to highlight the developments in this area and to discuss the prospects and visions for the year 2000 and beyond. The aims of the ASI were: to provide a platform for dissemination of knowledge; to promote communication between people who have a serious interest in this field of chemistry; to help establishing international scientific contacts and to provide an opportunity for the scientists with an appropriate scientific background to learn of recent developments in this field of science. There were 15 lecturers and 67 participants in this NATO ASI.