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Author: Charles E. Jr. Carraher Publisher: Elsevier ISBN: 0323153909 Category : Science Languages : en Pages : 368
Book Description
Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.
Author: Charles E. Jr. Carraher Publisher: Elsevier ISBN: 0323153909 Category : Science Languages : en Pages : 368
Book Description
Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.
Author: Walter Kaminsky Publisher: Springer Science & Business Media ISBN: 3642601782 Category : Technology & Engineering Languages : en Pages : 674
Book Description
45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing the ligands of the organometallic compounds, the structure of the polymers produced can be tailored in a wide manner. In invited lectures and posters, relevant aspects of the metalorganic catalysts for synthesis and polymerization are discussed in this book. This includes mechanism and kinetics, stereochemistry, material properties, and industrial applications.
Author: Narendra Pal Singh Chauhan Publisher: Walter de Gruyter GmbH & Co KG ISBN: 1501514792 Category : Science Languages : en Pages : 198
Book Description
The book covers silicon, phosphorus, sulfur, tin and germanium based inorganic polymers. It also includes chapters on organometallic polymers, transition metal based coordination polymers and geopolymers. The book is ideal for students and career starters in the industry.
Author: Y.Z. Voloshin Publisher: Elsevier ISBN: 0080529178 Category : Science Languages : en Pages : 433
Book Description
Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.
Author: Narendra Pal Singh Chauhan Publisher: Walter de Gruyter GmbH & Co KG ISBN: 1501514601 Category : Science Languages : en Pages : 154
Book Description
The book covers silicon, phosphorus, sulfur, tin and germanium based inorganic polymers. It also includes chapters on organometallic polymers, transition metal based coordination polymers and geopolymers. The book is ideal for students and career starters in the industry.
Author: Masayoshi Higuchi Publisher: Springer Nature ISBN: 4431568913 Category : Technology & Engineering Languages : en Pages : 92
Book Description
This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
Author: Wade H. Shafer Publisher: Springer Science & Business Media ISBN: 1468426044 Category : Science Languages : en Pages : 300
Book Description
Masters Theses in the Pure and Applied Sciences was first conceived, published, and disseminated by TPRC at Purdue University in 1957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dissemina tion phases of the activity was transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thought that such an arrangement would be more beneficial to the academic and general scientific and technical community. After five years of this joint undertaking we have concluded that it will be in the interest of all concerned if the printing and distribution of the volume were handled by a well-known publishing house to assure improved service and better communication. Hence, effective with this Volume 18, Masters Theses in the Pure and Applied Sciences will be disseminated on a worldwide basis by Plenum Publishing Corporation of New York. All back issues can also be ordered from Plenum. As we embark on this new partnership with Plenum, we also initiate a new venture in that this important annual reference work now covers Canadian universities as well as those in the United States. We are sure that this broader base will greatly enhance the value of these volumes.
Author: Evamarie Hey-Hawkins Publisher: John Wiley & Sons ISBN: 3527819134 Category : Technology & Engineering Languages : en Pages : 463
Book Description
Provides complete and undiluted knowledge on making inorganic polymers functional. This comprehensive book reflects the state of the art in the field of inorganic polymers, based on research conducted by a number of internationally leading research groups working in this area. It covers the synthesis aspects of synthetic inorganic polymers and looks at multiple inorganic monomers as building blocks, which exhibit unprecedented electronic, redox, photo-emissive, magnetic, self-healing and catalytic properties. It also looks at the applications of inorganic polymers in areas such as optoelectronics, energy storage, industrial chemistry, and biology. Beginning with an overview of the use of smart inorganic polymers in daily life, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences goes on to study the synthesis, properties, and applications of polymers incorporating different heteroelements such as boron, phosphorus, silicon, germanium, and tin. The book also examines inorganic polymers in flame-retardants, as functional materials, and in biology. An excellent addition to the polymer scientists' and synthetic chemists' toolbox Summarizes the state of the art on how to make and use functional inorganic polymers, from synthesis to applications Edited by the coordinator of a highly funded European community research program (COST action) that focuses specifically on the exploration of inorganic polymers Features contributions from top experts in the field Aimed at academics and industrial researchers in this field, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences will also benefit scientists who want to get a better overview on the state-of-the-art of this rapidly advancing area.
Author: Ruren Xu Publisher: Elsevier ISBN: 0444535993 Category : Science Languages : en Pages : 612
Book Description
The contributors to this book discuss inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions. They go on to describe the synthesis, preparation and assembly of six important categories of compounds with wide coverage of distinct synthetic chemistry systems
Author: Charles E. Jr. Carraher
Author: Charles E. Jr. Carraher
Author: Walter Kaminsky
Author: Narendra Pal Singh Chauhan
Author: 
Author: Y.Z. Voloshin
Author: Narendra Pal Singh Chauhan
Author: Masayoshi Higuchi
Author: Wade H. Shafer
Author: Evamarie Hey-Hawkins
Author: Ruren Xu