Author: Geewon ChungPublisher:
ISBN:
Category :
Languages : en
Pages : 544
Book Description
Synthesis and Characterization of New Dithiolate Ligands and Their Transition Metal Complexes
Author: Geewon ChungSynthesis and Characterization of Transition Metal Complexes of the Ligand DDDT−2, 5,6-Dihydro-l,4-dithiin-2,3-dithiolate
Author: Jane Alena Hanna WelchPublisher:
ISBN:
Category :
Languages : en
Pages : 570
Book Description
The Synthesis and Characterization of Some Transition Metal Complexes Derived from Oxime Ligands
Author: Gary A. NicholsonSynthesis, Characterization, and Reactivity of Transition Metal Complexes Containing Multi-donor Ligands
Author: John C. LinehanSynthesis and Characterization of Helical Ligand Transition Metal Complexes
Author: Andrew FessakSyntheses and Characterization of the New Dithiolene Ligand, 1,3-propanediyldithioethylene-1,2-dithiolate, and Representative Transition Metal Complexes
Author: Huiyan LuSynthesis and Characterization of Ligands and Transition Metal Complexes Containing M-terphenyl Scaffolds
Author: Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands
Author: Jamie HicksPublisher: Springer
ISBN: 9811029059
Category : Science
Languages : en
Pages : 214
Book Description
This thesis describes the synthesis and characterization of numerous metal-metal bonded complexes that are stabilized by extremely bulky amide ligands. It provides a comprehensive overview of the field, including discussions on groundbreaking complexes and reactions, before presenting in detail, exciting new findings from the PhD studies. The thesis appeals to researchers, professors and chemistry undergraduates with an interest in inorganic and/or organometallic chemistry.
Synthesis and Characterization of New Tetraaza, Tetraene, Macrocyclic Ligands and Their Metal Complexes
Author: Dennis Patrick RileyPublisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 716
Book Description
Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation
Author: Veeranna YempallyPublisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.