Synthesis and Aspects of the Chemistry of Some Cage Compounds PDF Download

Author: David L. Goff
Publisher:
ISBN:
Category : Clathrate compounds
Languages : en
Pages : 192

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Author: Yan Voloshin
Publisher: Springer
ISBN: 3319277383
Category : Science
Languages : en
Pages : 653

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Book Description
This fundamental book presents the most comprehensive summary of the current state of the art in the chemistry of cage compounds. It introduces different ways of how ions and molecules can be encapsulated by three-dimensional caging ligands to form molecular and polymeric species: covalent, supramolecular, and coordination capsules. The authors introduce their classification, reactivity, and selected practical applications. Because encapsulation can isolate caged ions and molecules from external factors, the encapsulated species can exhibit unique physical and chemical properties. The resulting specific reactivity and selectivity can open up a range of applications, including chemical separation, recognition, chiral separation, catalysis, applications as sensors or probes, as molecular or supramolecular devices, or molecular carriers (cargo).A particularly strong emphasis in this book is on the summary and review of the synthesis of various types of cage compounds. Readers will find over 850 literature references summarized and clearly represented in over 600 schemes and illustrations. The book is structured by the types of caging ligands (covalent, supramolecular, or coordination capsules). The authors further arranged the chapters by ligand classes and types of encapsulated species (neutral molecules, anions, or cations). Readers will hence find an exhaustive reference resource and summary of the current state of research into encapsulated species, nowadays almost a separated realm of modern chemistry.

Author: David S. Teager
Publisher:
ISBN:
Category :
Languages : en
Pages : 228

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Author: Vladimir Ya Lee
Publisher: Academic Press
ISBN: 0128019913
Category : Science
Languages : en
Pages : 758

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Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

Author: Eiji Ōsawa
Publisher: VCH Publishers
ISBN:
Category : Cage hydrocarbons
Languages : en
Pages : 432

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Author: Yan Voloshin
Publisher: Springer
ISBN: 331956420X
Category : Science
Languages : en
Pages : 475

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This fundamental book presents the most comprehensive summary of the current state in chemistry of cage metal complexes. After their previous book “The Encapsulation Phenomenon” (www.springer.com/978-3-319-27737-0) the authors in this book focus on the encapsulation of metal ions by different types of three-dimensional mono- and polynucleating caging ligands. Within these cage metal complexes, (metal) ions can be isolated from external factors. The book provides both a classification of the cage compounds and summaries of synthetic approaches. On that basis the authors then describe the unique chemical and physical properties and the resulting reactivity of the cage compounds, as well as practical and potential applications as potent topological drugs and prodrugs, antifibrillogenic agents, radiodiagnostic and radiotherapeutic compounds, paramagnetic probes, single-molecule magnets, electrocatalysts for hydrogen production, (photo)electronic devices, and many more. Readers will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented in over 300 color schemes and figures.

Author: Yanjun Wang
Publisher:
ISBN:
Category : Polycyclic compounds
Languages : en
Pages : 240

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Author: K.K. Laali
Publisher: JAI Press
ISBN: 9780762305988
Category : Science
Languages : en
Pages : 0

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Book Description
Carbocyclic and Heterocyclic Cage Compounds and their Building Blocks is the first independent Supplement in the series. The collection of essays presented is very much at the forefront of research in this active area and the topics discussed complement and evolve from the more general treatment in earlier volumes of the Series. Furthermore it was appropriate to produce a collection of work at the cutting edge of the field, where progress in heterocyclic cage compounds are discussed together in a single volume, thus avoiding the organic versus organometallic barriers in an effort to raise more awareness concerning their similarities and differences. Since phosphaalkynes serve as building blocks for a host of phosphorus-carbon cage compounds discussion of the versatile chemistry of phosphaalkynes is relevant. Likewise, discussion of the versatile chemistry of phosphaalkenes is appropriate since they function as synthetic precursors to phosphaalkynes and are the products of electrophilic addition to phosphaalkynes.

Author: Gerard Marriott
Publisher: Academic Press
ISBN:
Category : Medical
Languages : en
Pages : 584

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The critically acclaimed laboratory standard for more than forty years, Methods in Enzymology is one of the most highly respected publications in the field of biochemistry. Since 1955, each volume has been eagerly awaited, frequently consulted, and praised by researchers and reviewers alike. More than 285 volumes have been published (all of them still in print) and much of the material is relevant even today--truly an essential publication for researchers in all fields of life sciences.

Author: University Microfilms International
Publisher: Ann Arbor, Mich. : University Microfilms International
ISBN:
Category : Reference
Languages : en
Pages : 712

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