Surfactant Enhanced Solubilization of Dense Non-aqueous Phase Liquids (DNAPLs) for Application to In-situ Porous Media Remediation PDF Download

Author: Lee P. Josselyn
Publisher:
ISBN:
Category : Surface active agents
Languages : en
Pages : 216

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Author: Donald F. Lowe
Publisher: CRC Press
ISBN: 9780849341175
Category : Science
Languages : en
Pages : 444

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A $19.3 million Department of Defense grant to Rice University funds the Advanced Applied Technology Demonstration Facility (AATDF). One of the project goals is the development of reduction strategies for nonaqueous phase liquids (NAPLs) in the subsurface. Surfactants and Cosolvents for NAPL Remediation records the results of AATDF research. The manual is a guide to the practical application of surfactants/cosolvent for in situ remediation. It is targeted to decision makers and anyone concerned with the design or implementation of these technologies. The book discusses the situational viability of surfactants/cosolvents , the possible results, design, and operation. It includes case studies, step-by-step guidance, and project cost work sheets. The successful results of the AATDF research, as documented Surfactants and Cosolvents for NAPL Remediation, are an invaluable contribution to the future of subsurface remediation. Without source NAPL reduction, the alternative is decades of plume management through pump-and-treat.

Author: Wade H. Shafer
Publisher: Springer Science & Business Media
ISBN: 1461519691
Category : Science
Languages : en
Pages : 426

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Masters Theses in the Pure and Applied Sciences was first conceived, published, and disseminated by the Center for Information and Numerical Data Analysis and Synthesis (CINDAS)* at Purdue University in 1957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dis semination phases of the activity were transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thought that such an arrangement would be more beneficial to the academic and general scientific and technical community. After five years of this joint undertaking we had concluded that it was in the interest of all concerned if the printing and distribution of the volumes were handled by an international publishing house to assure improved service and broader dissemination. Hence, starting with Volume 18, Masters Theses in the Pure and Applied Sciences has been disseminated on a worldwide basis by Plenum Publishing Corporation of New York, and in the same year the coverage was broadened to include Canadian universities. All back issues can also be ordered from Plenum. We have reported in Volume 38 (thesis year 1993) a total of 13,787 thesis titles from 22 Canadian and 164 United States universities. We are sure that this broader base for these titles reported will greatly enhance the value of this impor tant annual reference work. While Volume 38 reports theses submitted in 1993, on occasion, certain uni versities do report theses submitted in previous years but not reported at the time.

Author: National Research Council
Publisher: National Academies Press
ISBN: 0309065496
Category : Science
Languages : en
Pages : 301

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This book presents a comprehensive, up-to-date review of technologies for cleaning up contaminants in groundwater and soil. It provides a special focus on three classes of contaminants that have proven very difficult to treat once released to the subsurface: metals, radionuclides, and dense nonaqueous-phase liquids such as chlorinated solvents. Groundwater and Soil Cleanup was commissioned by the Department of Energy (DOE) as part of its program to clean up contamination in the nuclear weapons production complex. In addition to a review of remediation technologies, the book describes new trends in regulation of contaminated sites and assesses DOE's program for developing new subsurface cleanup technologies.

Author: David A. Sabatini
Publisher:
ISBN:
Category : Dense nonaqueous phase liquids
Languages : en
Pages : 18

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 212

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Due to the limitations of conventional groundwater remediation technologies, innovative methods have been sought to enhance the removal of recalcitrant compounds such as trichloroethylene (TCE) and tetrachloroethylene (PCE), which are frequently trapped in the subsurface as dense nonaqueous phase liquids (DNAPLs). Surfactant-Enhanced Aquifer Remediation (SEAR) is one such method, which has been adapted from enhanced oil recovery techniques used by the petroleum industry. It involves sweeping a surfactant solution across the DNAPL-contaminated portion of the aquifer. The surfactants accomplish rapid removal of the DNAPL contaminant by greatly increasing its effective aqueous solubility and by reducing the interfacial tension between the DNAPL and water phases. In field demonstrations conducted to date, up to 99% removal efficiencies have been achieved with just three pore volumes of surfactant followed by water flooding. In a typical remediation scheme, surfactants are used to remediate DNAPL source areas and complement the use of other technologies, such as conventional pump- and -treat systems, for removing the dissolved-phase plumes that are associated with DNAPL source areas. Currently, simple options for remediating DNAPL source areas are limited. Residual DNAPL in an aquifer acts as a continual source of contamination to the groundwater, and site closure cannot be achieved unless the source is removed. This surfactant-based technology will be more cost-effective than conventional pump-and-treat systems and will provide for a more rapid site cleanup.

Author: National Research Council
Publisher: National Academies Press
ISBN: 030909447X
Category : Science
Languages : en
Pages : 371

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At hundreds of thousands of commercial, industrial, and military sites across the country, subsurface materials including groundwater are contaminated with chemical waste. The last decade has seen growing interest in using aggressive source remediation technologies to remove contaminants from the subsurface, but there is limited understanding of (1) the effectiveness of these technologies and (2) the overall effect of mass removal on groundwater quality. This report reviews the suite of technologies available for source remediation and their ability to reach a variety of cleanup goals, from meeting regulatory standards for groundwater to reducing costs. The report proposes elements of a protocol for accomplishing source remediation that should enable project managers to decide whether and how to pursue source remediation at their sites.

Author: Godage B. Wickramanayake
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 272

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Book Description
- DNAPL Site Characterization- DNAPL Modeling- DNAPL Remediation Technologies- DNAPLs in Fractured Media- Surfactant/Cosolvent Flushing.

Author: John McCarthy
Publisher: CRC Press
ISBN: 9780873718288
Category : Technology & Engineering
Languages : en
Pages : 412

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Book Description
This valuable resource discusses several strategies of manipulating colloids for environmental restoration, identifies advantages and disadvantages of each strategy, and considers obstacles limiting the application of each strategy. Approaches evaluated include the following: Chemical modification of subsurface systems to mobilize or deposit colloids in situ Altering the mobility of microorganisms to improve delivery of microbes for bioremediation Manipulating colloids or biocolloids (bacteria) to change aquifer permeability to either enhance bioremediation or create in situ barriers Introducing modified colloids, surfactants, and emulsions to control colloid mobility or to increase recovery of sorbed contaminants by pump and treat methods Manipulation of Groundwater Colloids for Environmental Restoration also contains short, focused research reports on specific studies relevant to the various approaches under consideration. Subjects covered range from mobility of organic macromolecules by controlled field injection experiments to new techniques that investigate surface chemistry and aggregation of inorganic colloids. Other topics discussed include the depositional behavior and transport of biocolloids in porous media, surfactants as modifiers of surface binding sites on colloids, and genetic engineering of microorganisms to serve as contaminant-scavenging biocolloids. Manipulation of Groundwater Colloids for Environmental Restoration is an excellent resource for research scientists in hydrology, chemistry, and microbiology; environmental consultants; regulators; environmental engineers; bioremediation microbiologists; and engineers.

Author: Brian L. Murphy
Publisher: Academic Press
ISBN: 0124047076
Category : Science
Languages : en
Pages : 747

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Book Description
The third edition of Introduction to Environmental Forensics is a state-of-the-art reference for the practicing environmental forensics consultant, regulator, student, academic, and scientist, with topics including compound-specific isotope analysis (CSIA), advanced multivariate statistical techniques, surrogate approaches for contaminant source identification and age dating, dendroecology, hydrofracking, releases from underground storage tanks and piping, and contaminant-transport modeling for forensic applications. Recognized international forensic scientists were selected to author chapters in their specific areas of expertise and case studies are included to illustrate the application of these methods in actual environmental forensic investigations. This edition provides updates on advances in various techniques and introduces several new topics. - Provides a comprehensive review of all aspects of environmental forensics - Coverage ranges from emerging statistical methods to state-of-the-art analytical techniques, such as gas chromatography-combustion-isotope ratio mass spectrometry and polytopic vector analysis - Numerous examples and case studies are provided to illustrate the application of these forensic techniques in environmental investigations