Surfactant Enhanced Aquifer Remediation of a DNAPL Site, Portsmouth, Ohio PDF Download

Author: Nichole L. Case
Publisher:
ISBN:
Category :
Languages : en
Pages : 224

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 8

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Book Description
Many DOE facilities are situated in areas of sand and gravel which have become polluted with dense, non-aqueous phase liquids or DNAPLs, such as chlorinated solvents, from the various industrial operations at these facilities. The presence of such DNAPLs in sand and gravel aquifers is now recognized as the principal factor in the failure of standard ground-water remediation methods, i.e., {open_quotes}pump-and-treat{close_quotes} operations, to decontaminate such systems. The principal objective of this study is to demonstrate that multi-component DNAPLs can be readily solubilized in sand and gravel aquifers by dilute surfactant solutions.

Author: David A. Sabatini
Publisher:
ISBN:
Category : Dense nonaqueous phase liquids
Languages : en
Pages : 18

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 212

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Due to the limitations of conventional groundwater remediation technologies, innovative methods have been sought to enhance the removal of recalcitrant compounds such as trichloroethylene (TCE) and tetrachloroethylene (PCE), which are frequently trapped in the subsurface as dense nonaqueous phase liquids (DNAPLs). Surfactant-Enhanced Aquifer Remediation (SEAR) is one such method, which has been adapted from enhanced oil recovery techniques used by the petroleum industry. It involves sweeping a surfactant solution across the DNAPL-contaminated portion of the aquifer. The surfactants accomplish rapid removal of the DNAPL contaminant by greatly increasing its effective aqueous solubility and by reducing the interfacial tension between the DNAPL and water phases. In field demonstrations conducted to date, up to 99% removal efficiencies have been achieved with just three pore volumes of surfactant followed by water flooding. In a typical remediation scheme, surfactants are used to remediate DNAPL source areas and complement the use of other technologies, such as conventional pump- and -treat systems, for removing the dissolved-phase plumes that are associated with DNAPL source areas. Currently, simple options for remediating DNAPL source areas are limited. Residual DNAPL in an aquifer acts as a continual source of contamination to the groundwater, and site closure cannot be achieved unless the source is removed. This surfactant-based technology will be more cost-effective than conventional pump-and-treat systems and will provide for a more rapid site cleanup.

Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 152

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During 1996 and 1997, five separate partitioning interwell tracer tests (PITTs) were conducted as part of two separate surfactant-enhanced aquifer remediation (SEAR) demonstrations targeting DNAPL (primarily TCE) at Operable Unit 2 (OU2), Hill Air Force Base, Utah. These PITTs were used as a DNAPL characterization tool to accurately determine: 1.) the total aquifer volume swept; 2.) the total amount of DNAPL present in the swept aquifer volume; and, 3.) the average residual saturation present. PITTs were conducted before and after each SEAR demonstration to provide remediation performance assessments and were hydraulically controlled without using sheetpile walls. The successful implementation of field-scale PITTs required an engineering design strategy using conventional characterization activities, laboratory studies, and UTCHEM modeling. The volume sampled by each PITT was on the order of an average of 6500 cu ft (14,000 gallon pore volume). Tracer recoveries ranged from 79% to 92%, indicating that, within experimental error, all of the injected tracers were recovered. The method of temporal moments was used to analyze each PITT, and the resulting DNAPL volume estimates were in close agreement with other measurements (e.g. SEAR DNAPL recoveries and core data estimates). Thus, in sandy alluvium, PITTs are very accurate estimators of DNAPL volumes, and provide an excellent characterization and performance assessment tool for DNAPL remediation efforts. Based on the success of these PITTs, the USAF is currently conducting large-scale PITTs to characterize the entire DNAPL source zone at OU2.

Author:
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Category : Hazardous waste site remediation
Languages : en
Pages : 36

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Author: Donald F. Lowe
Publisher: CRC Press
ISBN: 9780849341175
Category : Science
Languages : en
Pages : 444

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A $19.3 million Department of Defense grant to Rice University funds the Advanced Applied Technology Demonstration Facility (AATDF). One of the project goals is the development of reduction strategies for nonaqueous phase liquids (NAPLs) in the subsurface. Surfactants and Cosolvents for NAPL Remediation records the results of AATDF research. The manual is a guide to the practical application of surfactants/cosolvent for in situ remediation. It is targeted to decision makers and anyone concerned with the design or implementation of these technologies. The book discusses the situational viability of surfactants/cosolvents , the possible results, design, and operation. It includes case studies, step-by-step guidance, and project cost work sheets. The successful results of the AATDF research, as documented Surfactants and Cosolvents for NAPL Remediation, are an invaluable contribution to the future of subsurface remediation. Without source NAPL reduction, the alternative is decades of plume management through pump-and-treat.

Author: James A. Smith
Publisher: Springer Science & Business Media
ISBN: 0306469286
Category : Science
Languages : en
Pages : 368

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As we transition into the 21st century, it is apparent that this is an exciting time for environmental engineers and scientists studying remediation technologies. There has been a rapid development of new ways to clean-up polluted groundwater. Research activities of the past and next 10 years will have a dramatic impact on the quality of the subsurface environment for the next century. In 20, or even 10 years from now, our approach to subsurface remediation will probably be vastly different than it is today. Many of the emerging technologies presented in this book will form the basis of standard remediation practices of the future. Physicochemical Groundwater Remediation presents detailed information on multiple emerging technologies for the remediation of the contaminated subsurface environment. All of these technologies apply our knowledge of physical and chemical processes to clean up ground water and the unsaturated zone, and many (if not all) of these emerging technologies will help define standard practices in the future. These technologies include in situ sorptive and reactive treatment walls, surfactant-enhanced aquifer remediation, optimization analyses for remediation system design, chemical, electrochemical, and biochemical remediation processes, and monitored natural attenuation. You will learn how palladium catalyzes the dehalogenation of chlorinated solvents. You will find out how barometric pumping can naturally remove significant quantities of volatile organic pollutants from shallow ground water and the unsaturated zone. You can learn about mobilizing non-aqueous phase liquids (NAPLs) without risking significant downward migration of the NAPL. You can find out how processes such as electroosmosis and electromigration can be exploited for groundwater remediation purposes and how zero-valent iron and zeolite treatment walls can be used in situ to treat and control contaminant plume migration. Contributors to this book are experts in groundwater remediation processes, and they represent industry, consulting, academia, and government. If your work involves the clean up of contaminated soil and groundwater, this book is an essential reference to keep you up to date on the most promising new developments in remediation research.

Author: Bernard H. Kueper
Publisher: Springer Science & Business
ISBN: 1461469228
Category : Technology & Engineering
Languages : en
Pages : 759

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Book Description
The purpose of this book is to help engineers and scientists better understand dense nonaqueous phase liquid (DNAPL) contamination of groundwater and the methods and technology used for characterization and remediation. Remediation of DNAPL source zones is very difficult and controversial and must be based on state-of-the-art knowledge of the behavior (transport and fate) of nonaqueous phase liquids in the subsurface and site specific geology, chemistry and hydrology. This volume is focused on the characterization and remediation of nonaqueous phase chlorinated solvents and it is hoped that mid-level engineers and scientists will find this book helpful in understanding the current state-of-practice of DNAPL source zone management and remediation.

Author: David A. Sabatini
Publisher:
ISBN:
Category : Language Arts & Disciplines
Languages : en
Pages : 320

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Book Description
Provides a timely and thorough review of surfactant-based remediation technologies. Covers fundamental mechanistic studies to scale-up and process modeling and full-scale field implementation studies. Summarizes the technical, economic, and sociopolitical issues affecting widespread implementation of these technologies. Includes contributions from academic and industrial researchers as well as regulatory personnel.