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Author: Peter Fogg Publisher: ISBN: Category : Science Languages : en Pages : 354
Book Description
Gives a critical and detailed survey of the solubility in a wide range of liquids of all gases in common use. The first part covers basic theoretical and practical aspects of the measurement of solubilities of gases. Limitations in the reliability of the available data are discussed and ways of predicting approximate solubilities of gases are indicated. Tables of solubility data for dissolution in aqueous and non-aqueous solvents are also included. Also contains diagrams and graphs that show the variation of solubility with pressure or temperature. Will leave the reader with a solid overview of the differing gas solubilities under conditions commonly encountered in chemical plants and laboratories.
Author: William Gerrard Publisher: Elsevier ISBN: 1483147681 Category : Science Languages : en Pages : 520
Book Description
Gas Solubilities: Widespread Applications discusses several topics concerning the various applications of gas solubilities. The first chapter of the book reviews Henr's law, while the second chapter covers the effect of temperature on gas solubility. The third chapter discusses the various gases used by Horiuti, and the following chapters evaluate the data on sulfur dioxide, chlorine data, and solubility data for hydrogen sulfide. Chapter 7 concerns itself with solubility of radon, thoron, and actinon. Chapter 8 tackles the solubilities of diborane and the gaseous hydrides of groups IV, V, and VI of the periodic table. Chapter 9 discusses the solubility of gases containing fluorine, while Chapter 10 talks about Hildebrand's theory in the light of all gas solubility data. Chapter 11 covers the hydrogen halide system, while Chapter 12 deals with the solubility of gases in water and aqueous solutions of slats, inorganic acids and bases, and organic compounds. Chapter 13 discusses gases in sea water, while Chapter 14 covers aerosol propellants and Chapter 15 tackles the solubility of nitric oxide. Chapter 16 discusses the biotechnological aspects, and Chapter 17 talks about more on making holes. Chapter 18 covers the evaluation of data on phosphine. The book would be of great interest to researchers and professionals concerned with applications of the soluble nature of gases.
Book Description
Arising no doubt from its pre-eminence as a natural liquid, water has always been considered by chemists as the original solvent in which very varied chemical reactions can take place, both for preparational and for analytical purposes. This explains the very long-standing interest shown in the study of aqueous solutions. In this con nection, it must be stressed that the theory of Arrhenius and Ostwald (1887-1894) on electrolytic dissociation, was originally devised solely for solutions in water and that the first true concept of acidity resulting from this is linked to the use of this solvent. The more recent development of numerous physico-chemical measurement methods has made possible an increase of knowledge in this area up to an extremely advanced degree of systematization. Thus today we have available both a very large amount of experimental data, together with very refined methods of deduction and of quantitative treatment of chemical reactions in solution which enable us to make the fullest use of this data. Nevertheless, . it appears quite evident at present that there are numerous chemical processes which cannot take place in water, and that its use as a solvent imposes 2 INTRODUCTION limitations. In order to overcome these limitations, it was natural that interest should be attracted to solvents other than water and that the new possibilities thus opened up should be explored.
Author: W. Gerrard Publisher: Springer Science & Business Media ISBN: 1489926445 Category : Science Languages : en Pages : 275
Book Description
The solubility of gases and liquids in liquids is of great importance in large areas of operations based on chemical concepts. Phenomena have appeared to be so varied that even experts have from time to time remarked on the difficulty of seeing a consistent pattern. Now for the first time the essential pattern of all known gas solubility data is set out in a graphic form for all to see. The continuous merging of the gas-liquid systems and the liquid-liquid systems is also illustrated. The pattern opens the way to rational predictions. The new data given for the lower alkanes and alkenes, the three methylamines, ammonia, bromomethane, and chloroethane, together with my previously reported data on hydrogen sulfide, dimethyl ether, chloromethane, and sulfur dioxide, have been obtained by a bubbler-manometer procedure which is fully described. Not only are these data of significance in many chemical processes, but they have also been vital to the development of the overall essential pattern covering all gases. The book is for chemists, chemical engineers, biotechnologists, certain physi cists, and teachers and students in these disciplines. It is a book for all those who are concerned with the use and inculcation of the fundamental, even rudimentary, principles of chemistry.