Studies on the Passive State of Metals PDF Download

Author: John Franklin Steiner
Publisher:
ISBN:
Category :
Languages : en
Pages : 246

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Author: Michel Froment
Publisher: Elsevier
ISBN: 1483102629
Category : Technology & Engineering
Languages : en
Pages : 784

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Book Description
Passivity of Metals and Semiconductors covers the proceedings of the Fifth International Symposium on Passivity, held in Bombannes, France on May30 - June3, 1983. The said symposium is concerned with passivity of metallic materials, localized corrosion, experimental techniques, and classical techniques such as optical techniques and electron spectroscopy. The book is divided into five sections. Section I deals with the concepts involved in the composition-transport phenomena and covers topics such as the transport of oxygen and water in oxide layers; the kinetics of oxidation of silicon; and the oxidation rate laws of metals that form nonstoichiometric oxides. Section II covers related techniques and their specific applications such as study of passivity of iron by in situ methods; optical methods in the study of passive films; and the analysis of multiple layer surface films by modulated reflection spectroscopy. Section III tackles amorphous metals - their passivity, their depassivation and repassivation in localized corrosion, and a comparison of models for localized breakdown of passivity. Part IV discusses the photoelectrochemistry of semiconductors; Part V tackles passivation and localized corrosion of stainless steels. The text is recommended for organic chemists, metallurgists, and engineers who would like to know more about the passivity of metals and their applications in different fields.

Author: N. D. Tomashov
Publisher: Springer Science & Business Media
ISBN: 1468417282
Category : Science
Languages : en
Pages : 182

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Book Description
Considerable progress has been made in the past 20 years toward understanding the basic mechanisms of corrosion, and the application of this knowledge to its control. From the very beginning, educational institutions and industrial research laboratories have contributed greatly toward determining and elucidating the fundamental principles of corrosion reactions. Some of the basic principles involved in cor rosion of metals can be credited to early investigators. Michael Faraday in 1830-1840 studied the relationship between the quantity of a metal dissolved and the electric current which was produced by this reaction. He also proposed that the passivation of iron was through the formation of a film and that the dissolution of a metal was electro chemical in nature. Sir Humphrey Davy in 1824 worked out the funda mentals of galvanic corrosion of ships' hulls and applied sacrificial zinc anodes to protect them from sea water corrosion. Richard Arlie in 1847 demonstrated that corrosion produced by oxygen at the surface of iron in a flowing stream generated a current. With the fundamental knowledge available to him from these early investigators, Willis Rodney Whitney developed and expressed, in its most useful form, one of the basic scientific principles which provides modern corrosion specialists with a fundamental basis of corrosion control. Dr. Whitney concluded that corrosion of iron is electrochemical, and that the rate is simply a function of the electromotive force and resistance of the circuit.

Author: Robert Peter Frankenthal
Publisher:
ISBN:
Category : Corrosion and anti-corrosives
Languages : en
Pages : 1104

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Author: D Landolt
Publisher: Elsevier
ISBN: 0857093738
Category : Technology & Engineering
Languages : en
Pages : 585

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Tribocorrosion causes the degradation or alteration of materials through the combined action of corrosion and wear. It limits the performance and life-time of installations, machines and devices with moving parts, and controls certain manufacturing processes such as chemical–mechanical polishing. The effects of tribocorrosion are most pronounced on passive metals which owe their corrosion resistance to a thin protecting oxide film. Most corrosion-resistant engineering alloys belong to this category.This book provides an introduction to the developing field of tribocorrosion and an overview of the latest research. Part one reviews basic notions of corrosion and tribology, before presenting the most recent results on the growth and structure of passive oxide films. Tribocorrosion mechanisms under fretting, sliding and erosion conditions, respectively, are then discussed. Part two focuses on methods for measuring and preventing tribocorrosion. It includes chapters on electrochemical techniques, the design of tribocorrosion test equipment, data evaluation and the optimisation of materials’ properties for tribocorrosion systems. Part three presents a selection of tribocorrosion problems in engineering and medicine. Three chapters address the tribocorrosion of medical implants including test methods and clinical implications. Other chapters examine tribocorrosion issues in nuclear power plants, marine environments, automotive cooling circuits, elevated-temperature metal working and chemical–mechanical polishing.With its distinguished editors and international team of expert contributors Tribocorrosion of passive metals and coatings is an invaluable reference tool for engineers and researchers in industry and academia confronted with tribocorrosion problems. Comprehensively reviews current research on the tribocorrosion of passive metals and coatings, with particular reference to the design of tribocorrosion test equipment, data evaluation and the optimisation of materials’ properties for tribocorrosion systems Chapters discuss tribocorrosion mechanisms under fretting, sliding and erosion conditions before focussing on methods for measuring and preventing tribocorrosion Includes a comprehensive selection of tribocorrosion problems in engineering and medicine, such as the tribocorrosion of medical implants, and tribocorrosion issues in nuclear power plants, marine environments, automotive cooling circuits and elevated-temperature metal working

Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 906

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Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.

Author:
Publisher:
ISBN:
Category : Physics
Languages : en
Pages : 1068

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 41

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An iron-based amorphous metal, Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} (SAM2X5), with very good corrosion resistance was developed. This material was prepared as a melt-spun ribbon, as well as gas atomized powder and a thermal-spray coating. During electrochemical testing in several environments, including seawater at 90 C, the passive film stability was found to be comparable to that of high-performance nickel-based alloys, and superior to that of stainless steels, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates. This material also performed very well in standard salt fog tests. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. This material and its parent alloy maintained corrosion resistance up to the glass transition temperature, and remained in the amorphous state during exposure to relatively high neutron doses.

Author: Charles Eldon White
Publisher:
ISBN:
Category : Magnesium
Languages : en
Pages : 58

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Author: National Research Council
Publisher: National Academies Press
ISBN: 0309187680
Category : Technology & Engineering
Languages : en
Pages : 192

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The field of corrosion science and engineering is on the threshold of important advances. Advances in lifetime prediction and technological solutions, as enabled by the convergence of experimental and computational length and timescales and powerful new modeling techniques, are allowing the development of rigorous, mechanistically based models from observations and physical laws. Despite considerable progress in the integration of materials by design into engineering development of products, corrosion considerations are typically missing from such constructs. Similarly, condition monitoring and remaining life prediction (prognosis) do not at present incorporate corrosion factors. Great opportunities exist to use the framework of these materials design and engineering tools to stimulate corrosion research and development to achieve quantitative life prediction, to incorporate state-of-the-art sensing approaches into experimentation and materials architectures, and to introduce environmental degradation factors into these capabilities. Research Opportunities in Corrosion Science and Engineering identifies grand challenges for the corrosion research community, highlights research opportunities in corrosion science and engineering, and posits a national strategy for corrosion research. It is a logical and necessary complement to the recently published book, Assessment of Corrosion Education, which emphasized that technical education must be supported by academic, industrial, and government research. Although the present report focuses on the government role, this emphasis does not diminish the role of industry or academia.