Studies of Cu/ZnO-based Catalysts Under Methanol Synthesis Conditions PDF Download

Author: P. Vesborg
Publisher:
ISBN:
Category :
Languages : en
Pages : 105

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Author: Jerzy Skrzypek
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 174

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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 12

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The adsorption and deactivation characteristics of coprecipitated Cu/ZnO-based catalysts were examined and correlated to their performance in methanol synthesis from CO2 hydrogenation. The addition of Ga2O3 and Y2O3 promoters is shown to increase the Cu surface area and CO2/H2 adsorption capacities of the catalysts and enhance methanol synthesis activity. Infrared studies showed that CO2 adsorbs spontaneously on these catalysts at room temperature as both monoand bi-dentate carbonate species. These weakly bound species desorb completely from the catalyst surface by 200 °C while other carbonate species persist up to 500 °C. Characterization using N2O decomposition, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) with energy-dispersive X-ray spectroscopy (EDX) analysis clearly indicated that Cu sintering is the main cause of catalyst deactivation. Ga and Y promotion improves the catalyst stability by suppressing the agglomeration of Cu and ZnO particles under pretreatment and reaction conditions.

Author: Wh-Hsun Cheng
Publisher: CRC Press
ISBN: 9780824792237
Category : Science
Languages : en
Pages : 346

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Book Description
This work details the technical, environmental and business aspects of current methanol production processes and presents recent developments concerning the use of methanol in transportation fuel and in agriculture. It is written by internationally renowned methanol experts from academia and industry.

Author: Martyn V. Twigg
Publisher: Routledge
ISBN: 1351462326
Category : Science
Languages : en
Pages : 609

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Book Description
This book bridges the gap between theory and practice. It provides fundamental information on heterogeneous catalysis and the practicalities of the catalysts and processes used in producing ammonia, hydrogen and methanol via hydrocarbon steam reforming. It also covers the oxidation reactions in making formaldehyde from methanol, nitric acid from ammonia and sulphuric acid from sulphur dioxide. Designed for use in the chemical industry and by those in teaching, research and the study of industrial catalysts and catalytic processes. Students will also find this book extremely useful for obtaining practical information not available in more conventional textbooks.

Author: Annemie Bogaerts
Publisher: MDPI
ISBN: 3038977500
Category : Technology & Engineering
Languages : en
Pages : 248

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Book Description
Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO2 conversion into value-added chemicals and fuels, N2 fixation for the synthesis of NH3 or NOx, methane conversion into higher hydrocarbons or oxygenates. It is also widely used for air pollution control (e.g., VOC remediation). Plasma catalysis allows thermodynamically difficult reactions to proceed at ambient pressure and temperature, due to activation of the gas molecules by energetic electrons created in the plasma. However, plasma is very reactive but not selective, and thus a catalyst is needed to improve the selectivity. In spite of the growing interest in plasma catalysis, the underlying mechanisms of the (possible) synergy between plasma and catalyst are not yet fully understood. Indeed, plasma catalysis is quite complicated, as the plasma will affect the catalyst and vice versa. Moreover, due to the reactive plasma environment, the most suitable catalysts will probably be different from thermal catalysts. More research is needed to better understand the plasma–catalyst interactions, in order to further improve the applications.

Author: Stefan Zander
Publisher: Sudwestdeutscher Verlag Fur Hochschulschriften AG
ISBN: 9783838150208
Category :
Languages : en
Pages : 132

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Methanol is one of the most important industrial base chemicals and also a starting material for many organic syntheses. A steadily rising amount is used as fuel or fuel additive because methanol can serve as liquid hydrogen carrier. In the chemical industry, methanol is produced from synthesis gas over Cu/ZnO based catalysts. The catalyst is prepared by a multi-step synthesis (co-precipitation, calcination, reduction). Already in early stages of the preparation structural characteristics can provide indications for the resulting activity of the final catalyst. In order to investigate correlations between preparation parameters, microstructure and activity of Cu/ZnO based catalysts, the effects of the pH during co-precipitation and aging, use of MgO instead of ZnO and doping with Ga-ions were examined in the present work. Precursors, calcined and reduced samples were investigated with different methods (XRD, XRF, physisorption, TPR, RFC, UV-Vis spectroscopy, XAS, XPS, SEM, TEM) and selected samples were tested in methanol synthesis.

Author: Martin Bertau
Publisher: Springer Science & Business Media
ISBN: 3642397093
Category : Technology & Engineering
Languages : en
Pages : 699

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Book Description
Methanol - The Chemical and Energy Feedstock of the Future offers a visionary yet unbiased view of methanol technology. Based on the groundbreaking 1986 publication "Methanol" by Friedrich Asinger, this book includes contributions by more than 40 experts from industry and academia. The authors and editors provide a comprehensive exposition of methanol chemistry and technology which is useful for a wide variety of scientists working in chemistry and energy related industries as well as academic researchers and even decision-makers and organisations concerned with the future of chemical and energy feedstocks.

Author: B. Eliasson
Publisher: Elsevier
ISBN: 0080553036
Category : Science
Languages : en
Pages : 1225

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Book Description
These proceedings contain 270 papers outlining ideas and contributions to the new scientific, technical and political discipline of Greenhouse Gas (GHG) Control. The contributions were presented at the 4th International Conference on Greenhouse Gas Control Technologies (GHGT-4). It was the largest gathering of experts active in this new and fast-developing field.GHGT-4 was different from its predecessors in that it included all greenhouse gases, not only CO2, and all issues which could contribute to the mitigation of the greenhouse problem - technical, economic and political. The main focus was on practical solutions and real demonstrations of mitigation technology being planned and implemented today. It also addressed ways to increase the efficiency of power production and utilisation, and looked at proposals to encourage the development of renewable energy sources.During the Opening Session, 10 keynote addresses were heard from prominent personalities in government, industry and academia. To tackle this very inter-disciplinary problem and to achieve acceptable solutions, it is essential for industry and government to initiate intense dialogue and cooperation. Conferences like this can provide the opportunity for a meeting of minds between engineers and politicians in the face of global challenge. The primary attributes of this global challenge are manifold: the problem is global and international; it is inter-disciplinary, both in substance and approach; it covers technical, political and economic issues and involves government, science, industry and academia; it is complex and non-linear; and it will take the efforts of all parties involved to solve the problem.These proceedings contain ideas for starting demonstration projects and for making better use of the power and flexibility of market measures. They also show it is a problem we can influence and that there is a wealth of ideas. The challenge now is to find the right partners to put these ideas into action.

Author: Robert Schlögl
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110608596
Category : Technology & Engineering
Languages : en
Pages : 685

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Book Description
Energy – in the headlines, discussed controversially, vital. The use of regenerative energy in many primary forms leads to the necessity to store grid dimensions for maintaining continuous supply and enabling the replacement of fossil fuel systems. Chemical energy storage is one of the possibilities besides mechano-thermal and biological systems. This work starts with the more general aspects of chemical energy storage in the context of the geosphere and evolves to dealing with aspects of electrochemistry, catalysis, synthesis of catalysts, functional analysis of catalytic processes and with the interface between electrochemistry and heterogeneous catalysis. Top-notch experts provide a sound, practical, hands-on insight into the present status of energy conversion aimed primarily at the young emerging research front.