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Author: George E. Kostakis Publisher: MDPI ISBN: 3038428019 Category : Science Languages : en Pages : 131
Book Description
This book is a printed edition of the Special Issue "Structural Design and Properties of Coordination Polymers" that was published in Crystals
Author: George E. Kostakis Publisher: MDPI ISBN: 3038428019 Category : Science Languages : en Pages : 131
Book Description
This book is a printed edition of the Special Issue "Structural Design and Properties of Coordination Polymers" that was published in Crystals
Author: Mao-Chun Hong Publisher: John Wiley & Sons ISBN: 0470467320 Category : Science Languages : en Pages : 428
Book Description
Design and Construction of Coordination Polymers Edited by Mao-Chun Hong Ling Chen A Unique Resource on coordination Polymers Coordination polymers are a growing, interdisciplinary field with numerous potential applications in chemistry and materials. Design and Construction of Coordination Polymers provides a comprehensive introduction to this field, focusing on synthetic strategies, structures, properties, and potential applications. Each chapter provides a unique perspective on coordination polymers, offering a dedicated approach as well as deeper insights on the most important facets of this interdisciplinary area. Combining the consistent editorial approach of a textbook with the up-to-date data and topics usually found in the latest monographs and handbooks, Design and Construction of Coordination Polymers offers an unparalleled reference to the state of the art. Among other topics, it covers: Coordination polymers with versatile structures Crystal engineering of coordination polymers Organic/inorganic hybrid complexes based on polyoxometalates Molecular-based magnetic and ferroelectric compounds Heavy main-group iodometalates Gas storage MOFs Bioinorganic coordination complexes Addressing a wide range of readers, Design and Construction of Coordination Polymers will prove an invaluable resource to everyone from senior-level undergraduate and graduate students to working scientists.
Author: Stuart R. Batten Publisher: Royal Society of Chemistry ISBN: 0854048375 Category : Science Languages : en Pages : 440
Book Description
The field of coordination polymer research is now vast, & one of the fastest growing areas of chemistry in recent times, with important work being done on a variety of different aspects. This book provides a broad overview of all the major facets of modern coordination polymer science in the one place.
Author: Ali Morsali Publisher: John Wiley & Sons ISBN: 1119370760 Category : Science Languages : en Pages : 211
Book Description
Coordination polymer is a general term used to indicate an infinite array composed of metal ions which are bridged by certain ligands among them. This incorporates a wide range of architectures including simple one-dimensional chains with small ligands to large mesoporous frameworks. Generally, the formation process proceeds automatically and, therefore, is called a self-assembly process. In general, the type and topology of the product generated from the self-assembly of inorganic metal nodes and organic spacers depend on the functionality of the ligand and valences and the geometric needs of the metal ions used. In this book the authors explain main group metal coordination polymer in bulk and nano size with some of their application, synthesis method and etc, The properties of these efficient materials are described at length including magnetism (long-range ordering, spin crossover), porosity (gas storage, ion and guest exchange), non-linear optical activity, chiral networks, reactive networks, heterogeneous catalysis, luminescence, multifunctional materials and other properties.
Author: Nidhi Goel Publisher: Elsevier ISBN: 0323955363 Category : Technology & Engineering Languages : en Pages : 429
Book Description
Porous Coordination Polymers: From Fundamentals to Advanced Applications brings together the latest advances in Porous Coordination Polymers (PCPs) for cutting-edge applications. The book begins by introducing PCPs, highlighting their structure, chemistry, basic properties and design approaches. This is followed by a chapter focusing on synthesis methods and mechanical properties. Subsequent chapters provide in-depth coverage of specific target applications, explaining the preparation of PCPs for areas including catalysis and photocatalysis, environmental remediation, gas storage and separation, energy storage and conversion, new generation magnets, nanocarriers in therapeutics, and biomedical imaging. Finally, current challenges and future developments are considered in detail. Porous Coordination Polymers are gaining increasing interest due to their attractive properties, such as structural flexibility, large surface area, tailorable pore size, and functional tunability, in turn enabling a wide range of possible applications which this book aims to highlight and to elucidate. This is a valuable resource for researchers and advanced students across polymer science, inorganic chemistry, environmental science, and materials science and engineering, as well as engineers, scientists, and R&D professionals with an interest in porous coordination polymers (PCPs) and novel polymeric materials for advanced industrial applications. Explores porous coordination polymers in detail while highlighting key ideas. Provides in-depth discussion of the design and development of new porous coordination polymers. Addresses present issues and looks at potential future developments in this innovative field.
Author: Matthew Hurlock Publisher: ISBN: Category : Coordination polymers Languages : en Pages : 0
Book Description
Important issues such as the capture of greenhouse gases, the detection of hazardous chemicals, and the storage of energy require materials with tunable properties. Coordination polymers are a type of hybrid polymeric crystalline material formed from the connection of organic ligands and metal ions or clusters through coordination bonds. The wide array of building blocks that can be used enables coordination polymers to be rationally designed and tuned to possess specific properties. Amongst coordination polymers, Metal-Organic Frameworks (MOFs) stand out due to their porosity, large internal surface areas, and diversity of structures. These features can be achieved through direct synthesis as well as through directed modification of the framework post-synthetically. The study of the structures of MOFs and how they relate to the properties of the material, such as luminescence, is important to help gain a deeper understanding and to facilitate the development of new materials with desired functionality. Luminescent MOFs are of particular interest due to their potential as selective chemical sensors. Ligand-based fluorescence is one of the most common forms of luminescence in MOFs. Ligands built from the molecule tetraphenylethene (TPE) are ideal candidates for these systems. The aggregation-induced emission properties of TPE molecules can be enhanced through rigidification within a coordination network. This work seeks to further understand how the structures of TPE MOFs relate to the properties of the framework. To accomplish this, a variety of new coordination polymers were synthesized using TPE ligands with carboxylate functionalization at the para- and meta-positions. The fluorescent properties of coordination polymers constructed from para-functionalized TPE ligands was controlled through post-synthetic insertion of additional ligands. Coordination polymers formed from meta-functionalized TPE ligands tended to form dense, non-porous structures but the properties of these materials could be controlled through mixed ligand synthesis. This approach allowed for the control of the fluorescence emission as well as the porosity of the frameworks. Through this work, a better understanding of how TPE ligands and their conformations influence the structure and properties of coordination polymers is gained, which will aid in the rational design of these types of materials.
Author: Ali Morsali Publisher: John Wiley & Sons ISBN: 1119792045 Category : Science Languages : en Pages : 226
Book Description
METAL-ORGANIC FRAMEWORKS WITH HETEROGENEOUS STRUCTURES A unique book that sheds light on Metal-Organic Frameworks complex systems that often display behaviors that surprise and cannot be easily described. In this book, MOF-based heterostructures technology with key characteristics is completely analyzed and the current state-of-the-art is discussed. The authors focus on the complex heterostructures promoted by MOFs with advantage of their recent new advances for various applications with particular emphasis on their design. As an extension of the design and synthesis, the shaping technology of heterostructure MOFs is also of great significance to the future practical applications in industry (adsorption/desorption, gas storage, catalysis, conductivity, optical activity) of this class of complex porous materials. As this unique book covers all of the aspects of complexity in MOFs with heterogeneous structures, it serves as an essential reference to the concepts of introducing complexity to designing the future new platforms of materials with advanced and superior properties. This important compact book provides the reader with: The principal aspects of heterogeneity that produce complexity in MOFs, their effects in the structure chemistry, performance and applications The effects of complexities on the structure of metal-organic frameworks The roles of complexities on metal-organic frameworks applications Explanation of synthesis strategies of the complex heterostructure MOFs. Audience This book will be beneficial for chemists, materials engineers, advanced postgraduate and graduate students, researchers and specialists who are working in the area of materials design and their chemistry, porous crystalline materials, coordination polymers, hybrid and functional materials, as well as industry professionals, such as those working on selective catalysis and adsorption-separation, optics, gas capture, processes of biological and pharmaceutical.
Author: Xinyue Zhang Publisher: ISBN: Category : Languages : en Pages : 0
Book Description
Incorporating dynamic interactions into polymer matrices has emerged as a powerful tool to engineer materials for advanced applications. Metal-ligand coordination as the dynamic component has been a popular choice due to the diversity and ease of tailoring the functional sites without altering the backbone chemistry. Extensive theoretical and experimental studies have been conducted to unveil the fundamental science and critical mechanisms for better material design. The sticky Rouse model has been developed to describe the linear viscoelasticity of associative polymers neglecting the chemistry and structural details of bonding sites. Most of the experimental research on polymers containing metal-ligand coordination has focused on synthesis methods or the optical and mechanical effects resulting from bonds breaking and reforming. A gap between the theoretical understanding and the experimental findings exists due to the challenge of decoupling the metal-ligand interactions from other factors governing the bulk polymer behavior. In addition, the dynamic surface properties and ionic conductivity performances arising from metal-ligand coordination are less studied. This dissertation contributes to the understanding of the structure-property relationships of metal-ligand coordinated polymers by bridging the molecular metal-ligand coordination details and the macroscopic behavior of the materials with carefully designed model systems. This dissertation starts with a combined experimental and theoretical approach to quantitatively establishing how the stability and structure of metal-ligand interaction acting as dynamic crosslinks determines the viscoelastic characteristics of a metallopolymer. A model system which is free from solvent molecules, chain entanglement and phase-separation was designed to decouple the metal-ligand interactions from other factors governing the polymer behavior. By analyzing the key parameters extracted from the experimental results, the enhanced sticky Rouse model was proposed. This assists subsequent rational design of metal-ligand coordinated polymers with an easily accessible and implementable quantitative model. We then moved on to demonstrate that introducing metal-ligand coordination not only enables the dynamic characteristics of the polymer, but also raises other fascinating properties. This idea was elaborated in the following two works. First, we proposed a surface design approach to enable a reversible transition between hydrophobicity and hydrophilicity on the polymer surface in response to changing the environment polarity via "hiding" polar metal-ligand coordination sites under non-polar PDMS backbone. The dynamic characteristics of the bulk polymer is governed by network architecture and coordination strength, and is directly correlated to the speed and extent of the surface evolution. Second, we investigated the ionic conductivity of metal-ligand coordinated PDMS. The interaction between the ligands on a polymer chain and the metal cations from the salt added facilities the ion dissociation within the PDMS, and turns the non-conductive PDMS into an ionic conductive PDMS. The ionic transport mechanism was discussed in the context of the density and strength of metal-ligand coordination. Synergistic effects were observed and discussed for mixed lithium (Li) and copper (Cu) coordination, which shows the improved mechanical strength as well as ionic conductivity compared to the Li-coordinated PDMS. The systematic study on the structure-property relationships of polymers containing metal-ligand coordination in this dissertation provides insights to assist the design of advanced materials.
Author: George E. Kostakis
Author: George E. Kostakis
Author: George Kostakis
Author: Mao-Chun Hong
Author: Stuart R. Batten
Author: Ali Morsali
Author: Nidhi Goel
Author: 楊翔凱
Author: Matthew Hurlock
Author: Ali Morsali
Author: Xinyue Zhang