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Author: H.L. Frisch Publisher: Elsevier ISBN: 0323149901 Category : Science Languages : en Pages : 449
Book Description
Simple Dense Fluids is a nine-chapter text that explores the chemistry and physics of simple fluid systems. Simple systems primarily include the noble gases, the homonuclear diatomic molecules, and a select group of some polyatomic but spherically symmetrical molecules. The opening chapter describes the change of thermodynamic functions along the saturation line and how these functions can best be obtained from sets of measurements that are often in conflict, with an emphasis on the functions of three simple liquids: argon, nitrogen, and oxygen. The following chapter outlines the basic thermodynamic and statistical mechanical ideas that have been applied to the liquid-vapor interface, followed by a summary of surface tension data of simple fluids. Considerable chapters are devoted to X-ray, light, and neutron scattering measurements on simple dense fluids. This book further discusses the use of electromagnetic data, especially the dielectric constant and refractive index, in the interpretation of molecular interactions and molecular structure. The available experimental data on several nonpolar liquids and liquid mixtures are also provided. The final chapters survey the nuclear relaxation and spectroscopic data in simple liquids. These chapters also present experimental data relevant to transport phenomena in simple fluids. Workers and researchers in the field of simple dense fluids will find this book of great value.
Author: H.L. Frisch Publisher: Elsevier ISBN: 0323149901 Category : Science Languages : en Pages : 449
Book Description
Simple Dense Fluids is a nine-chapter text that explores the chemistry and physics of simple fluid systems. Simple systems primarily include the noble gases, the homonuclear diatomic molecules, and a select group of some polyatomic but spherically symmetrical molecules. The opening chapter describes the change of thermodynamic functions along the saturation line and how these functions can best be obtained from sets of measurements that are often in conflict, with an emphasis on the functions of three simple liquids: argon, nitrogen, and oxygen. The following chapter outlines the basic thermodynamic and statistical mechanical ideas that have been applied to the liquid-vapor interface, followed by a summary of surface tension data of simple fluids. Considerable chapters are devoted to X-ray, light, and neutron scattering measurements on simple dense fluids. This book further discusses the use of electromagnetic data, especially the dielectric constant and refractive index, in the interpretation of molecular interactions and molecular structure. The available experimental data on several nonpolar liquids and liquid mixtures are also provided. The final chapters survey the nuclear relaxation and spectroscopic data in simple liquids. These chapters also present experimental data relevant to transport phenomena in simple fluids. Workers and researchers in the field of simple dense fluids will find this book of great value.
Author: G.H.A. Cole Publisher: Elsevier ISBN: 1483214591 Category : Technology & Engineering Languages : en Pages : 298
Book Description
An Introduction to the Statistical Theory of Classical Simple Dense Fluids covers certain aspects of the study of dense fluids, based on the analysis of the correlation effects between representative small groupings of molecules. The book starts by discussing empirical considerations including the physical characteristics of fluids; measured molecular spatial distribution; scattering by a continuous medium; the radial distribution function; the mean potential; and the molecular motion in liquids. The text describes the application of the theories to the description of dense fluids (i.e. interparticle force, classical particle trajectories, and the Liouville Theorem) and the deduction of expressions for the fluid thermodynamic functions. The theory of equilibrium short-range order by using the concept of closure approximation or total correlation; some numerical consequences of the equilibrium theory; and irreversibility are also looked into. The book further tackles the kinetic derivation of the Maxwell-Boltzmann (MB) equation; the statistical derivation of the MB equation; the movement to equilibrium; gas in a steady state; and viscosity and thermal conductivity. The text also discusses non-equilibrium liquids. Physicists, chemists, and engineers will find the book invaluable.
Author: K. Stephan Publisher: Springer Science & Business Media ISBN: 1475769318 Category : Technology & Engineering Languages : en Pages : 273
Book Description
The physical properties of fluids are perhaps among the most extensively investigated physical constants of any single group of materials. This is particularly true of the thermodynamic prop erties of pure substances since the condition of thermodynamic equilibrium provides the simplest considerations for experimental measurement as well as theoretical treatment. In the case of non equilibrium transport properties, the situation is significantly complicated by the necessity of measurement of gradients in the experiment and the mathematical difficulties in handling non equilibrium distribution functions in theoretical treatments. Hence, our knowledge of the trans port properties of gases and liquids is perhaps one order of magnitude lower than for equilibrium thermodynamic properties. This situation is very much apparent when examining the available nu merical data on the viscosity of fluids particularly at high pressures. In this work, the authors have performed an outstanding contribution to the engineering literature by their critical evaluation of the pressure dependence of the available data on the viscosity of selected substances. The recommended values reported in the tables and figures also incorporate the saturated liquid and gas states as well as the data of the dilute gas in an attempt to integrate the present work with the recently published work by CINDAS/Purdue University on the viscosity of fluids at low pressures [166]. A deliberate effort was made to treat as many of the substances in the CINDAS volume as possible for which adequate high pressure data exist.
Author: Jean-Pierre Hansen Publisher: Elsevier ISBN: 0080571018 Category : Science Languages : en Pages : 569
Book Description
This book gives a comprehensive and up-to-date treatment of the theory of "simple" liquids. The new second edition has been rearranged and considerably expanded to give a balanced account both of basic theory and of the advances of the past decade. It presents the main ideas of modern liquid state theory in a way that is both pedagogical and self-contained. The book should be accessible to graduate students and research workers, both experimentalists and theorists, who have a good background in elementary mechanics. Compares theoretical deductions with experimental results Molecular dynamics Monte Carlo computations Covers ionic, metallic, and molecular liquids
Author: Karl Stephan Publisher: Springer ISBN: 9781475769333 Category : Technology & Engineering Languages : en Pages : 268
Book Description
The physical properties of fluids are perhaps among the most extensively investigated physical constants of any single group of materials. This is particularly true of the thermodynamic prop erties of pure substances since the condition of thermodynamic equilibrium provides the simplest considerations for experimental measurement as well as theoretical treatment. In the case of non equilibrium transport properties, the situation is significantly complicated by the necessity of measurement of gradients in the experiment and the mathematical difficulties in handling non equilibrium distribution functions in theoretical treatments. Hence, our knowledge of the trans port properties of gases and liquids is perhaps one order of magnitude lower than for equilibrium thermodynamic properties. This situation is very much apparent when examining the available nu merical data on the viscosity of fluids particularly at high pressures. In this work, the authors have performed an outstanding contribution to the engineering literature by their critical evaluation of the pressure dependence of the available data on the viscosity of selected substances. The recommended values reported in the tables and figures also incorporate the saturated liquid and gas states as well as the data of the dilute gas in an attempt to integrate the present work with the recently published work by CINDAS/Purdue University on the viscosity of fluids at low pressures [166]. A deliberate effort was made to treat as many of the substances in the CINDAS volume as possible for which adequate high pressure data exist.
Author: Jean-Pierre Hansen Publisher: Academic Press ISBN: 012387033X Category : Science Languages : en Pages : 637
Book Description
Comprehensive coverage of topics in the theory of classical liquids Widely regarded as the standard text in its field, Theory of Simple Liquids gives an advanced but self-contained account of liquid state theory within the unifying framework provided by classical statistical mechanics. The structure of this revised and updated Fourth Edition is similar to that of the previous one but there are significant shifts in emphasis and much new material has been added. Major changes and Key Features in content include: Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchical reference theory of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation. Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchian reference of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation.
Author: H.L. Frisch
Author: H.L. Frisch
Author: Harry Lloyd Frisch
Author: Harry Lloyd Frisch
Author: G.H.A. Cole
Author: K. Stephan
Author: Arnold Kaufmann
Author: Jean-Pierre Hansen
Author: Karl Stephan
Author: Jean-Pierre Hansen
Author: G. H. A. Cole