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Combustion Chemistry

Combustion Chemistry PDF Author: W. C. Jr. Gardiner
Publisher: Springer Science & Business Media
ISBN: 1468401866
Category : Science
Languages : en
Pages : 515

Book Description
Detailed study of the rates and mechanisms of combustion reactions has not been in the mainstream of combustion research until the recent recognition that further progress in optimizing burner performance and reducing pollutant emission can only be done with fundamental understanding of combustion chemistry. This has become apparent at a time when our understanding of the chemistry, at least of small-molecule combustion, and our ability to model combustion processes on large computers have developed to the point that real confidence can be placed in the results. This book is an introduction for outsiders or beginners as well as a reference work for people already active in the field. Because the spectrum of combustion scientists ranges from chemists with little computing experience to engineers who have had only one college chemistry course, everything needed to bring all kinds of beginners up to the level of current practice in detailed combustion modeling is included. It was a temptation to include critical discussions of modeling results and computer programs that would enable outsiders to start quickly into problem solving. We elected not to do either, because we feel that the former are better put into the primary research literature and that people who are going to do combustion modeling should either write their own programs or collaborate with experts. The only exception to this is in the thermochemical area, where programs have been included to do routine fitting operations. For reference purposes there are tables of thermochemical, transport-property, and rate coefficient data.

Combustion Chemistry

Combustion Chemistry PDF Author: W. C. Jr. Gardiner
Publisher: Springer Science & Business Media
ISBN: 1468401866
Category : Science
Languages : en
Pages : 515

Book Description
Detailed study of the rates and mechanisms of combustion reactions has not been in the mainstream of combustion research until the recent recognition that further progress in optimizing burner performance and reducing pollutant emission can only be done with fundamental understanding of combustion chemistry. This has become apparent at a time when our understanding of the chemistry, at least of small-molecule combustion, and our ability to model combustion processes on large computers have developed to the point that real confidence can be placed in the results. This book is an introduction for outsiders or beginners as well as a reference work for people already active in the field. Because the spectrum of combustion scientists ranges from chemists with little computing experience to engineers who have had only one college chemistry course, everything needed to bring all kinds of beginners up to the level of current practice in detailed combustion modeling is included. It was a temptation to include critical discussions of modeling results and computer programs that would enable outsiders to start quickly into problem solving. We elected not to do either, because we feel that the former are better put into the primary research literature and that people who are going to do combustion modeling should either write their own programs or collaborate with experts. The only exception to this is in the thermochemical area, where programs have been included to do routine fitting operations. For reference purposes there are tables of thermochemical, transport-property, and rate coefficient data.

Combustion Measurements

Combustion Measurements PDF Author: Norman Chigier
Publisher: CRC Press
ISBN: 1040292305
Category : Technology & Engineering
Languages : en
Pages : 551

Book Description
The book begins with an introduction to the general problems of making measurements in high temperature and a presentation of chemically reacting flow systems. It describes each instrument with the various diagnostic techniques and discusses measurements that have been made in furnaces, flames, and rocket engines. The detailed measurement techniques described in this book cover a wide spectrum of applications in combustion systems, including gas turbine, rocket measurement techniques that were developed in laboratories. Information obtained on detailed temperature, velocity, particle size, and gas concentration distribution is leading to improve understanding of the chemical combustion process and to design imporvements in combustors.

Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels

Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels PDF Author: Wenyu Sun
Publisher: Springer Nature
ISBN: 9819945100
Category : Technology & Engineering
Languages : en
Pages : 178

Book Description
In this thesis, attention was paid to several novel oxygenated fuels—carbonates, polyethers and ketones. Combustion kinetic investigations were performed for typical representative compounds, including dimethyl carbonate, diethyl carbonate, cyclopentanone, 3-pentanone, 1,2-dimethoxyethane and dimethoxymethane. For experiments, suitable diagnostic techniques were used to measure the detailed speciation information of the target fuels under different conditions. For kinetic modeling, rate coefficients for crucial elementary reactions were obtained through high-level theoretical calculations. Based on that, validated kinetic models with good predictive performances were developed. On the basis of experimental measurements and model interpretations, this work highlighted two important combustion characteristics regarding the practical use: the pollutant formation and the ignition performance. Besides, the correlation between oxygen-containing functional groups and the aforementioned combustion characteristics was revealed. To reveal the potential interactions between the reaction networks of oxygenated additives and the hydrocarbon base fuels during combustion. Chemical structures of laminar premixed flames fueled by binary fuels were measured, and by changing the initial fuel compositions, the addition effects of the oxygenates on the fuel consumption and pollutant formation behaviors were explored. It was found that complicated chemical interactions do not exist in the reaction networks under the investigated conditions.

Ninth Symposium (International) on Combustion

Ninth Symposium (International) on Combustion PDF Author: Sam Stuart
Publisher: Elsevier
ISBN: 1483261573
Category : Science
Languages : en
Pages : 1118

Book Description
Ninth Symposium (International) on Combustion covers the proceedings of the Ninth Symposium (International) on Combustion, held at Cornell University in Ithaca, New York on August 27 to September 1, 1962, under the auspices of the Combustion Institute. The book focuses on the processes and reactions involved in combustion. The selection first offers information on flame strength of propane-oxygen flames at low pressures in turbulent flow and mixing and flow in ducted turbulent jets. Topics include radial profile of the jetting velocity, radial growth of the jet, and mixing zones of a ducted jet. The text then elaborates on turbulent flame studies in two-dimensional open burners; turbulent mass transfer and rates of combustion in confined turbulent flames; and flame stabilization in a boundary layer. The publication examines the theoretical study of properties of laminar steady state flames as a function of properties of their chemical components and spectra of alkali metal-organic halide flames. The text then takes a look at the thermal radiation theory for plane flame propagation in coal dust clouds; flame characteristics of the diborane-hydrazine system; and studies of the combustion of dimethyl hydrazine and related compounds. The selection is a dependable reference for readers interested in the processes and reactions involved in combustion.

Applied Combustion Diagnostics

Applied Combustion Diagnostics PDF Author: Katharina Kohse-Hoinghaus
Publisher: CRC Press
ISBN: 1498719414
Category : Technology & Engineering
Languages : en
Pages : 734

Book Description
The editors have assembled a world-class group of contributors who address the questions the combustion diagnostic community faces. They are chemists who identify the species to be measured and the interfering substances that may be present; physicists, who push the limits of laser spectroscopy and laser devices and who conceive suitable measuremen

Shock Waves @ Marseille II

Shock Waves @ Marseille II PDF Author: Raymond Brun
Publisher: Springer Science & Business Media
ISBN: 3642788327
Category : Science
Languages : en
Pages : 474

Book Description
Recently, there have been significant advances in the fields of high-enthalpy hypersonic flows, high-temperature gas physics, and chemistry shock propagation in various media, industrial and medical applications of shock waves, and shock-tube technology. This series contains all the papers and lectures of the 19th International Symposium on Shock Waves held in Marseille in 1993. They will be published in four topical volumes, each containing papers on related topics, and preceded by an overview written by a leading international expert. The volumes may be purchased independently.

Proceedings

Proceedings PDF Author:
Publisher:
ISBN:
Category : Detonation waves
Languages : en
Pages : 1532

Book Description


Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion PDF Author:
Publisher: Elsevier
ISBN: 0128195797
Category : Technology & Engineering
Languages : en
Pages : 1034

Book Description
Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications.

Gaseous Detonations

Gaseous Detonations PDF Author: M.A. Nettleton
Publisher: Springer Science & Business Media
ISBN: 9400931492
Category : Medical
Languages : en
Pages : 266

Book Description
My introduction to the fascinating phenomena associated with detonation waves came through appointments as an external fellow at the Department of Physics, University College of Wales, and at the Department of Mechanical Engineering, University of Leeds. Very special thanks for his accurate guidance through the large body of information on gaseous detonations are due to Professor D. H. Edwards of University College of Wales. Indeed, the onerous task of concisely enumerating the key features of unidimensional theories of detonations was undertaken by him, and Chapter 2 is based on his initial draft. When the text strays to the use of we, it is a deserved acknow ledgement of his contribution. Again, I should like to thank Professor D. Bradley of Leeds University for his enthusiastic encouragement of my efforts at developing a model of the composition limits of detonability through a relationship between run-up distance and composition of the mixture. The text has been prepared in the context of these fellowships, and I am grateful to the Central Electricity Generating Board for its permission to accept these appointments.

Chemically Reacting Flow

Chemically Reacting Flow PDF Author: Robert J. Kee
Publisher: John Wiley & Sons
ISBN: 047146130X
Category : Science
Languages : en
Pages : 884

Book Description
Complex chemically reacting flow simulations are commonly employed to develop quantitative understanding and to optimize reaction conditions in systems such as combustion, catalysis, chemical vapor deposition, and other chemical processes. Although reaction conditions, geometries, and fluid flow can vary widely among the applications of chemically reacting flows, all applications share a need for accurate, detailed descriptions of the chemical kinetics occurring in the gas-phase or on reactive surfaces. Chemically Reacting Flow: Theory and Practice combines fundamental concepts in fluid mechanics and physical chemistry, assisting the student and practicing researcher in developing analytical and simulation skills that are useful and extendable for solving real-world engineering problems. The first several chapters introduce transport processes, primarily from a fluid-mechanics point of view, incorporating computational simulation from the outset. The middle section targets physical chemistry topics that are required to develop chemically reacting flow simulations, such as chemical thermodynamics, molecular transport, chemical rate theories, and reaction mechanisms. The final chapters deal with complex chemically reacting flow simulations, emphasizing combustion and materials processing. Among other features, Chemically Reacting Flow: Theory and Practice: -Advances a comprehensive approach to interweaving the fundamentals of chemical kinetics and fluid mechanics -Embraces computational simulation, equipping the reader with effective, practical tools for solving real-world problems -Emphasizes physical fundamentals, enabling the analyst to understand how reacting flow simulations achieve their results -Provides a valuable resource for scientists and engineers who use Chemkin or similar software Computer simulation of reactive systems is highly effective in the development, enhancement, and optimization of chemical processes. Chemically Reacting Flow helps prepare both students and professionals to take practical advantage of this powerful capability.