Author: Harutun G. KarianPublisher:
ISBN:
Category : Molecular orbitals
Languages : en
Pages : 168
Book Description
Semi-rigorous Molecular Orbital Calculation of Transition Metal Complexes
Author: Harutun G. KarianPublisher:
ISBN:
Category : Molecular orbitals
Languages : en
Pages : 168
Book Description
Molecular Orbitals of Transition Metal Complexes
Author: Yves JeanPublisher: Oxford University Press
ISBN: 0198530935
Category : Science
Languages : en
Pages : 288
Book Description
This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.
Molecular Orbital Calculations for Octahedral Transition Metal Complexes of CO, CN- and N2
Author: Kenneth George CaultonPublisher:
ISBN:
Category : Complex compounds
Languages : en
Pages : 246
Book Description
Molecular Orbital Calculations for Transition Metal Complexes Containing Pi-acceptor Ligands
Author: Roger L. DeKockPublisher:
ISBN:
Category : Ligand field theory
Languages : en
Pages : 606
Book Description
A Theoretical Study of the Electronic Structure of Transition-metal Complexes
Author: James W. RichardsonPublisher:
ISBN:
Category : Atoms
Languages : en
Pages : 128
Book Description
Approximate Molecular Orbital Calculations on Large Low Summetry Transition Metal Complexes
Author: Michael Bishop HallMolecular Orbital Calculations for Transition Metal Complexes, Infrared Studies of Some Fluorozirconates
Author: Rex StoessigerPublisher:
ISBN:
Category : Molecular orbitals
Languages : en
Pages : 118
Book Description
Molecular Orbital Calculations for Transition Metal Chlorides
Author: Douglas Dean RadtkePublisher:
ISBN:
Category : Chlorides
Languages : en
Pages : 298
Book Description
On Being Well-coordinated: A Half-century Of Research On Transition Metal Complexes
Author: John L BurmeisterPublisher: World Scientific
ISBN: 9814488003
Category : Science
Languages : en
Pages : 654
Book Description
This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
Inorganica chimica acta
Author: Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 308
Book Description