Photoionization and Photo-Induced Processes in Mass Spectrometry PDF Download

Author: Ralf Zimmermann
Publisher: John Wiley & Sons
ISBN: 3527335102
Category : Science
Languages : en
Pages : 448

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Book Description
Provides comprehensive coverage of laser-induced ionization processes for mass spectrometry analysis Drawing on the expertise of the leading academic and industrial research groups involved in the development of photoionization methods for mass spectrometry, this reference for analytical scientists covers both the theory and current applications of photo-induced ionization processes. It places widely used techniques such as MALDI side by side with more specialist approaches such as REMPI and RIMS, and discusses leading edge developments in ultrashort laser pulse desorption, to give readers a complete picture of the state of the technology. Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications starts with a complete overview of the fundamentals of the technique, covering the basics of the gas phase ionization as well as those of laser desorption and ablation, pulse photoionization, and single particle ionization. Numerous application examples from different analytical fields are described that showcase the power and the wide scope of photo ionization in mass spectrometry. -The first general reference book on photoionization techniques for mass spectrometry -Examines technologies and applications of gas phase resonance-enhanced multiphoton ionization mass spectrometry (REMPI-MS) and gas phase resonance ionization mass spectrometry (RIMS) -Provides complete coverage of popular techniques like MALDI -Discusses the current and potential applications of each technology, focusing on process and environmental analysis Photoionization and Photo-Induced Processes in Mass Spectrometry: Fundamentals and Applications is an excellent book for spectroscopists, analytical chemists, photochemists, physical chemists, and laser specialists.

Author: V. S. Letokhov
Publisher: Springer
ISBN: 9783662134870
Category : Technology & Engineering
Languages : en
Pages : 466

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Book Description
The laser as a source of coherent optical radiation has made it possible to investigate nonlinear interaction of optical radiation with atoms and mole cules. Its availability has given rise to new research fields, such as non linear optics, laser spectroscopy, laser photochemistry, that lie at the boundary between quantum electronics and physical optics, optical spectros copy and photochemistry, respectively. The use of coherent optical radiation in each of these fields has led to the discovery of qualitatively ne\~ effects and possibilities; in particular, some rather subtle effects of interaction between highly monochromatic light and atoms and molecules, in optical spec troscopy, have formed the bases for certain methods of so-called nonlinear, laser Doppler-free spectroscopy. These methods have made it possible to in 5 6 crease the resolution of spectroscopic studies from between 10 and 10 , lim 11 ited by Doppl er 1 i ne broadeni ng up, to about 10 ; at present some 1 abor atories are developing new techniques that have even higher resolution. The discovery and elaboration of the methods of nonlinear laser spectroscopy have resulted largely from contributions by scientists from many countries, in particular from the USA (Massachusetts Institute of Technology, Stanford Uni versity, National Bureau of Standards in Boulder, Harvard University, etc. ), the USSR (P. N. Levedev Institute of Physics, Institute of Semiconductor Phys ics in Novosibirsk, Institute of Spectroscopy, etc.

Author: Sabine Becker
Publisher: John Wiley & Sons
ISBN: 9780470517208
Category : Science
Languages : en
Pages : 514

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Book Description
Providing an exhaustive review of this topic, Inorganic Mass Spectrometry: Principles and Applications provides details on all aspects of inorganic mass spectrometry, from a historical overview of the topic to the principles and functions of mass separation and ion detection systems. Offering a comprehensive treatment of inorganic mass spectrometry, topics covered include: Recent developments in instrumentation Developing analytical techniques for measurements of trace and ultratrace impurities in different materials This broad textbook in inorganic mass spectrometry, presents the most important mass spectrometric techniques used in all fields of analytical chemistry. By covering recent developments and advances in all fields of inorganic mass spectrometry, this text provides researchers and students with information to answer any questions on this topic as well as providing the basic fundamentals for understanding this potentially complex, but increasingly relevant subject.

Author: Philippe Schmitt-Kopplin
Publisher: Elsevier
ISBN: 0128140143
Category : Science
Languages : en
Pages : 780

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Book Description
Fundamentals and Applications of Fourier Transform Mass Spectrometry is the first book to delve into the underlying principles on the topic and their linkage to industrial applications. Drs. Schmitt-Kopplin and Kanawati have brought together a team of leading experts in their respective fields to present this technique from many different perspectives, describing, at length, the pros and cons of FT-ICR and Orbitrap. Numerous examples help researchers decide which instruments to use for their particular scientific problem and which data analysis methods should be applied to get the most out of their data. - Covers FT-ICR-MS and Orbitrap's fundamentals, enhancing researcher knowledge - Includes details on ion sources, data processing, chemical analysis and imaging - Provides examples across the wide spectrum of applications, including omics, environmental, chemical, pharmaceutical and food analysis

Author: Thomas Day Goodacre
Publisher:
ISBN: 9783030738907
Category :
Languages : en
Pages : 0

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Book Description
This thesis explores two distinct applications of laser spectroscopy: the study of nuclear ground state properties, and element selective radioactive ion beam production. It also presents the methods and results of an investigation into isotope shifts in the mercury isotopic chain. These Resonance Ionization Laser Ion Source (RILIS) developments are detailed, together with an RILIS ionization scheme that allowed laser ionized ion beams of chromium, germanium, radium and tellurium to be generated at the Isotope Mass Separator On-Line (ISOLDE) facility. A combination of laser spectroscopy with decay spectroscopy and mass spectrometry unambiguously demonstrated a cessation of the extreme shape staggering first observed in the 1970s and revealed the characteristic kink at the crossing of the N=126 shell closure. A series of RILIS developments were required to facilitate this experiment, including mercury "ionization scheme" development and the coupling of the RILIS with an arc discharge ion source. Laser spectroscopy has since become a powerful tool for nuclear physics and the Resonance Ionization Laser Ion Source (RILIS), of the ISOLDE facility at CERN, is a prime example. Highlighting important advances in this field, the thesis offers a unique and revealing resource. .

Author: Charles M. Miller
Publisher: CRC Press
ISBN: 9780750302302
Category : Science
Languages : en
Pages : 376

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Book Description
Resonance Ionization Spectroscopy 1992 brings together developments in resonance ionization spectroscopy (RIS), an ultrasensitive analytical technique for elemental or isotopic analysis. The development of RIS in this book is of great interest to researchers in laboratories working in physics, chemistry, materials science, and earth and environmental sciences.

Author: John C. Travis
Publisher: John Wiley & Sons
ISBN: 9780471576846
Category : Technology & Engineering
Languages : en
Pages : 374

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Book Description
Laser-enhanced ionization (LEI) is a type of optical spectrometrythat employs photoexcitation to ionize atoms selectively. Over thepast two decades, this method--originally known as the optogalvaniceffect--has been the object of extensive worldwide research and thesubject of numerous papers and published articles. Until now,however, no single volume has presented this wealth of theory anddata in a cohesive and accessible form. Laser-Enhanced Ionization Spectrometry fills this gap in theliterature. It synthesizes vast amounts of information previouslyavailable only through scattered research papers and covers everyaspect of the technology, from underlying principles and theory tomethodology and applications. This book examines the state of theart of LEI, compares it with other methods, and demonstrates howlaser-enhanced collisional ionization is especially well suited toanalytical atomic spectrometry. The contributors to this collaborative effort--from Russia,Australia, Europe, and the United States--clarify terminology,explain the inner workings of LEI, and offer derivations for bothidealized forms and realistic approximations. They also analyze thecapabilities and limitations of this technique as an analyticalmethod, including instrumentation, sources of noise, limits ofdetection, interferences, and applications. After concentrating largely on flame LEI as the most commonly usedmethod to derive LEI measurements, the discussion moves to thedevelopment of nonflame technologies for LEI. There is alsoextended coverage of the relationship between LEI and laser-inducedfluorescence, including an examination of the interplay oflaser-induced ionization and fluorescence techniques in differentatomic and molecular reservoirs. Laser-Enhanced Ionization Spectrometry places understanding,usefulness, and practical applications ahead of detailedderivations. For practicing analytical chemists andspectroscopists, it offers a clear and uncluttered approach to acomplex subject, as well as a fresh perspective on a still-emergingtechnology. This book sums up the present understanding and state of the art oflaser-enhanced ionization (LEI)-a unique but underutilized tool foranalytical atomic spectrometry. LEI possesses the special abilityto ionize atoms selectively. The text focuses on the role of thistechnology in analytical chemistry, and covers both theory andapplications in one complete, self-contained volume. Carefully crafted by leading experts from around the globe, withcontributions under six key headings, Laser-Enhanced IonizationSpectrometry * Draws on hundreds of research papers to create a comprehensivereference for LEI * Describes in depth how ions are produced, and how a signal isgenerated and detected * Provides an extensive and up-to-date compilation of published LEIdetection limits * Emphasizes basic understanding and practical applications ratherthan detailed derivations * Discusses terms and definitions and clears up sources ofconfusion in the field * Offers up-to-date coverage of instrumentation and applications * Evaluates the usefulness of LEI as an analytical tool * Deals with questions of limits of detection, interference, andnoise * Devotes an entire segment to nonflame technologies for LEI * Extends the discussion to fluorescence techniques and how theycan be interrelated with LEI in various atomic and molecularreservoirs

Author: Kara Marie Lynch
Publisher: Springer
ISBN: 9783319361383
Category : Science
Languages : en
Pages : 0

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Book Description
This work details an application of collinear resonance ionization spectroscopy for the separation of short-lived isomeric states and their subsequent study with decay spectroscopy. It reports the successful construction of a novel decay spectroscopy apparatus that can operate at pressures below 1 x 10^-9 mbar. The method is demonstrated by separating the nuclear ground and isomeric states of 204Fr and performing alpha-decay spectroscopy. An equivalent mass spectrometer would require 4.6 million times as much resolution to achieve the same result. This work unambiguously confirms the existence of a second isomeric state in 204Fr. The author also demonstrates the effectiveness of this method for laser spectroscopy and identification of hyperfine-structure components with energy tagging. This method was successfully used in 202Fr to identify ground and isomeric states. The measurement of 202Fr reported in this thesis demonstrates a factor of 100 improvement in sensitivity compared to state-of-the-art fluorescence techniques. The work reported in this thesis won the author the IOP Nuclear Physics Group Early Career Prize.

Author: Helmut H. Telle
Publisher: John Wiley & Sons
ISBN: 9780470059401
Category : Science
Languages : en
Pages : 516

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Book Description
Laser Chemistry: Spectroscopy, Dynamics and Applications provides a basic introduction to the subject, written for students and other novices. It assumes little in the way of prior knowledge, and carefully guides the reader through the important theory and concepts whilst introducing key techniques and applications.

Author: Marek Domin
Publisher: Royal Society of Chemistry
ISBN: 1849739269
Category : Science
Languages : en
Pages : 528

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Book Description
Ambient ionization has emerged as one of the hottest and fastest growing topics in mass spectrometry enabling sample analysis with minimal sample preparation. Introducing the subject and explaining the basic concepts and terminology, this book will provide a comprehensive, unique treatise devoted to the subject. Written by acknowledged experts, there are full descriptions on how new ionization techniques work, with an overview of their strengths, weaknesses and applications. This title will bring the reader right up to date, with both applications and theory, and will be suitable as a tutorial text for those starting in the field from a variety of disciplines.