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Dispersive Kinetics

Dispersive Kinetics PDF Author: Andrzej Plonka
Publisher: Springer Science & Business Media
ISBN: 9401596581
Category : Science
Languages : en
Pages : 238

Book Description
Dynamical processes in which many timescales coexist are called dispersive. The rate coefficients for dispersive processes depend on time. In the case of a chemical reaction, the time dependence of the rate coefficient, k(t), termed the specific reaction rate, is rationalized in the following way. Reactions by their very nature have to disturb reactivity distributions of the reactants in condensed media, as the more reactive species are the first ones to disappear from the system. The extent of this disturbance depends on the ratio of the rates of reactions to the rate of internal rearrangements (mixing) in the system restoring the initial distribution in reactivity of reactants. If the rates of chemical reactions exceed the rates of internal rearrangements, then the initial distributions in reactant reactivity are not preserved during the course of reactions and the specific reaction rates depend on time. Otherwise the extent of disturbance is negligible and classical kinetics, with a constant specific reaction rate, k, termed the reaction rate constant, may be valid as an approximation. In condensed media dispersive dynamical processes are endemic and this is the first monograph devoted to these processes.

Dispersive Kinetics

Dispersive Kinetics PDF Author: Andrzej Plonka
Publisher: Springer Science & Business Media
ISBN: 9401596581
Category : Science
Languages : en
Pages : 238

Book Description
Dynamical processes in which many timescales coexist are called dispersive. The rate coefficients for dispersive processes depend on time. In the case of a chemical reaction, the time dependence of the rate coefficient, k(t), termed the specific reaction rate, is rationalized in the following way. Reactions by their very nature have to disturb reactivity distributions of the reactants in condensed media, as the more reactive species are the first ones to disappear from the system. The extent of this disturbance depends on the ratio of the rates of reactions to the rate of internal rearrangements (mixing) in the system restoring the initial distribution in reactivity of reactants. If the rates of chemical reactions exceed the rates of internal rearrangements, then the initial distributions in reactant reactivity are not preserved during the course of reactions and the specific reaction rates depend on time. Otherwise the extent of disturbance is negligible and classical kinetics, with a constant specific reaction rate, k, termed the reaction rate constant, may be valid as an approximation. In condensed media dispersive dynamical processes are endemic and this is the first monograph devoted to these processes.

Particle Dispersion and Inter-phase Kinetic Energy Transfer in a Turbulent, Two-phase Shear Layer

Particle Dispersion and Inter-phase Kinetic Energy Transfer in a Turbulent, Two-phase Shear Layer PDF Author: Kenneth T. Kiger
Publisher:
ISBN:
Category :
Languages : en
Pages : 368

Book Description
The transport of heavy, polydispersed particles and the inter-phase transfer of kinetic energy is measured experimentally in a turbulent shear layer. Specifically, fundamental/subharmonic forcing and conditional-averaging techniques were used to study the particle/turbulence interaction with the large-scale, spanwise, coherent vortices, starting from their initial roll-up through the first pairing event. It is shown that the pairing event plays a homogenizing role on the particulate field, but the amount of homogenization is strongly dependent upon the particle's viscous relaxation time, the eddy turnover time, as well as the time the particles are allowed to interact with each scale prior to a pairing event. Thus, even though the smaller size particles become well-mixed across the structure, the larger sizes are still dispersed in an inhomogeneous fashion. The dispersed/carrier phase coupling was examined through the measurement of conditionally-averaged kinetic energy transfer (which results from the work done to accelerate or decelerate the dispersed phase), as well as the conditionally-averaged particle dissipation (energy dissipated by shear deformation in the carrier phase due to the relative slip between the particles and the carrier fluid).

Recent Progress in Solid Dispersion Technology

Recent Progress in Solid Dispersion Technology PDF Author: Kohsaku Kawakami
Publisher: MDPI
ISBN: 3039215019
Category : Science
Languages : en
Pages : 202

Book Description
Amorphous solid dispersion (ASD) is a powerful formulation technology to improve oral absorption of poorly soluble drugs. Despite their being in existence for more than half a century, controlling ASD performance is still regarded as difficult because of ASD’s natural non-equilibrium. However, recent significant advances in ASD knowledge and technology may enable a much broader use of ASD technology. This Special Issue, which includes 3 reviews and 6 original articles, focuses on recent progresses in ASD technology in hopes of helping to accelerate developmental studies in the pharmaceutical industry. In striving for a deep understanding of ASD non-equilibrium behavior, the Special issue also delves into and makes progress in the theory of soft-matter dynamics.

Recent Developments in Bioenergy Research

Recent Developments in Bioenergy Research PDF Author: Vijai G. Gupta
Publisher: Elsevier
ISBN: 0128227648
Category : Technology & Engineering
Languages : en
Pages : 471

Book Description
Recent Developments in Bioenergy Research reviews all these topics, reports recent research findings, and presents potential solutions to challenging issues. The book consolidates the most recent research on the (bio)technologies, concepts and commercial developments that are currently in progress on different types of widely-used biofuels and integrated biorefineries across biochemistry, biotechnology, biochemical engineering and microbiology. Chapters include very recent/emerging topics, such as non-ionic and ionic liquids/surfactants for enhancement of lignocellulose enzymatic hydrolysis and lignocellulose biomass as a rich source of bio-ionic liquids. The book is a useful source of information for those working in the area of- industrial wastewater treatment and microbial fuel cells, but is also a great resource for senior undergraduate and graduate students, researchers, professionals, biochemical engineers and other interested individuals/groups working in the field of biofuel/bioenergy. - Provides unique information on biomass-based biofuels for fundamental and applied research - Outlines research advancements in the areas of bio-hydrogen, bioethanol, bio-methane and biorefineries - Includes emerging topics on biomass (including wastes) characterization and its uses as a resource for environmental bioremediation and bioenergy - Reviews enzyme engineering for biomass to bioproducts and biochemicals, lipids/bio-oil - Focuses on biological/ biochemical routes, as these options have the greatest potential to be the most cost-effective methods for biofuel/bioenergy production

Recent Developments in Catalysis

Recent Developments in Catalysis PDF Author: B. Viswanathan
Publisher: Editions TECHNIP
ISBN: 9782710806264
Category : Science
Languages : en
Pages : 820

Book Description


Theory and Applications of Fractional Differential Equations

Theory and Applications of Fractional Differential Equations PDF Author: A.A. Kilbas
Publisher: Elsevier
ISBN: 9780444518323
Category : Mathematics
Languages : en
Pages : 550

Book Description
This work aims to present, in a systematic manner, results including the existence and uniqueness of solutions for the Cauchy Type and Cauchy problems involving nonlinear ordinary fractional differential equations.

Factorization, Singular Operators and Related Problems

Factorization, Singular Operators and Related Problems PDF Author: Stefan Samko
Publisher: Springer Science & Business Media
ISBN: 9401702276
Category : Mathematics
Languages : en
Pages : 341

Book Description
These proceedings comprise a large part of the papers presented at the In ternational Conference Factorization, Singular Operators and related problems, which was held from January 28 to February 1, 2002, at the University of th Madeira, Funchal, Portugal, to mark Professor Georgii Litvinchuk's 70 birth day. Experts in a variety of fields came to this conference to pay tribute to the great achievements of Professor Georgii Litvinchuk in the development of vari ous areas of operator theory. The main themes of the conference were focussed around the theory of singular type operators and factorization problems, but other topics such as potential theory and fractional calculus, to name but a couple, were also presented. The goal of the conference was to bring together mathematicians from var ious fields within operator theory and function theory in order to highlight recent advances in problems many of which were originally studied by Profes sor Litvinchuk and his scientific school. A second aim was to stimulate in ternational collaboration even further and promote the interaction of different approaches in current research in these areas. The Proceedings will be of great interest to researchers in Operator The ory, Real and Complex Analysis, Functional and Harmonic Analysis, Potential Theory, Fractional Calculus and other areas, as well as to graduate students looking for the latest results.

Polymer Reaction Engineering of Dispersed Systems

Polymer Reaction Engineering of Dispersed Systems PDF Author: Werner Pauer
Publisher: Springer
ISBN: 3319964364
Category : Technology & Engineering
Languages : en
Pages : 224

Book Description
The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students.

Recent Advances in Multidisciplinary Applied Physics

Recent Advances in Multidisciplinary Applied Physics PDF Author: A. Méndez-Vilas
Publisher: Elsevier
ISBN: 9780080446486
Category : Science
Languages : en
Pages : 1010

Book Description
The 1st International Meeting on Applied Physics (APHYS-2003) succeeded in creating a new international forum for applied physics in Europe, with specific interest in the application of techniques, training, and culture of physics to research areas usually associated with other scientific and engineering disciplines. This book contains a selection of peer-reviewed papers presented at APHYS-2003, held in Badajoz (Spain), from 15th to 18th October 2003, which included the following Plenary Lectures: * Nanobiotechnology - Interactions of Cells with Nanofeatured Surfaces and with Nanoparticles * Radiation Protection of Nuclear Workers - Ethical Issues * Chaotic Data Encryption for Optical Communications

Advances in Thermoplastic Elastomers

Advances in Thermoplastic Elastomers PDF Author: Nikhil K. Singha
Publisher: Elsevier
ISBN: 0323986382
Category : Technology & Engineering
Languages : en
Pages : 656

Book Description
Advances in Thermoplastic Elastomers: Challenges and Opportunities brings together the state-of-the-art in thermoplastic elastomers (TPEs), covering innovative materials, synthesis techniques, processing methods and sustainability. Sections outline thermoplastic elastomers, rubber elastic, and thermoplastic vulcanizates, and review the current landscape, from research and published literature, to commercialization and patents. Subsequent chapters offer methodical coverage of different categories of advanced thermoplastic elastomer materials, including areas such as polyolefin-based TPEs and high performance TPEs. The final chapters in the book examine options for sustainability, including bio-based, bio-resourced, and biodegradable TPEs, as well as circular economy and recycling of TPEs.Finally, outlook and future market and research trends are reviewed. This is a valuable book for researchers and advanced students working with elastomers, polymer science, materials chemistry, and materials engineering. In an industrial setting, this is an essential resource for R&D professionals, scientists, and engineers looking to utilize thermoplastic elastomers in a range of advanced applications. - Focuses on novel materials, such as polyolefin-based TPEs, fluorinated TPEs, silicone-based TPEs, and ionic TPEs - Discusses sustainability in terms of bio-based or biocompatible TPEs, recycling and the circular economy - Helps bridge the gap between research and commercialization, reviewing patents, literature, trends, and market.