Author: Karsten BeckPublisher:
ISBN:
Category :
Languages : en
Pages : 358
Book Description
Reactions of Transition Metal Carbonyl Complexes with Isocyanides
Author: Karsten BeckPhotochemistry and Photocatalyzed Reactions of Group VIII Transition Metal Carbonyl Complexes
Author: Carol Lynn ReichelPublisher:
ISBN:
Category : Metal carbonyls
Languages : en
Pages : 614
Book Description
Reactions of Photogenerated Coordinatively Unsaturated Group VI Transition Metal Carbonyl Complexes with 1,3-dienes
Author: William Campbell MillsPublisher:
ISBN:
Category : Carbonyl compounds
Languages : en
Pages : 80
Book Description
The Formation of Metallocycloimides from the Reaction of Isocyanates with a Neutral Transition Metal Carbonyl
Author: Peter JernakoffPublisher:
ISBN:
Category :
Languages : en
Pages : 13
Book Description
The nucleophilic carbonyl complex (W(eta-C5H5)2(CO)) (1) reacts readily with the isocyanates OCNR (R = CH3, Ph) in pentane to give the first reported metallocycloimides (W(eta-C5H5)2(C(O)N(CH3)C(O))) (2) and (W(eta-C5H5)2(C(O)N(Ph)C(O))) (3). It is suggested that the reaction involves initial eta 1-C coordination of an isocyanate to give a zwitterionic intermediate in which the ligands are simultaneously activated in opposite senses, and that nucleophilic attack by the heteroallene on the electrophilic carbonyl then gives a metallocycloimide. Complex 2 has been structurally characterized by a single crystal X-ray diffraction study (monoclinic space group P2 sub 1/m, with Z = 2; a = 7.6586 A, b = 8.6718 A, c = 9.6557 A; Beta = 101.45 deg; d calc = 2.20 g/cc; R = 2.20 % and R sub w = 2.19 %) which establishes that the metallocycloimide group is essentially planar. Both 2 and 3 are moderately water sensitive, regenerating 1 at 55 C and ambient temperatures respectively. Complex 1 in toluene does not react with 1.7 atmospheres of CO2 at temperatures up to 85 C.
Synthesis and Characterization of Polydentate Isocyanide Transition Metal Complexes
Author: Michael John DiPierroPublisher:
ISBN:
Category :
Languages : en
Pages : 386
Book Description
Kinetics and Mechanisms of Substitution and Exchange Reactions of Transition Metal Carbonyl Complexes
Author: Reactions of Polynuclear Transition Metal Carbonyl Complexes with Organo-isonitriles and Some Other [Pi]-acceptor Ligands
![Reactions of Polynuclear Transition Metal Carbonyl Complexes with Organo-isonitriles and Some Other [Pi]-acceptor Ligands PDF](https://books.google.com/books/content/images/frontcover/Lt9rNwAACAAJ?fife=w80-h100)
Author: J. NewmanKinetics and Mechanisms of Substitution Reactions on Transition Metal Carbonyl Complexes Containing a Metal-metal Bond
Author: David C. SonnenbergerPublisher:
ISBN:
Category :
Languages : en
Pages : 330
Book Description
Inorganic Reactions and Methods, The Formation of Bonds to Transition and Inner-Transition Metals
Author: A. P. HagenPublisher: John Wiley & Sons
ISBN: 0470145501
Category : Science
Languages : en
Pages : 727
Book Description
Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.
Advances in Organometallic Chemistry
Author: Publisher: Academic Press
ISBN: 0080580122
Category : Science
Languages : en
Pages : 523
Book Description
Advances in Organometallic Chemistry