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Preparation and Characterization of Superhard Materials of Crystalline Carbon Nitride

Preparation and Characterization of Superhard Materials of Crystalline Carbon Nitride PDF Author: Yip-Wah Chung
Publisher:
ISBN:
Category :
Languages : en
Pages : 8

Book Description
Prompted by the prediction of Cohen and coworkers that beta carbon nitride may have properties similar to diamond, there have been many attempts to synthesize this hypothetical metastable material. We successfully synthesized this material via epitaxial stabilization using TiN(111) and ZrN(111) as the growth template. The coatings were CN/TiN or CN/ZrN multilayers grown in a dual-magnetron system. The existence of beta carbon nitride in these multilayers has been confirmed with cross-section electron diffraction, Rutherford backscattering, Raman spectroscopy and near-edge x-ray diffraction. Most important, these multilayers exhibit hardness in the 50 GPa, in spite of the large volume fraction (60-70%) of the softer TiN or ZrN component. Attempts to improve the hardness by using TiB2 (which is harder than TiN and ZrN) as the growth template did not work as well because TiB2 was markedly softened by the presence of nitrogen.

Preparation and Characterization of Superhard Materials of Crystalline Carbon Nitride

Preparation and Characterization of Superhard Materials of Crystalline Carbon Nitride PDF Author: Yip-Wah Chung
Publisher:
ISBN:
Category :
Languages : en
Pages : 8

Book Description
Prompted by the prediction of Cohen and coworkers that beta carbon nitride may have properties similar to diamond, there have been many attempts to synthesize this hypothetical metastable material. We successfully synthesized this material via epitaxial stabilization using TiN(111) and ZrN(111) as the growth template. The coatings were CN/TiN or CN/ZrN multilayers grown in a dual-magnetron system. The existence of beta carbon nitride in these multilayers has been confirmed with cross-section electron diffraction, Rutherford backscattering, Raman spectroscopy and near-edge x-ray diffraction. Most important, these multilayers exhibit hardness in the 50 GPa, in spite of the large volume fraction (60-70%) of the softer TiN or ZrN component. Attempts to improve the hardness by using TiB2 (which is harder than TiN and ZrN) as the growth template did not work as well because TiB2 was markedly softened by the presence of nitrogen.

Synthesis, Structure Characterization of Super Hard Nitride Material

Synthesis, Structure Characterization of Super Hard Nitride Material PDF Author: Fathia Mamdouh
Publisher: LAP Lambert Academic Publishing
ISBN: 9783847378020
Category :
Languages : en
Pages : 108

Book Description
This work concerned with preparation of Carbon Nitride thin films which is theoretically compete Diamond in hardness. CNx films perpared by the electrolysis of methanol -urea organic solution under different concentrations and applied voltages. This study characterized the structure of the prepared films by FTIR and GIXRD techniques and studied the optical properties of the CNx films by UV-Vis spectrometer. this study aimed at how the nitrogen to carbon ratio in the deposited films affect the structure and the properties of the deposited films.

Carbon Nitrides

Carbon Nitrides PDF Author: Oleksandr Savateev
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110746972
Category : Science
Languages : en
Pages : 386

Book Description


Synthesis, Characterization, and Applications of Graphitic Carbon Nitride

Synthesis, Characterization, and Applications of Graphitic Carbon Nitride PDF Author: Sabu Thomas
Publisher: Elsevier
ISBN: 0128230614
Category : Technology & Engineering
Languages : en
Pages : 428

Book Description
Synthesis, Characterization and Applications of Graphitic Carbon Nitride: An Uprising Carbonaceous Material offers an up-to-date record on the major findings and observations relating to graphitic carbon nitride-based systems, elaborately covering all the aspects of carbon nitride as chemical stable and pollution-free materials that are easy to prepare in a cost-effective way, along with their applications in photocatalytic degradation of pollutants, photocatalytic hydrogen generation, carbon dioxide reduction, disinfection, sensors and supercapacitors. Graphitic carbon nitride (g-C3N4) is a fascinating visible light photocatalyst, which possesses many properties that can be used for many applications.This makes the book an indispensable reference for (post)-graduate students, researchers in academia and industry, and engineers working in the field of graphitic carbon-nitride-based systems. - Includes the applications of graphitic carbon nitride as a photocatalyst for the reduction of CO2 - Describes the synthesis structure and properties of graphitic carbon nitride-based systems - Deals with the development of graphitic carbon nitride-based nanocomposites - Includes hydrogen production via water splitting by using graphitic carbon nitride - Describes the applications of graphitic carbon nitride in the field of sensors, solar cells, fuel cells and in analytical chemistry

Preparation and Characterization of Carbon Nitride Thin Films

Preparation and Characterization of Carbon Nitride Thin Films PDF Author: Lian Wan
Publisher:
ISBN:
Category :
Languages : en
Pages : 144

Book Description


Materials Research

Materials Research PDF Author:
Publisher: Allied Publishers
ISBN: 9788177644500
Category : Materials science
Languages : en
Pages : 720

Book Description
Contributed articles with reference to India.

Transition Metal Carbides and Nitrides

Transition Metal Carbides and Nitrides PDF Author: Louis Toth
Publisher: Elsevier
ISBN: 032315722X
Category : Technology & Engineering
Languages : en
Pages : 296

Book Description
Refractory Materials, Volume 7: Transition Metal Carbides and Nitrides discusses the developments in transition metal carbide and nitride research. This volume is organized into nine chapters that emphasize the mechanical and superconducting properties of these compounds. The introductory chapters deal with the general properties, preparation techniques, characterization, crystal chemistry, phase relationships, and thermodynamics of transition metal carbides and nitrides. The following chapter highlights the mechanical properties of these compounds, such as elastic and plastic deformation, fracture, strengthening mechanisms, and hardness. The discussion then shifts to specific electrical and magnetic properties, including electrical resistivity, Hall coefficient, and magnetic susceptibility. A separate chapter is devoted to carbides and nitrides as superconductors. The concluding chapters explore certain theories that explain the mechanisms of band structure and bonding in carbides and nitrides. This volume is of great value to research workers in metallurgy, ceramics, physics, chemistry, and related fields, as well as to advanced students investigating problems concerning high temperature materials or interstitial compounds.

Comprehensive Materials Processing

Comprehensive Materials Processing PDF Author:
Publisher: Newnes
ISBN: 0080965334
Category : Technology & Engineering
Languages : en
Pages : 5485

Book Description
Comprehensive Materials Processing, Thirteen Volume Set provides students and professionals with a one-stop resource consolidating and enhancing the literature of the materials processing and manufacturing universe. It provides authoritative analysis of all processes, technologies, and techniques for converting industrial materials from a raw state into finished parts or products. Assisting scientists and engineers in the selection, design, and use of materials, whether in the lab or in industry, it matches the adaptive complexity of emergent materials and processing technologies. Extensive traditional article-level academic discussion of core theories and applications is supplemented by applied case studies and advanced multimedia features. Coverage encompasses the general categories of solidification, powder, deposition, and deformation processing, and includes discussion on plant and tool design, analysis and characterization of processing techniques, high-temperatures studies, and the influence of process scale on component characteristics and behavior. Authored and reviewed by world-class academic and industrial specialists in each subject field Practical tools such as integrated case studies, user-defined process schemata, and multimedia modeling and functionality Maximizes research efficiency by collating the most important and established information in one place with integrated applets linking to relevant outside sources

Preparation and Characterisation of Carbon Nitride Thin Films

Preparation and Characterisation of Carbon Nitride Thin Films PDF Author: Sandra Elizabeth Rodil
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description


TATF' 96

TATF' 96 PDF Author:
Publisher:
ISBN:
Category : Thin films
Languages : en
Pages : 318

Book Description