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Author: Cristina Prisacariu Publisher: Springer Science & Business Media ISBN: 3709105145 Category : Technology & Engineering Languages : en Pages : 276
Book Description
A comprehensive account of the physical / mechanical behaviour of polyurethanes (PU ́s) elastomers, films and blends of variable crystallinity. Aspects covered include the elasticity and inelasticity of amorphous to crystalline PUs, in relation to their sensitivity to chemical and physical structure. A study is made of how aspects of the constitutive responses of PUs vary with composition: the polyaddition procedure, the hard segment, soft segment and chain extender (diols and diamines) are varied systematically in a large number of systems of model and novel crosslinked andthermoplastic PUs. Results will be related to: microstructural changes, on the basis of evidence from x-ray scattering (SAXS and WAXS), and also dynamic mechanical analyses (DMA), differential scanning calorimetry (DSC) and IR dichroism. Inelastic effects will be investigated also by including quantitative correlations between the magnitude of the Mullins effect and the fractional energy dissipation by hysteresis under cyclic straining, giving common relations approached by all the materials studied. A major structural feature explored is the relationship between the nature of the hard segment (crystallising or not) and that of the soft segments. Crystallinity has been sometimes observed in the commercial PUs hard phase but this is usually limited to only a few percent for most hard segment structures when solidified from the melt. One particular diisocyanate, 4,4’-dibenzyl diisocyanate (DBDI) that, in the presence of suitable chain extenders ( diols or diamines), gives rise to significant degrees of crystallinity [i-iii] and this is included in the present work. Understanding the reaction pathways involved, in resolving the subtle morphological evolution at the nanometre level, and capturing mathematically the complex, large-deformation nonlinear viscoelastic mechanical behaviour are assumed to bring new important insights in the world basic research in polyurethanes and towards applied industrial research in this area.
Author: Cristina Prisacariu Publisher: Springer Science & Business Media ISBN: 3709105145 Category : Technology & Engineering Languages : en Pages : 276
Book Description
A comprehensive account of the physical / mechanical behaviour of polyurethanes (PU ́s) elastomers, films and blends of variable crystallinity. Aspects covered include the elasticity and inelasticity of amorphous to crystalline PUs, in relation to their sensitivity to chemical and physical structure. A study is made of how aspects of the constitutive responses of PUs vary with composition: the polyaddition procedure, the hard segment, soft segment and chain extender (diols and diamines) are varied systematically in a large number of systems of model and novel crosslinked andthermoplastic PUs. Results will be related to: microstructural changes, on the basis of evidence from x-ray scattering (SAXS and WAXS), and also dynamic mechanical analyses (DMA), differential scanning calorimetry (DSC) and IR dichroism. Inelastic effects will be investigated also by including quantitative correlations between the magnitude of the Mullins effect and the fractional energy dissipation by hysteresis under cyclic straining, giving common relations approached by all the materials studied. A major structural feature explored is the relationship between the nature of the hard segment (crystallising or not) and that of the soft segments. Crystallinity has been sometimes observed in the commercial PUs hard phase but this is usually limited to only a few percent for most hard segment structures when solidified from the melt. One particular diisocyanate, 4,4’-dibenzyl diisocyanate (DBDI) that, in the presence of suitable chain extenders ( diols or diamines), gives rise to significant degrees of crystallinity [i-iii] and this is included in the present work. Understanding the reaction pathways involved, in resolving the subtle morphological evolution at the nanometre level, and capturing mathematically the complex, large-deformation nonlinear viscoelastic mechanical behaviour are assumed to bring new important insights in the world basic research in polyurethanes and towards applied industrial research in this area.
Author: C. Hepburn Publisher: Springer Science & Business Media ISBN: 940112924X Category : Technology & Engineering Languages : en Pages : 458
Book Description
The aim of this monograph has been to distil into a single volume, in an easily read and assimilated format, the essentials of this often complex technology such that it is usable by all technical and semi-technical people who wish to become their own polyurethane and polyurethane elastomer expert.
Author: I.R. Clemitson Publisher: CRC Press ISBN: 1420065777 Category : Science Languages : en Pages : 274
Book Description
Currently, raw material suppliers are the sole providers of polyurethane processing information. In most cases, they give instruction only on how to mix products and do not always include an explanation of the accompanying logic as to why these recommendations are being made. Castable Polyurethane Elastomers explains the production proces
Author: I.R. Clemitson Publisher: CRC Press ISBN: 1498726399 Category : Science Languages : en Pages : 306
Book Description
This second edition of a bestseller is a practical guide to the production of castable polyurethane articles. The book shows the progression from raw materials to prepolymer production, including the chemistry and functionality of the processes. It provides a comprehensive look at various problem-solving and processing techniques, examining the selection of different systems on both the micro and macro levels. Reorganized for better flow, this edition describes new processing methods, expands coverage of health and safety aspects, and brings all standards up to date.
Author: Api Publisher: CRC Press ISBN: 9781587160387 Category : Technology & Engineering Languages : en Pages : 642
Book Description
Conference proceedings from 'Defining the Future Through Technology- Polyurethanes', held in Westin Copley Place, Boston, Massachusetts, on October 8-11 2000. Sponsored by the Alliance for the Polyurethanes Industry.
Author: Kurt C. Frisch Publisher: CRC Press ISBN: 1000725499 Category : Technology & Engineering Languages : en Pages : 340
Book Description
Flexible polyurenthane foams of all types are a unique group of plastics materials, characterized by the fact that a multitude of different sets of properties can be obtained by varying the levels of a relatively small number of base components in the formulations. Different foam grades, primarily characterized by density and hardness, can be obtained by changing the ratio between base polyol, polymer polyol, water, blowing agent, isocyanate and other components. It is not uncommon for foam producers in industrialized countries to manufacture more than one hundred different foam grades based on these basic chemicals, plus the ancillary chemicals needed for optimized processing. This has always made flexible polyurethane foams a highly suitable candidate for correlating these variations in the formulations with the resulting properties in a mathematical way, aimed at predicting the properties as accurately as possible, fine-tuning existing grades or designing new foam grades. This book discusses the methodology for obtaining meaningful equations for correlating properties with formulation variables and other influencing factors
Author: Michael Szycher, Ph.D Publisher: CRC Press ISBN: 9780849306020 Category : Technology & Engineering Languages : en Pages : 698
Book Description
Handbook of Polyurethanes serves as the first source of information of useful polymers. This new book thoroughly covers the entire spectrum of polyurethanes - from current technology to buyer's information. Discussions include: block and heteroblock systems rubber plasticity structure-property relations microphase separation catalysis of isocyanate reactions synthesis of polyurethanes for thermoplastics, thermosets, and curable compositions by either heat or U.V. energy biomedical applications of urethane elastomers castables, sealants, and caulking compounds flexible and semi-flexible foams health and safety This handbook compiles data from many sources, exhaustively illustrating the complex principles involved in polyurethane chemistry and technology. Handbook of Polyurethanes represents invaluable information for corporations, universities, or independent inventors.
Author: Fahmina Zafar Publisher: BoD – Books on Demand ISBN: 9535107267 Category : Science Languages : en Pages : 484
Book Description
The enchanting and worthy world of PU beckoned to bring forth the book titled "Polyurethane". The book is divided into three sections: structures, properties and characterization of PU, applications of PU and a separate section on Biobased PU, covering the research and development in these areas. Each contributed chapter handles new and interesting topics introducing the reader to the wider known and unknown applications of PU such as PU for grouting technologies, fuel binder, extraction of metals, treatment of industry wastewater, alkanolamide PU coatings and foams, and others. The book aims to cater a larger audience comprising of readers from polymer chemistry, materials chemistry, and industrial chemistry.
Author: NinaM.K. Lamba Publisher: Routledge ISBN: 1351423371 Category : Medical Languages : en Pages : 298
Book Description
Polyurethanes in Biomedical Applications studies the use of polyurethanes in implanted medical devices. This analysis describes the concepts of polymer science, the manufacture of polyurethanes, and the biological responses to implant polyurethanes, reflecting the developments in biomaterials science and the interdisciplinary nature of bioengineering.
Author: Cristina Prisacariu
Author: Cristina Prisacariu
Author: C. Hepburn
Author: I.R. Clemitson
Author: I.R. Clemitson
Author: Api
Author: Kurt C. Frisch
Author: Michael Szycher, Ph.D
Author: Fahmina Zafar
Author: 
Author: NinaM.K. Lamba