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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
A composition useful for the extraction of metals and metalloids comprises (a) carbon dioxide fluid (preferably liquid or supercritical carbon dioxide); and (b) a polymer in the carbon dioxide, the polymer having bound thereto a ligand that binds the metal or metalloid; with the ligand bound to the polymer at a plurality of locations along the chain length thereof (i.e., a plurality of ligands are bound at a plurality of locations along the chain length of the polymer). The polymer is preferably a copolymer, and the polymer is preferably a fluoropolymer such as a fluoroacrylate polymer. The extraction method comprises the steps of contacting a first composition containing a metal or metalloid to be extracted with a second composition, the second composition being as described above; and then extracting the metal or metalloid from the first composition into the second composition.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
A composition useful for the extraction of metals and metalloids comprises (a) carbon dioxide fluid (preferably liquid or supercritical carbon dioxide); and (b) a polymer in the carbon dioxide, the polymer having bound thereto a ligand that binds the metal or metalloid; with the ligand bound to the polymer at a plurality of locations along the chain length thereof (i.e., a plurality of ligands are bound at a plurality of locations along the chain length of the polymer). The polymer is preferably a copolymer, and the polymer is preferably a fluoropolymer such as a fluoroacrylate polymer. The extraction method comprises the steps of contacting a first composition containing a metal or metalloid to be extracted with a second composition, the second composition being as described above; and then extracting the metal or metalloid from the first composition into the second composition.
Author: Maartje F. Kemmere Publisher: John Wiley & Sons ISBN: 3527607056 Category : Technology & Engineering Languages : en Pages : 358
Book Description
Recently, supercritical fluids have emerged as more sustainable alternatives for the organic solvents often used in polymer processes. This is the first book emphasizing the potential of supercritical carbon dioxide for polymer processes from an engineering point of view. It develops a state-of-the-art overview on polymer fundamentals, polymerization reactions and polymer processing in supercritical carbon dioxide. The book covers topics in a multidisciplinary approach starting from polymer chemistry and thermodynamics, going through monitoring, polymerization processes and ending with polymer shaping and post-processing. The authors are internationally recognized experts from different fields in polymer reaction engineering in supercritical fluids. The book was initiated by the Working Party on Polymer Reaction Engineering of the European Federation of Chemical Engineering and further renowned international experts.
Author: De-en Jiang Publisher: John Wiley & Sons ISBN: 1119091179 Category : Science Languages : en Pages : 397
Book Description
Covers a wide range of advanced materials and technologies for CO2 capture As a frontier research area, carbon capture has been a major driving force behind many materials technologies. This book highlights the current state-of-the-art in materials for carbon capture, providing a comprehensive understanding of separations ranging from solid sorbents to liquid sorbents and membranes. Filled with diverse and unconventional topics throughout, it seeks to inspire students, as well as experts, to go beyond the novel materials highlighted and develop new materials with enhanced separations properties. Edited by leading authorities in the field, Materials for Carbon Capture offers in-depth chapters covering: CO2 Capture and Separation of Metal-Organic Frameworks; Porous Carbon Materials: Designed Synthesis and CO2 Capture; Porous Aromatic Frameworks for Carbon Dioxide Capture; and Virtual Screening of Materials for Carbon Capture. Other chapters look at Ultrathin Membranes for Gas Separation; Polymeric Membranes; Carbon Membranes for CO2 Separation; and Composite Materials for Carbon Captures. The book finishes with sections on Poly(amidoamine) Dendrimers for Carbon Capture and Ionic Liquids for Chemisorption of CO2 and Ionic Liquid-Based Membranes. A comprehensive overview and survey of the present status of materials and technologies for carbon capture Covers materials synthesis, gas separations, membrane fabrication, and CO2 removal to highlight recent progress in the materials and chemistry aspects of carbon capture Allows the reader to better understand the challenges and opportunities in carbon capture Edited by leading experts working on materials and membranes for carbon separation and capture Materials for Carbon Capture is an excellent book for advanced students of chemistry, materials science, chemical and energy engineering, and early career scientists who are interested in carbon capture. It will also be of great benefit to researchers in academia, national labs, research institutes, and industry working in the field of gas separations and carbon capture.
Author: M.B. King Publisher: Springer Science & Business Media ISBN: 9401121389 Category : Science Languages : en Pages : 335
Book Description
The aim of this book is to present the current state of the art of extracting natural products with near-critical solvents and to view the possibilities of further extensions of the technique. Relevant background theory is given but does not dominate the book. Carbon dioxide is the near-critical solvent used in most recent applications and inevitably receives prominence. In addition to general descriptions and reviews, the book contains three chapters by indus trial practitioners who describe in detail the operation of their processes and discuss the market for their products. Sections on the design of the pressure vessels and pumps required in these processes and on the acquisition of the data required for design are included. The costing of the processes is also discussed. There is good scope for combining a near-critical extraction step with other process steps in which the properties of near-critical solvents are utilised, for example as a reaction or crystallisation medium and a chapter is devoted to these important aspects. It is hoped that the work will be found to contain a great deal of specific information of use to those already familiar with this field. However the style of presentation and content is such that it will also be useful as an introduction. In particular it will be helpful to those wondering if this form of separation method has anything to offer for them, whether they are engineers, chemists or managers in industry, or in academic or research institutions.
Author: Ashok Kumar Nadda Publisher: Elsevier ISBN: 032385821X Category : Technology & Engineering Languages : en Pages : 432
Book Description
CO2-philic Polymers, Nanocomposites and Chemical Solvents: Capture, Conversion and Industrial Products is a multidisciplinary book that provides a compilation of concrete information on various polymers, porous materials hydrogels, membranes, nanoparticles, biochar metal-organic frameworks, bioinspired surfaces, polysaccharides, organic solvents, chemicals, eutectic solvents, amine-based chemical compounds, porphyrins, ionic liquids, ceramics and cutting-edge technologies for CO2 sequestration and conversion. Each chapter covers the latest developments and methods of synthesis and applications in the area. The book discusses, in detail, valuable commercial products from CO2, such as ethanol, methanol, formic acid, and precursors of other fine chemicals. The book covers the scientific, technological and practical concepts concerning the research, development and realization of CO2-philic polymers, nanocomposites and chemical solvents. This makes it a valuable resource for academic researchers and graduate students in chemical engineering, materials science and chemical engineers/engineers working in the industry. Provides a comprehensive overview of candidates and techniques for CO2 capture and conversion Written by worldwide experts from academia Contains numerous illustrations, tables, figures, graphs, bibliographies and extensive references Appeals to a broad academic audience with its interdisciplinary content
Author: Janusz Pawliszyn Publisher: Elsevier ISBN: 9780444505101 Category : Science Languages : en Pages : 1170
Book Description
This title is the first comprehensive book on sampling and modern sample preparation techniques and has several main objectives: to facilitate recognition of sample preparation as both an integral part of the analytical process; to present a fundamental basis and unified theoretical approach for the professional development of sample preparation; to emphasize new developments in sample preparation technology; and to highlight the future impact of sample preparation on new directions in analytical science, particularly automation, miniaturization and field implementation. Until recently, there has been relatively little scientific interest in sampling and sample preparation, however this situation is presently changing as sampling and sample preparation become integral parts of the analytical process with their own unique challenges and research opportunities. Sampling and Sample Preparation for Field and Laboratory is an essential resource for all analytical chemists, and in particular those involved in method development. Not only does it cover the fundamental aspects of extraction, it also covers applications in various matrices and includes sampling strategies and equipment and how these can be integrated into the analytical process for maximum efficiency.
Author: D. Max Roundhill Publisher: Springer Science & Business Media ISBN: 1475752040 Category : Science Languages : en Pages : 387
Book Description
Extractions of Metals from Soils and Waters represents a new emphasis in the series Modern Inorganic Chemistry, namely the impact inorganic chemistry can have on the environment. Also, this is the first volume ever to introduce the reader to all aspects of heavy metal extraction. While the primary emphasis is on complexation chemistry, attention is also paid to phase transfer aspects. Particular methods of note include electrokinetics, phytoremediation, and sensors. Aimed primarily at chemists, this book will also appeal to engineers, plant biochemists, environmental health specialists, and practitioners or students of environmental law.
Author: Isha Ruhulla Kamrupi Publisher: LAP Lambert Academic Publishing ISBN: 9783846512234 Category : Languages : en Pages : 192
Book Description
Polymers have become an inextricable part of our daily life. Not only the synthesis but also the processing of polymers has been given a major attention. Most of the commercial methods use environmentally hazardous volatile organic solvents (VOC)and chlorofluorocarbons (CFC) for processing and synthesis of polymers. Due to the enormous increment of VOC/CFC emissions and also the generation of aqueous waste streams, chemical engineers and chemists have already been looking for new and cleaner alternatives. One of these methods is the use of supercritical fluids as a processing solvent. An intense research activity concentrated in the last decade has demonstrated that dense carbon dioxide is an attractive solvent for polymer synthesis as it is environmentally benign, inexpensive, with tunable physico-chemical properties and substantially inert towards chain transfer reactions. We have briefly described the synthesis of different polymers and their nanocomposites with metal nanoparticles in supercritical carbon dioxide in this book.
Author: Ashok Kumar Nadda Publisher: Elsevier ISBN: 0323857779 Category : Technology & Engineering Languages : en Pages : 430
Book Description
CO2-philic Polymers, Nanocomposites and Chemical Solvents: Capture, Conversion and Industrial Products is a multidisciplinary book that provides a compilation of concrete information on various polymers, porous materials hydrogels, membranes, nanoparticles, biochar metal-organic frameworks, bioinspired surfaces, polysaccharides, organic solvents, chemicals, eutectic solvents, amine-based chemical compounds, porphyrins, ionic liquids, ceramics and cutting-edge technologies for CO2 sequestration and conversion. Each chapter covers the latest developments and methods of synthesis and applications in the area. The book discusses, in detail, valuable commercial products from CO2, such as ethanol, methanol, formic acid, and precursors of other fine chemicals. The book covers the scientific, technological and practical concepts concerning the research, development and realization of CO2-philic polymers, nanocomposites and chemical solvents. This makes it a valuable resource for academic researchers and graduate students in chemical engineering, materials science and chemical engineers/engineers working in the industry. Provides a comprehensive overview of candidates and techniques for CO2 capture and conversion Written by worldwide experts from academia Contains numerous illustrations, tables, figures, graphs, bibliographies and extensive references Appeals to a broad academic audience with its interdisciplinary content
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Author: Deborah Lynn Apodaca
Author: Maartje F. Kemmere
Author: De-en Jiang
Author: M.B. King
Author: Ashok Kumar Nadda
Author: Janusz Pawliszyn
Author: D. Max Roundhill
Author: Isha Ruhulla Kamrupi
Author: Ashok Kumar Nadda