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Author: Omar Azzaroni Publisher: John Wiley & Sons ISBN: 1119455014 Category : Technology & Engineering Languages : en Pages : 840
Book Description
Serves as a guide for seasoned researchers and students alike, who wish to learn about the cross-fertilization between biology and materials that is driving this emerging area of science This book covers the most relevant topics in basic research and those having potential technological applications for the field of biopolymer brushes. This area has experienced remarkable increase in development of practical applications in nanotechnology and biotechnology over the past decade. In view of the rapidly growing activity and interest in the field, this book covers the introductory features of polymer brushes and presents a unifying and stimulating overview of the theoretical aspects and emerging applications. It immerses readers in the historical perspective and the frontiers of research where our knowledge is increasing steadily—providing them with a feeling of the enormous potential, the multiple applications, and the many up-and-coming trends behind the development of macromolecular interfaces based on the use of polymer brushes. Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials offers chapters on: Functionalization of Surfaces Using Polymer Brushes; Polymer Brushes by ATRP and Surface-Mediated RAFT Polymerization for Biological Functions; Electro-Induced Copper Catalyzed Surface Modification with Monolayer and Polymer Brush; Polymer Brushes on Flat and Curved Substrates; Biomimetic Anchors for Antifouling Polymer Brush Coating; Glycopolymer Brushes Presenting Sugars in Their Natural Form; Smart Surfaces Modified with Phenylboronic Acid-Containing Polymer Brushes; DNA Brushes; Polymer Brushes as Interfacial Materials for Soft Metal Conductors and Electronics; and more. Presents a comprehensive theory/simulation section that will be valuable for all readers Includes chapters not only on the biological applications of polymer brushes but also on biological systems that resemble polymer brushes on flat surfaces Addresses applications in coatings, friction, sensors, microelectromechanical systems, and biomaterials Devotes particular attention to the functional aspects of hybrid nanomaterials employing polymer brushes as functional units Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials is aimed at both graduate students and researchers new to this subject as well as scientists already engaged in the study and development of polymer brushes.
Author: Omar Azzaroni Publisher: John Wiley & Sons ISBN: 1119455014 Category : Technology & Engineering Languages : en Pages : 840
Book Description
Serves as a guide for seasoned researchers and students alike, who wish to learn about the cross-fertilization between biology and materials that is driving this emerging area of science This book covers the most relevant topics in basic research and those having potential technological applications for the field of biopolymer brushes. This area has experienced remarkable increase in development of practical applications in nanotechnology and biotechnology over the past decade. In view of the rapidly growing activity and interest in the field, this book covers the introductory features of polymer brushes and presents a unifying and stimulating overview of the theoretical aspects and emerging applications. It immerses readers in the historical perspective and the frontiers of research where our knowledge is increasing steadily—providing them with a feeling of the enormous potential, the multiple applications, and the many up-and-coming trends behind the development of macromolecular interfaces based on the use of polymer brushes. Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials offers chapters on: Functionalization of Surfaces Using Polymer Brushes; Polymer Brushes by ATRP and Surface-Mediated RAFT Polymerization for Biological Functions; Electro-Induced Copper Catalyzed Surface Modification with Monolayer and Polymer Brush; Polymer Brushes on Flat and Curved Substrates; Biomimetic Anchors for Antifouling Polymer Brush Coating; Glycopolymer Brushes Presenting Sugars in Their Natural Form; Smart Surfaces Modified with Phenylboronic Acid-Containing Polymer Brushes; DNA Brushes; Polymer Brushes as Interfacial Materials for Soft Metal Conductors and Electronics; and more. Presents a comprehensive theory/simulation section that will be valuable for all readers Includes chapters not only on the biological applications of polymer brushes but also on biological systems that resemble polymer brushes on flat surfaces Addresses applications in coatings, friction, sensors, microelectromechanical systems, and biomaterials Devotes particular attention to the functional aspects of hybrid nanomaterials employing polymer brushes as functional units Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials is aimed at both graduate students and researchers new to this subject as well as scientists already engaged in the study and development of polymer brushes.
Author: Rigoberto C. Advincula Publisher: John Wiley & Sons ISBN: 3527604995 Category : Technology & Engineering Languages : en Pages : 501
Book Description
Materials scientists, polymer chemists, surface physicists and materials engineers will find this book a complete and detailed treatise on the field of polymer brushes, their synthesis, characterization and manifold applications. In a first section, the various synthetic pathways and different surface materials are introduced and explained, followed by a second section covering important aspects of characterization and analysis in both flat surfaces and particles. These specific surface initiated polymerization (SIP) systems such as linear polymers, homopolymers, block copolymers, and hyperbranched polymers are unique compared to previously reported systems by chemisorption or physisorption. They have found their way in both large-scale and miniature applications of polymer brushes, which is covered in the last section. Such 'hairy' surfaces offer fascinating opportunities for addressing numerous problems of both academic and, in particular, industrial interest: high-quality, functional or protective coatings, composite materials, surface engineered particles, metal-organic interfaces, biological applications, micro-patterning, colloids, nanoparticles, functional devices, and many more. It is the desire of the authors that this book will be of benefit to readers who want to "brush-up on polymers".
Author: Vikas Mittal Publisher: CRC Press ISBN: 1439857954 Category : Technology & Engineering Languages : en Pages : 330
Book Description
Polymer Brushes: Substrates, Technologies, and Properties covers various aspects of polymer brush technology, including synthesis, properties, performance, and applications. It presents both experimental details and theoretical insights to enable a better understanding of the brush system.After an overview of polymer brush systems, the book discuss
Author: Inga Lilge Publisher: Springer ISBN: 3658195959 Category : Science Languages : en Pages : 95
Book Description
In her research, Inga Lilge focuses on a systematic study of poly(acrylamide) (PAAm) brushes prepared by surface-initiated atom transfer radical polymerization (SI-ATRP). In addition to the analysis of the time dependence of the polymer brush growth, the conformation of the polymer brushes is varied by grafting or cross-linking density. The results have practical implications for the study of cellular interactions on PAAm brushes since cell-substrate interactions are known to influence various cell characteristics, such as migration and adhesion.
Author: Rigoberto C. Advincula Publisher: ISBN: Category : Languages : en Pages :
Book Description
Materials scientists, polymer chemists, surface physicists and materials engineers will find this book a complete and detailed treatise on the field of polymer brushes, their synthesis, characterization and manifold applications. In a first section, the v.
Author: Jacob Odulio Publisher: ISBN: Category : Languages : en Pages : 0
Book Description
This perspective offers an overview of polymer brushes; thin films of polymers anchored to a substrate. Three common synthesis methods are reviewed including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), and nitroxide-mediated polymerization (NMP). The characteristics of brush density and solvent on polymer brushes are elucidated and examined in relation to possible applications of polymer brushes. The applications of polymer brushes in colloid stabilization and antifouling are demonstrated in regards to brush density and general properties of polymer architectures commonly used in polymer brushes.
Author: Mike John Edwards Publisher: Mike John Edwards ISBN: Category : Science Languages : en Pages : 77
Book Description
A comprehensive theoretical ebook in the field of soft matter and biological science. This Ebook contains most recent advances in theory and simulations of artificial knee joint.
Author: Mike John Edwards (Majid Farzin) Publisher: Mike John Edwards ISBN: Category : Science Languages : en Pages : 99
Book Description
The present ebook covers the mathematical modeling and numerical simulations of polyelectrolyte brush bilayers under shear motion. The similar conditions could be found in mammalian knee joints. The new findings which is described in the last chapter shows that polymer brush bilayers are useful in lubrication exclusively in the presence of hydrodynamic interactions between monomers. This reveals the significance of interstitial water in knee joint.
Author: Mike John Edwards Publisher: Mike John Edwards ISBN: Category : Science Languages : en Pages : 111
Book Description
This is the third edition of the book which contains ten chapters and it covers my research about polymer brush bilayers under shear. The chapter ten is devoted to polymer brush bilayers under non-equilibrium shear inversion which is very important in studying mammalian synovial joint behavior. In this chapter, it is revealed that the hydrodynamic interactions produce mechanical instabilities in the system while adding electrostatic interactions removes those mechanical instabilities.
Author: Karson Shayne Brooks Publisher: ISBN: Category : Languages : en Pages : 362
Book Description
Post-polymerization modification of reactive polymer brushes serves as a way to fabricate and design polymeric thin films that can be precisely tuned for desired applications. When combined with click chemistry (reactions that are fast, high yielding, and react with high fidelity), post-polymerization modification is further simplified, allowing for the design of even more complex surfaces. Herein, a new click reaction, sulfur fluoride exchange (SuFEx) chemistry, is studied for post-polymerization of reactive polymer brushes, and aminolysis of well-studied poly(pentafluorophenyl acrylate) (Poly(PFPA)) brushes are used for the generation of complex morphologies and self-sorting multi-functional surfaces. First, the conditions, reactivities, and limitations of SuFEx chemistry in polymer brush systems are extensively studied with variations of the brush systems, catalysts, and reactants. Studies on the kinetics of the reaction as well as product identification provide guidance for using this reaction in polymer brush systems as well as give further evidence for elucidation of the reaction mechanism. Complex morphological features and surfaces are also generated and studied in poly(PFPA) brush films. Surface creasing, a failure mechanism of soft materials when exposed to substantial stress, is induced through the confined reaction of Jeffamine M-2070, an amine bearing copolymer of poly(ethylene oxide) and poly(propylene oxide), with the brush surface. The variables governing and controlling crease formation in poly(PFPA) polymer brushes as well as the underlying mechanism are investigated in order to better control, understand, and ultimately expand this phenomenon to other polymer brush systems. Poly(PFPA) brushes are additionally used to fabricate a self-sorting surface with three orthogonal click reactions. Using poly(PFPA) as a scaffold, an amine-bearing strained alkyne and an amine-bearing sulfonyl fluoride were patterned onto the surface and reacted with complementary functionalities for aminolysis, strain-promoted alkyne azide cycloaddition, and SuFEx chemistry in one reaction vessel. This results in a surface that can self-sort three orthogonal reactions to pattern chemical functionalities as well as differing morphologies. Finally, poly(PFPA) polymer networks are fabricated using a photoactive cross-linker in order to create dense reactive polymer films that can be fabricated simply, scaled for industrial use, and expanded to other surfaces with no surface pretreatment required.
Author: Omar Azzaroni
Author: Omar Azzaroni
Author: Rigoberto C. Advincula
Author: Vikas Mittal
Author: Inga Lilge
Author: Rigoberto C. Advincula
Author: Jacob Odulio
Author: Mike John Edwards
Author: Mike John Edwards (Majid Farzin)
Author: Mike John Edwards
Author: Karson Shayne Brooks