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Author: Hartmut Zabel Publisher: Springer Science & Business Media ISBN: 3642752705 Category : Science Languages : en Pages : 365
Book Description
The progress of materials science depends on the development of novel materials and the development of novel experimental techniques. The research on graphite intercalation compounds combines both aspects: new compounds with strikingly new and anisotropic properties have been synthesized and analyzed during the past couple of years by means of state-of-the-art experimental methods. At the same time, the preparation of the compounds already known has improved con siderably, giving increased reliability and reproducibility of the experimental results. The high quality experimental data now available have stimulated theo retical work. Moreover, the theoretical work has had a great impact on further experimental studies, with the effect of a much improved understanding of this class of materials. This volume is dedicated to a thorough description of all relevant experimen tal and theoretical aspects of the structural and dynamical properties of graphite intercalation compounds. Because of the large number of topics, a second vol ume, which is now in preparation, will follow and will treat the electronic, transport, magnetic, and optical properties. The second volume will also contain a chapter on applications of graphite intercalation compounds. There have been a number of reviews written on selected aspects of these compounds in various journals and conference proceedings during the last couple of years, but this is the first comprehensive review since the thorough overview provided by M.S. Dresselhaus and G. Dresselhaus appeared ten years ago.
Author: Patrick Bernier Publisher: Springer Science & Business Media ISBN: 146152850X Category : Science Languages : en Pages : 402
Book Description
This volume provides a record of the second ASI on the subject "Chemical Physics of Intercalation", which was patterned after its highly successful July 1987 predecessor. A growing community of chemists, physicists and materials scientists has come to appreciate the utility of extending the intercalation concept to generic guest-host compounds and solid solutions. The unifying themes are the complex phase equilibria which result from the competition between repulsive and attractive interactions between and within the guest and host substructures, the tunability of properties by control of guest concentration and superlattice periodicity, and the broad spectrum of potential applications which these materials may provide. The success of this initiative may be judged by noting the enlarged scope of materials covered in this volume as compared to its predecessor. The present volume covers the spectrum from 3-dimensional oxides, 2-dimensional classical layer intercalates,- dimensional doped polymers and zero-dimensional doped fullerene lattices. Hybrid systems such as polymers in layer hosts and nonporous hosts are also treated. Several chapters provide global unifying viewpoints by focussing on sold state chemical aspects, transport and optical properties, the occurrence of superconductivity, etc.
Author: Hartmut Zabel Publisher: Springer Science & Business Media ISBN: 3642844790 Category : Science Languages : en Pages : 442
Book Description
The research on graphite intercalation compounds often acts as a forerunner for research in other sciences. For instance, the concept of staging, which is fundamental to graphite intercalation compounds, is also relevant to surface science in connection with adsorbates on metal surfaces and to high-temperature superconducting oxide layer materials. Phonon-folding and mode-splitting effects are not only basic to graphite intercalation compounds but also to polytypical systems such as supercon ductors, superlattices, and metal and semiconductor superlattices. Charge transfer effects playa tremendously important role in many areas, and they can be most easily and fundamentally studied with intercalated graphite. This list could be augmented with many more examples. The important message, however, is that graphite inter calation compounds represent a class of materials that not only can be used for testing a variety of condensed-matter concepts, but also stimulates new ideas and approaches. This volume is the second of a two-volume set. The first volume addressed the structural and dynamical aspects of graphite intercalation compounds, together with the chemistry and intercalation of new compounds. This second volume provides an up-to-date status report from expert researchers on the transport, magnetic, elec tronic and optical properties ofthis unique class of materials. The band-structure cal culations of the various donor and acceptor compounds are discussed in depth, and detailed reviews are provided ofthe experimental verification ofthe electronic struc ture in terms of their photoemission spectra and optical properties.
Author: A. D. Norman Publisher: John Wiley & Sons ISBN: 0470145412 Category : Science Languages : en Pages : 537
Book Description
Die langerwartete Komplettierung der Reihe 'Inorganic Reactions and Methods' beginnt jetzt mit der Publikation des 6. Bandes. Seit Jahren vielfach in Forschung und Berufsalltag bewährt, behandelt die Reihe alle Gebiete der anorganischen Synthesechemie - die Chemie der Elemente, Koordinationsverbindungen, Donor-Acceptor-Addukte, organometallische Stoffe, Polymere und Festkörper sowie bioanorganische Materialien. Mit Autoren-, Sach- und Verbindungsregister! (07/98)
Author: Frank H. Herbstein Publisher: Oxford University Press, USA ISBN: 9780198568933 Category : Science Languages : en Pages : 722
Book Description
This book provides an account of the structure and properties of crystalline binary adducts. Such crystals are perhaps better known as molecular compounds and complexes and are estimated to make up one quarter of the world's crystals. More than 600 figures, 200 tables and 3500 references are included in the book.
Author: M.S. Dresselhaus Publisher: Springer ISBN: 1475755562 Category : Technology & Engineering Languages : en Pages : 492
Book Description
This volume is prepared from lecture notes for the course "Intercalation in Layered Materials" which was held at the Ettore Majorana Centre for Scientific Culture at Erice, Sicily in July, 1986, as part of the International School of Materials Science and Tech nology. The course itself consisted of formal tutorial lectures, workshops, and informal discussions. Lecture notes were prepared for the formal lectures, and short summaries of many of the workshop presentations were prepared. This volume is based on these lecture notes and research summaries. The material is addressed to advanced graduate students and postdoctoral researchers and assumes a background in basic solid state physics. The goals of this volume on Intercalation in Layered Materials include an introduc tion to the field for potential new participants, an in-depth and broad exposure for stu dents and young investigators already working in the field, a basis for cross-fertilization between workers on various layered host materials and with various intercalants, and an elaboration of the complementarity of intercalated layered materials with deliberately structured superlattices.
Author: L. Pietronero Publisher: Springer ISBN: Category : Science Languages : en Pages : 344
Book Description
When an area of research is in fast growth, it often happens that no one single journal is to be found where most of the relevant publications are contained. Such is the case of the physics of intercalation compounds, a field which, by sitting at a corner point between materials science, solid state physics, and chemistry, finds its contributions largely scattered about in the literature. Given these circumstances it is of crucial interest to find a place where the most recent contributions and up-to-date referen ces can be found at once. For intercalated graphite and other similar com pounds this role has been played so far by proceedings of international con ferences, such as La Napoule (1977), Nijmegen (1979), Provincetown (1980), and Sendai (1980). The present book is an ideal continuation of this series, as it contains most of the invited and contributed papers of the Trieste International Con ference on the Physics of Intercalation Compounds, held in Trieste, Italy during the week 6-10 July 1981. The main emphasis is on intercalated graphite, though several interesting contributions deal with other materials, such as polyacetylene and transition metal compounds, or with general problems, such as two-dimensional melting. The book is divided into six sections-Structure and General Properties, Electronic Porperties, Stability and Phonons, Ordering and Phase Transitions, Magnetic Resonance, and Transport Properties-reflecting the main areas of interest, and also broadly the main discussion sessions of the Conference.
Author: W. Müller-Warmuth Publisher: Springer Science & Business Media ISBN: 9401108900 Category : Technology & Engineering Languages : en Pages : 525
Book Description
The combination of solid materials of different structural dimensionality with atomic or molecular guest species via intercalation processes represents a unique and widely variable low temperature synthesis strategy for the design of solids with particular composition, structure and physical properties. In the last decade this field has experienced a rapid development and represents now an established specific domain of solid state research and materials science. Substantial progress has been made with respect to an understanding of the complex relationship between structure, bonding, physical properties and chemical reactivity since the first volume on the subject appeared in this series in 1979 (Intercalated Layered Materials, F. Levy, ed.). The purpose of this volume is to present a survey on progress and per spectives based on the treatment of a series of major areas of activities in this field. By the very nature of its subject this monograph has an interdisciplinary character and addresses itself to chemists, physicists and materials scien tists interested in intercalation research and related aspects such as design and characterization of complex materials, low temperature synthesis, solid state reaction mechanisms, electronic/ionic conductivity, control of electronic properties of solids with different structural dimensionality and application of intercalation systems. Several chapters have been devoted to specific groups of host lattices.