Author: Frederick Joseph HeldrichPublisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 154
Book Description
Part I. Synthetic Applications of Reductive Electrochemical Couplings
Author: Frederick Joseph HeldrichPublisher:
ISBN:
Category : Electrochemistry
Languages : en
Pages : 154
Book Description
Synthetic Organic Electrochemistry
Author: Albert J. FryPublisher: John Wiley & Sons
ISBN: 9780471633969
Category : Science
Languages : en
Pages : 356
Book Description
An introduction to electrochemical methods and their use in the synthetic laboratory. Covers the major organic electrochemical pathways of synthetic interest, while de-emphasizing the mechanistic literature. For each functional group covered, the essential features of its electrochemical behavior are outlined, including the presumed intermediates. This Second Edition has been revised, covering the literature through early 1988, and presents useful electrochemical reactions superior to, and, in some cases, without counterparts in, conventional chemical methods.
Nickel-catalyzed Reductive Coupling of Alkyl, Allyl and Vinyl Electrophiles
Author: Michael R. PrinsellPublisher:
ISBN:
Category :
Languages : en
Pages : 187
Book Description
"The nickel-catalyzed reductive coupling of two organic electrophiles to form new carbon-carbon bonds is a fast emerging field of chemistry, with applications to the synthesis of medicinally interesting compounds. This method is an alternative to traditional transition metal-catalyzed cross-coupling reactions of organic electrophiles with organometallic nucleophiles. This thesis details the author's work towards the development of several reactions to reductively couple organic molecules to form Csp3-Csp3 bonds, including alkyl, allyl and vinyl halides. Chapter 1 delves into the background of traditional metal-catalyzed crosscoupling reactions as well as the advantages and challenges associated with using a reductive method to construct C-C bonds. In particular this chapter presents the specific challenges associated with the formation of a carbon-carbon bond between two Csp3 hybridized carbons. Chapter 2 outlines the development of a mild, general dimerization reaction of alkyl halides. This chapter also focuses on the use of sodium iodide to extend the coupling to molecules that are unreactive to the standard reaction conditions. Chapter 3 details work towards the cross-coupling of two alkyl halides. While cross-selectivity remains a challenge, some potential solutions are discussed. Chapter 4 presents the optimization and reaction scope of the coupling of allyl acetates with secondary alkyl halides, as well as progress towards couplings with primary alkyl halides. In addition, the first report of the catalytic coupling of vinyl bromides with allyl acetates is reported. Chapter 5 focuses on work towards the reductive cyclization of alkyl halides and allyl acetates. Initial results show promising diastereomeric ratios. Chapter 6 details work on the dehydrogenative synthesis of bipyridine and terpyridine ligands. These ligands are useful and are used for many reductive coupling reactions in the Weix group"--Pages vi.
Modern Electrosynthetic Methods in Organic Chemistry
Author: Frank MarkenPublisher: CRC Press
ISBN: 0429783833
Category : Science
Languages : en
Pages : 212
Book Description
Modern Electrosynthetic Methods in Organic Chemistry introduces readers to new ways of making materials and compounds using low waste processes, employing energy from electricity rather than chemical reagents. It explores electro-organic synthesis, which offers clean synthesis tools as well as unusual reaction intermediates and reaction types. Despite applications previously remaining niche, due to the advent of microfluidic reactors this book is a must-read for industry professionals and academics alike. It targets specific areas of recent progress and development in the field that show high novelty and potential, at the same time inviting a wider range of applications in green and clean technology. Key Features: Offers clean synthesis tools Targets areas of recent progress and development Addresses the most recent advances in the field
Proceedings of the Symposium on Fundamentals and Potential Applications of Electrochemical Synthesis
Author: Robert Delaye WeaverPublisher:
ISBN:
Category : Science
Languages : en
Pages : 286
Book Description
Organic Redox Chemistry
Author: Jun-Ichi YoshidaPublisher: John Wiley & Sons
ISBN: 352734487X
Category : Science
Languages : en
Pages : 260
Book Description
Organic Redox Chemistry Explore the most recent advancements and synthesis applications in redox chemistry Redox chemistry has emerged as a crucial research topic in synthetic method development. In Organic Redox Chemistry: Chemical, Photochemical and Electrochemical Syntheses, some key researchers in this field, including editors Dr. Frédéric W. Patureau and the late Dr. Jun-Ichi Yoshida, deliver an insightful exploration of this rapidly developing topic. This book highlights electron transfer processes in synthesis by using different techniques to initiate them, allowing for a multi-directional perspective in organic redox chemistry. Covering a wide array of the important and recent developments in the field, Organic Redox Chemistry will earn a place in the libraries of chemists seeking a one-stop resource that compares chemical, photochemical, and electrochemical methods in organic synthesis.
Dissertation Abstracts International
Author: Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 886
Book Description
American Doctoral Dissertations
Author: Publisher:
ISBN:
Category : Dissertation abstracts
Languages : en
Pages : 816
Book Description
Comprehensive Dissertation Index
Author: Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 754
Book Description
Electrochemical Synthesis of Nanoengineered Materials and Their Applications
Author: Nosang Vincent MyungPublisher: Frontiers Media SA
ISBN: 2889631923
Category :
Languages : en
Pages : 116
Book Description