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Author: Philip C.B. Page Publisher: Springer ISBN: 3540489568 Category : Science Languages : en Pages : 194
Book Description
Organosulfur Chemistry has enjoyed a renaissance of interest over the last few years, fuelled by its impact in the areas of heterocyclic and radical chemistry, and particularly stereocontrolled processes including asymmetric synthesis. One result of this resurgence of interest in the field is a rapidly escalating number of related publications. This volume is intended to provide coverage of some of the highlights of contemporary organosulfur chemistry chosen from the entire range of current activity.
Author: Philip C.B. Page Publisher: Springer ISBN: 3540489568 Category : Science Languages : en Pages : 194
Book Description
Organosulfur Chemistry has enjoyed a renaissance of interest over the last few years, fuelled by its impact in the areas of heterocyclic and radical chemistry, and particularly stereocontrolled processes including asymmetric synthesis. One result of this resurgence of interest in the field is a rapidly escalating number of related publications. This volume is intended to provide coverage of some of the highlights of contemporary organosulfur chemistry chosen from the entire range of current activity.
Author: N. Kharasch Publisher: Elsevier ISBN: 1483224856 Category : Science Languages : en Pages : 637
Book Description
Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
Author: S. Oae Publisher: Springer Science & Business Media ISBN: 1468420496 Category : Science Languages : en Pages : 714
Book Description
In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.
Author: Philip C.B. Page Publisher: Springer ISBN: 354048986X Category : Science Languages : en Pages : 205
Book Description
Organosulfur Chemistry has enjoyed a renaissance of interest over the last few years, fuelled by its impact in the areas of heterocyclic and radical chemistry, and particularly stereocontrolled processes including asymmetric synthesis. One result of this resurgence of interest in the field is a rapidly escalating number of related publications. This volume is intended to provide coverage of some of the highlights of contemporary organosulfur chemistry chosen from the entire range of current activity.
Author: Patrick Metzner Publisher: Elsevier ISBN: 1483289281 Category : Science Languages : en Pages : 219
Book Description
Designed for the practising organic chemist, this book details over a hundred experimental procedures using sulfer compounds in organic synthesis. Many of these methods are new to the literature, having been published since 1991, and illustrate the striking versatility of the use of sulfur reagents. Examples are simple to perform and extremely useful, and as such this book will be an invaluable aid to all involved in synthetic organic chemistry, whether in academic or industrial laboratories.
Author: Ismayil A. Aliyev Publisher: Springer Nature ISBN: 3030696219 Category : Science Languages : en Pages : 388
Book Description
This book is devoted to the synthetic and physical chemistry of aromatic thiols and their closest derivatives, sulfides, sulfoxides, sulfones, including those substituted by various functional groups such as acyl and thioacyl, alkoxide, ester, hydroxyl and halogens. In some cases, for comparison, selenium and oxygen analogues are also detailed. The main focus of the book is on synthetic methods, both traditional and new, based on the use of transition metals as catalysts, as well as the reactivity of the compounds obtained. Its addition to the influence of conformational and electronic factors on spectral (NMR, IR, UV, NQR) and electrochemical characteristics of the compounds is presented. Finally, the book describes the application of aromatic thiols and their derivatives as drug precursors, high-tech materials, building blocks for organic synthesis, analytical reagents and additives for oils and fuels. It is a useful handbook for all those interested in organosulfur chemistry.
Author: R. J. Cremlyn Publisher: John Wiley & Sons ISBN: Category : Science Languages : en Pages : 272
Book Description
Sulfur chemistry is becoming increasingly important as the role of this element is explored in both biological and environmental fields. After the initial chapters have discussed the synthesis, reactivity, and properties of the compounds in general, each of the next nine chapters takes a specific sulfur containing functional group and expands the discussion on synthetic procedures. The final chapter looks at the major uses of organo-sulfur compounds and their impact on biological and environmental areas.
Author: Takeshi Toru Publisher: John Wiley & Sons ISBN: 3527623248 Category : Science Languages : en Pages : 448
Book Description
In this first book to gather the information on this hot topic otherwise widely spread throughout the literature, experienced editors and top international authors cover everything the reader needs -- from the synthesis of chiral organosulfur compounds to applications and catalysis: * Asymmetric synthesis of chiral sulfinates and sulfoxides * Synthesis and use of chiral dithioacetal derivatives, ylids, chiral sulfoximines and sulfinamides * Use of chiral sulfoxides as ligands in catalysis * Asymmetric reactions of alpha-sulfenyl, alpha-sulfinyl and alpha-sulfonyl carbanions. As a result, readers will be able to improve their own performance in asymmetric synthesis.
Author: Gordon Harlow Whitham Publisher: Oxford University Press, USA ISBN: Category : Medical Languages : en Pages : 106
Book Description
Currently there is no concise teaching text aimed at 2/3rd year undergraduates on organosulfur chemsitry. Organosulfur chemistry is widely taught at this level. After a brief introductory chapter the main part of the book deals with the preparation and chemical properties of the principaltypes of organosulfur compounds classified under the headings: Divalent sulfur compounds, Tricoordinate sulfur compounds, and Tetracoordinate sulfur compounds. In choosing examples to illustrate the text, the guiding principle has been that the illustrations should provide insight into and anunderstanding of the characteristic features of organosulfur chemistry. Two concluding chapters deal, on the one hand, with applications of organosulfur compounds in organic synthesis and, on the other, with a brief summary of organoselenium chemistry, highlighting the similarities and differenceswith respect to organosulfur chemistry.
Author: Gerald Kutney Publisher: ChemTec Publishing ISBN: 1895198372 Category : Science Languages : en Pages : 180
Book Description
This attractive volume presents the history, characteristics, and uses for that vibrant yellow element, sulfur. Commercial sulfuric acid production from the early 16th century until today is reviewed, spanning the Ancient and Renaissance periods, the Industrial Age (to which sulfur was vitally important), and the Sulfur War of 1840. The book introduces "the Sulfur Age" and the processes of this period -- such as the Nordhausen, Bell and Leblanc methods --, then goes on to review native sulfur production in Sicily, once a major supplier to the world. Colorful characters abound here, including the Gabelloti, Doppioni, and wine merchants. The focus shifts to Frasch Sulfur production, with a portrait of Herman Frasch, his life and career, and a look at areas touched by his legacy (e.g., Texas, Mexico, Poland and Iraq). Moving to present day, the book presents "recovered" sulfur -- derived from sour gas and oil -- which constitutes 90% of today's elemental sulfur supply, and looks to Canada, a powerhouse supplier of Recovered Sulfur. An entire chapter is devoted to the modern-day sulfur entrepreneur, with a profile of various investors (from the reluctant to the private and institutional), and evaluates the benefits of adopting "revolutionary technologies". Finally, the book forecasts the sulfur industry's future and potential supply sources, such as worldwide oil sands. If you need a single, comprehensive book on sulfur, this is a book for your library.
Author: Philip C.B. Page
Author: Philip C.B. Page
Author: N. Kharasch
Author: S. Oae
Author: Philip C.B. Page
Author: Patrick Metzner
Author: Ismayil A. Aliyev
Author: R. J. Cremlyn
Author: Takeshi Toru
Author: Gordon Harlow Whitham
Author: Gerald Kutney