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Author: Vladimir Ya Lee Publisher: Academic Press ISBN: 0128019913 Category : Science Languages : en Pages : 758
Book Description
Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. - Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry - Covers important breakthroughs in the field, along with the historically significant achievements of the past - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) - Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology
Author: Vladimir Ya Lee Publisher: Academic Press ISBN: 0128019913 Category : Science Languages : en Pages : 758
Book Description
Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds' structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. - Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry - Covers important breakthroughs in the field, along with the historically significant achievements of the past - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) - Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology
Author: Vaclav Chvalovsky Publisher: Springer Science & Business Media ISBN: 1475703813 Category : Science Languages : en Pages : 315
Book Description
The term "carbon-functional organosilicon compound" is used for organosilicon compounds in which a functional group is bonded to an organic moiety that is in turn con nected to silicon via a Si-C bond. Thus, only Si-Cn-Y com pounds (Y designates a functional group) will be discussed in this book 1 Si-O-Cn-Y compounds will in general not be considered, although the latter group does include a large number of natural substances containing silylated hydroxyl groups. (Because of the differing importance of various Y groups, the reader will find some deviation from this restriction). Finally, compounds containing a silyl group as the functional group are not considered. An overview of the field of organosilicon chemistry would show that in the last several decades the commercial synthesis of organosilicon products has increased substan tially, both in annual production and also in the increasing variety of compounds produced. This increase in the number of commercially available carbon-functional monomers and polymers (silicone polymers) is most remarkable and is occurring because new applications are continually being found for these compounds. As might be expected, the number of publications in this field is also increasing. The important position of silicon in the periodic table - between carbon, aluminum, and phosphorus - means that an understanding of the nature of the bonds in organosilicon compounds is quite important in order to understand the bonding in these other areas.
Author: Zvi Rappoport Publisher: John Wiley & Sons ISBN: 0471623849 Category : Science Languages : en Pages : 1188
Book Description
Complementing the six volumes already published in Patai'sChemistry of the Functional Groups series this title covers topicsnot previously updated in the set. Written by key researchers in the field it includes more practicalchapters and industrial examples than before as well as additionalmaterial. There is a strong emphasis on "Poly" derivatives of variousclasses of silicon compounds as well as a chapter on silicon inmodern high-technology. These supplement the "practical" parts ofearlier volumes and enhance past material. * Continues with the high standard expected of the series * Complement to the 3 volume set of the chemistry of organicsilicon compounds published in 1998 * Updates content from previous volumes and includes chapters ontheory and silicon based radicals that are of theoretical andpractical importance * An invaluable reference source to organic chemists working inacademia and industry * Includes many more industrial examples than previous titles inthe series This volume complements the main volumes, with little overlap, andensures the functional group series continues its superiority inthe silicon field. This volume is now available in electronic format from BooksOnline.
Author: Norbert Auner Publisher: Wiley-VCH ISBN: 9783527306701 Category : Science Languages : en Pages : 0
Book Description
Never Change a winning team. The fifth volume in this renowned series retains the established and successful concept: Leading experts from academia and industry present a comprehensive and detailed overview of the latest results in organosilicon chemistry. Synthesis and characterization of new organosilicon compounds Applications in polymer and materials science Summary of the latest research results The result is a unique collection of first-hand information, vital for every expert working in this field. From the contents: Reactions of Silicon Atoms- An Access to Unusual Molecules New Reactions of Stable Silylenes Synthesis and Chemistry of Some Bridged Silicocations Synthesis of a Highly Enantiomerically Enriched Silyllithium Compound Experimental Determination of the Inversion Barriers of Oligosily Anions SiO and SiOSiN Chains, Rings, and Cages Novel Cyclic and Polycyclic Chalcogenides of Silicon Organosilicon Compounds in Medicine and Cosmetics Organosilicon Chemistry and Nanoscience Sustainable Silicon Production The Role of Silanes in Filled and Crosslinked Polymers Catalytic Hydrosilylation of Fatty Compounds Novel Routes fro the Preparation of Nanoporous Silica Particles Aluminosiloxanes as Molecular Models for Aluminosilicates
Author: Vladimir Ya Lee Publisher: Academic Press ISBN: 0128143630 Category : Science Languages : en Pages : 1436
Book Description
Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. - Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects - Covers important breakthroughs in the field, along with historically significant achievements - Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more
Author: Ernest W. Colvin Publisher: Butterworth-Heinemann ISBN: 148314223X Category : Science Languages : en Pages : 361
Book Description
Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a "ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.
Author: Herbert W Roesky Publisher: Academic Press ISBN: 0128035684 Category : Science Languages : en Pages : 540
Book Description
Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter
Author: Constantine D. Papaspyrides Publisher: Newnes ISBN: 0444538097 Category : Technology & Engineering Languages : en Pages : 943
Book Description
Polymer Green Flame Retardants covers key issues regarding the response of polymers during fire, the mechanisms of their flame retardation, the regulations imposed on their use, and the health hazards arising from their combustion. Presenting the latest research developments, the book focuses in particular on nanocomposites, believed to be the most promising approach for producing physically superior materials with low flammability and ecological impact. The fire properties of nanocomposites of various matrixes and fillers are discussed, the toxicological characteristics of these materials are analyzed, addressing also their environmental sustainability. Edited by distinguished scientists, including an array of international industry and academia experts, this book will appeal to chemical, mechanical, environmental, material and process engineers, upper-level undergraduate and graduate students in these disciplines, and generally to researchers developing commercially attractive and environmentally friendly fire-proof products. - Provides recent findings on the manufacture of environmentally sustainable flame retardant polymeric materials - Covers legislation and regulations concerning flame retarded polymeric material use - Includes tables containing the fire properties of the most common polymeric materials
Author: Vladimir Ya Lee
Author: Vladimir Ya Lee
Author: Grish Chandra
Author: Vaclav Chvalovsky
Author: Stephan Pawlenko
Author: Zvi Rappoport
Author: Norbert Auner
Author: Vladimir Ya Lee
Author: Ernest W. Colvin
Author: Herbert W Roesky
Author: Constantine D. Papaspyrides