Introductory Organic Reaction Mechanisms: A color-coded approach to arrow pushing PDF Download

Author: Michael Leonard
Publisher: Lulu.com
ISBN: 1304515893
Category : Science
Languages : en
Pages : 365

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Book Description
To master Organic Chemistry, it is essential to master mechanism. This book uses a novel approach to help you better understand the mechanisms of 80 common organic reactions. Each one is color coded so that you can clearly see the changes that take place during the reaction. The electrons involved in the mechanism are color coded, as are the arrows originating from those electrons and the bonds or lone pairs formed by them in the intermediates and product. As a result, you can trace specific pairs of electrons through an entire transformation. The description of what each mechanistic arrow means is color coded correspondingly so that it is easy to match up the text with the relevant portion of a reaction diagram.

Author: Robert B. Grossman
Publisher: Springer Science & Business Media
ISBN: 0387954686
Category : Science
Languages : en
Pages : 371

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Book Description
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.

Author: Xiaoping Sun
Publisher: John Wiley & Sons
ISBN: 1118507916
Category : Science
Languages : en
Pages : 401

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Book Description
Instills a deeper understanding of how and why organic reactions happen Integrating reaction mechanisms, synthetic methodology, and biological applications, Organic Mechanisms gives organic chemists the tools needed to perform seamless organic reactions. By explaining the underlying mechanisms of organic reactions, author Xiaoping Sun makes it possible for readers to gain a deeper understanding of not only chemical phenomena, but also the ability to develop new synthetic methods. Moreover, by emphasizing biological applications, this book enables readers to master both advanced organic chemistry theory and practice. Organic Mechanisms consists of ten chapters, beginning with a review of fundamental physicochemical principles that are essential for understanding the nature of organic mechanisms. Each one of the remaining chapters is devoted to a major class of organic reactions, including: Aliphatic C H bond functionalization Functionalization of the alkene C=C bond by cycloaddition reactions Nucleophilic substitutions on sp3-hybridized carbons Nucleophilic additions and substitutions on carbonyl groups Reactivity of the α-hydrogen to carbonyl groups Rearrangements A brief review of basic organic chemistry begins each chapter, helping readers move from fundamental concepts to an advanced understanding of reaction mechanisms. Key mechanisms are illustrated by expertly drawn figures highlighting microscopic details. End-of-chapter problems enable readers to put their newfound knowledge into practice by solving key problems in organic reactions with the use of mechanistic studies, and a Solutions Manual is available online for course instructors. Thoroughly referenced and current with recent findings in organic reaction mechanisms, Organic Mechanisms is recommended for upper-level undergraduates and graduate students in advanced organic chemistry, as well as for practicing chemists who want to further explore the mechanistic aspects of organic reactions.

Author: Daniel E. Levy
Publisher: John Wiley & Sons
ISBN: 111821045X
Category : Science
Languages : en
Pages : 258

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Book Description
Find an easier way to learn organic chemistry with Arrow-Pushing in Organic Chemistry: An Easy Approach to Understanding Reaction Mechanisms, a book that uses the arrow-pushing strategy to reduce this notoriously challenging topic to the study of interactions between organic acids and bases. Understand the fundamental reaction mechanisms relevant to organic chemistry, beginning with Sn2 reactions and progressing to Sn1 reactions and other reaction types. The problem sets in this book, an excellent supplemental text, emphasize the important aspects of each chapter and will reinforce the key ideas without requiring memorization.

Author: Michael B. Smith
Publisher: John Wiley & Sons
ISBN: 0470084944
Category : Science
Languages : en
Pages : 2379

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Book Description
The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations

Author: A. C. Knipe
Publisher: John Wiley & Sons
ISBN: 1118707869
Category : Science
Languages : en
Pages : 728

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Book Description
Organic Reaction Mechanisms 2013, the 49th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2013. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation.

Author: Reinhard Bruckner
Publisher: Springer Science & Business Media
ISBN: 3642036503
Category : Science
Languages : en
Pages : 873

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Book Description
This English edition of a best-selling and award-winning German textbook Reaction Mechanisms: Organic Reactions · Stereochemistry · Modern Synthetic Methods is aimed at those who desire to learn organic chemistry through an approach that is facile to understand and easily committed to memory. Michael Harmata, Norman Rabjohn Distinguished Professor of Organic Chemistry (University of Missouri) surveyed the accuracy of the translation, made certain contributions, and above all adapted its rationalizations to those prevalent in the organic chemistry community in the English-speaking world. Throughout the book fundamental and advanced reaction mechanisms are presented with meticulous precision. The systematic use of red "electron-pushing arrows" allows students to follow each transformation elementary step by elementary step. Mechanisms are not only presented in the traditional contexts of rate laws and substituent effects but, whenever possible, are illustrated using practical, useful and state-of-the-art reactions. The abundance of stereoselective reactions included in the treatise makes the reader familiar with key concepts of stereochemistry. The fundamental topics of the book address the needs of upper-level undergraduate students, while its advanced sections are intended for graduate-level audiences. Accordingly, this book is an essential learning tool for students and a unique addition to the reference desk of practicing organic chemists, who as life-long learners desire to keep abreast of both fundamental and applied aspects of our science. In addition, it will well serve ambitious students in chemistry-related fields such as biochemistry, medicinal chemistry and pharmaceutical chemistry. From the reviews: "Professor Bruckner has further refined his already masterful synthetic organic chemistry classic; the additions are seamless and the text retains the magnificent clarity, rigour and precision which were the hallmark of previous editions. The strength of the book stems from Professor Bruckner’s ability to provide lucid explanations based on a deep understanding of physical organic chemistry and to limit discussion to very carefully selected reaction classes illuminated by exquisitely pertinent examples, often from the recent literature. The panoply of organic synthesis is analysed and dissected according to fundamental structural, orbital, kinetic and thermodynamic principles with an effortless coherence that yields great insight and never over-simplifies. The perfect source text for advanced Undergraduate and Masters/PhD students who want to understand, in depth, the art of synthesis ." Alan C. Spivey, Imperial College London "Bruckner’s ‘Organic Mechanisms’ accurately reflects the way practicing organic chemists think and speak about organic reactions. The figures are beautifully drawn and show the way organic chemists graphically depict reactions. It uses a combination of basic valence bond pictures with more sophisticated molecular orbital treatments. It handles mechanisms both from the "electron pushing perspective" and from a kinetic and energetic view. The book will be very useful to new US graduate students and will help bring them to the level of sophistication needed to be serious researchers in organic chemistry." Charles P. Casey, University of Wisconsin-Madison "This is an excellent advanced organic chemistry textbook that provides a key resource for students and teachers alike." Mark Rizzacasa, University of Melbourne, Australia.

Author: Peter Wepplo
Publisher: Curved Arrow Press
ISBN: 0977931331
Category : Science
Languages : en
Pages : 158

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Book Description
A Handbook to Organic Chemistry Mechanisms is designed to accompany a standard organic chemistry textbook. The book presents complete mechanisms, start to finish, without any steps skipped or left out. The mechanisms have been carefully written to show each step in a logical and easy to follow format. Students have enthusiastically attested to the ease with which they could understand the mechanisms. Reaction mechanisms are one of the most challenging aspects of organic chemistry. This book is derived from Part D of A Guide to Organic Chemistry Mechanisms. That book is a guided inquiry workbook that shows students how to study and enables them to learn reaction mechanisms. Student knowledge is increased step by step by completing mechanisms at easy, moderate, and textbook levels of difficulty. A Handbook to Organic Chemistry Mechanisms also relies on example-based teaching. Chemical reactions can be learned in context, the way infants learn. Learning reactions from rules is difficult when there are many exceptions. Substitution and elimination reactions are noteworthy due to the number of conditions that must be accounted for. With example-based teaching, you can deduce the importance that stereochemistry, structure, solvent, leaving group, charge, basicity, or nucleophilicity may have on a reaction. A Handbook to Organic Chemistry Mechanisms has been designed with the principle that our brains are pattern-matching machines. Therefore, an emphasis has been placed upon the patterns of reactions. Each chapter represents a basic mechanistic theme. That theme is repeated with the examples. Insightful explanations have been included with the mechanisms. This book will be a valuable resource for reviewing for an exam, solving problems, or studying for the MCAT.

Author: Peter Wepplo
Publisher: Curved Arrow Press
ISBN: 9780977931309
Category : Science
Languages : en
Pages : 0

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Book Description
This is a reaction mechanism workbook designed to accompany a standard organic chemistry textbook. The book presents reaction mechanisms at three levels of difficulty: basic, moderate, and advanced. In Part A, the easiest, the missing curved arrows are missing. In Part B, the same problem is repeated with every other intermediate or product missing. In Part C, the problems are written in textbook fashion, and the same number of arrows have been retained. Thus, you are guided from learning the logic of a reaction to writing a complete mechanism. Once you have mastered a mechanism, you should be able to solve similar problems in your textbook. Part D gives completed mechanisms.

Author: Jiben Roy
Publisher: Universal-Publishers
ISBN: 1612332617
Category : Science
Languages : en
Pages : 259

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Book Description
A Self-Study Guide to the Principles of Organic Chemistry: Key Concepts, Reaction Mechanisms, and Practice Questions for the Beginner will help students new to organic chemistry grasp the key concepts of the subject quickly and easily, as well as build a strong foundation for future study. Starting with the definition of "atom," the author explains molecules, electronic configuration, bonding, hydrocarbons, polar reaction mechanisms, stereochemistry, reaction varieties, organic spectroscopy, aromaticity and aromatic reactions, biomolecules, organic polymers, and a synthetic approach to organic compounds. The over one hundred diagrams and charts contained in this volume will help students visualize the structures and bonds as they read the text, and make the logic of organic chemistry clear and easily understood. Each chapter ends with a list of frequently-asked questions and answers, followed by additional practice problems. Answers are included in the Appendix.