Organic Ion-molecule Reactions in a Flowing Afterglow PDF Download

Author: Robert Jeffrey Schmitt
Publisher:
ISBN:
Category : Afterglow (Physics)
Languages : en
Pages : 260

View

Book Description

Author: Karen Knutsen
Publisher:
ISBN:
Category : Charge transfer
Languages : en
Pages : 390

View

Book Description

Author: J. L. Franklin
Publisher: Springer Science & Business Media
ISBN: 1468419382
Category : Science
Languages : en
Pages : 403

View

Book Description
Of Volume 2.- 8. Flowing Afterglow Studies.- 1. Introduction.- 2. Studies Bearing on Intermediate Complex Formation in Thermal Energy Collisions.- 2.1. Temperature Dependence of Slow Ion-Molecule Reactions.- 2.2. Three-Body Reaction Rate Constants.- 2.3. Rotational Excitation in Ion-Neutral Reactions.- 2.4. Miscellaneous Considerations of Intermediate Complex Processes.- 3. Studies Bearing on Negative-Ion Resonance Formation.- 4. Studies Bearing on Energetics.- 5. Conclusions.- References.- 9. Ion Cyclotron Resonance Spectrometry.- 1. Introduction.- 1.1. General Characteristics.- 2. Theoretica.

Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

View

Book Description
A variable temperature-selected ion flow drift tube (VT-SIFDT) and a high temperature flowing afterglow (HTFA) have been used to study ion-molecule reactions in the 220 - 1400 K temperature range. The effects of electronic, vibrational, and rotational energy on the kinetics of a wide range of reactions important in combustion chemistry have been investigated.

Author: Linda Margaret Parker
Publisher:
ISBN:
Category : Afterglow (Physics)
Languages : en
Pages : 270

View

Book Description

Author: Siu H. Stephen Chan
Publisher:
ISBN:
Category : Ions
Languages : en
Pages : 458

View

Book Description

Author: Michael T. Bowers
Publisher: Elsevier
ISBN: 1483282341
Category : Science
Languages : en
Pages : 468

View

Book Description
Gas Phase Ion Chemistry, Volume 3: Ions and Light discusses how ions are formed by electron impact, ion–molecule reactions, or electrical discharge. This book discusses the use of light emitted by excited molecules to characterize either the chemistry that formed the excited ion, the structure of the excited ion, or both. Organized into 10 chapters, this volume begins with an overview of the extension of the classical flowing afterglow technique to include infrared and chemiluminescence and laser-induced fluorescence detection. This text then examines the experiments involving molecules that are isolated from collisions for periods exceeding several milliseconds. Other chapters consider the photodetachment in negative ion beams and the chemical information that can be obtained from such studies. This book discusses as well the electronic states of the open-shell organic cations. The final chapter deals with ion beam spectroscopy. This book is a valuable resource for chemists and scientists.

Author: Pierre Ausloos
Publisher: Springer Science & Business Media
ISBN: 9400937873
Category : Science
Languages : en
Pages : 491

View

Book Description
This volume presents the proceedings of a 1986 Advanced Study Institute entitled "Structure/Reactivity and Thermochemistry of Ions", held at Les Arcs, France, June 30 to July 11, 1986. The format of a NATO Institute is ideally suited to in-depth communications between scien tists of diverse backgrounds. Particularly in the field of ion physics and chemistry, where on-going research involves physicists, physical chemists, and organic chemists - who use a variety of experimental and theoretical techniques - it is found that in the relaxed but stimula ting atmosphere of a NATO ASI, each professional group provides unique insights, leading to a better definition and solution of problems relating to the properties of gas phase ions. This book presents chapters based on the lectures presented at the Les Arcs ASI. The participants took the initiative to organize a number of specialized workshops - informal discussion groups which considered questions or problem areas of particular interest. The accounts of these sessions, which are also included in this book, make stimulating reading, and include considerable useful information. This Advanced Study Institute is the fourth in a series of NATO-spon sored institutes devoted to the chemistry and physics of ions in the gas phase. The first, in 1974, in Biarritz, France, focussed on "Interactions between Ions and Molecules".

Author: Stepen R. Leone
Publisher:
ISBN:
Category :
Languages : en
Pages : 18

View

Book Description
An extensive set of studies was undertaken utilizing infrared chemiluminescence, visible chemiluminescence and laser induced fluorescence detection to explore the dynamics of ion molecule reactions in a flowing afterglow apparatus. Detailed product vibrational state distributions were determined for a variety of reactions including heavy atom transfer in polyatomic systems, charge transfer reactions and proton transfer reactions. Absolute branching ratios for production of electronically excited oxygen atoms were measured for a reaction of atmospheric importance. The rotational state distribution of an ion in an electric drift field has been characterized and a study of the velocity distribution has been initiated.

Author: Toshihiro Fujii
Publisher: Springer
ISBN: 1489975888
Category : Science
Languages : en
Pages : 350

View

Book Description
This book explores the mechanism of alkali-metal ion/molecule association reaction, surveys the instrumental basis to study its kinetic, and describes the instrumentation to the measurement of alkali-metal ion affinities. The applications of the ion complexation mechanism in the condensed phase in reaction to direct analysis MS are also covered. Other topics include mechanism and reaction rate, experimental and theoretical ion affinities, applications of ion attachment reactions (IAR) to mass spectrometry such as alkali ion CIMS, ion attachment MS and cationization mass spectrometry of ESI, FAB, FD, LD, MALDI and SIMS and topics of IAR-based direct analysis mass spectrometry.